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111.
Ghosh S Roehm B Begum RA Kut J Hossain MA Day VW Bowman-James K 《Inorganic chemistry》2007,46(23):9519-9521
The crystal structures of two metallo oxides, perrhenate and dichromate, are reported with a diprotonated tetraamido/diamino-based macrocycle, L, in which the floppy ligand assumes a folded conformation. When the four amides are deprotonated, this same ligand binds transition-metal ions in its tetraanionic form, H-4L. For the divalent metal ions Cu2+ and Ni2+, H-4L again folds and dinuclear complexes are formed. With trivalent metal ions Co3+ and Fe3+, the ligand wraps about the metal ions, resulting in mononuclear complexes. 相似文献
112.
Salwinder Singh Dhaliwal Vivek Sharma Arvind Kumar Shukla Janpriya Kaur Vibha Verma Prabhjot Singh Harkirat Singh Shams H. Abdel-Hafez Samy Sayed Ahmed Gaber Reham Ali Akbar Hossain 《Molecules (Basel, Switzerland)》2021,26(24)
Biofortification of pulse crops with Zn and Fe is a viable approach to combat their widespread deficiencies in humans. Lentil (Lens culinaris Medik.) is a widely consumed edible crop possessing a high level of Zn and Fe micronutrients. Thus, the present study was conducted to examine the influence of foliar application of Zn and Fe on productivity, concentration, uptake and the economics of lentil cultivation (LL 931). For this, different treatment combinations of ZnSO4·7H2O (0.5%) and FeSO4·7H2O (0.5%), along with the recommended dose of fertilizer (RDF), were applied to the lentil. The results of study reported that the combined foliar application of ZnSO4·7H2O (0.5%) + FeSO4·7H2O (0.5%) at pre-flowering (S1) and pod formation (S2) stages was most effective in enhancing grain and straw yield, Zn and Fe concentration, and uptake. However, the outcome of this treatment was statistically on par with the results obtained under the treatment ZnSO4·7H2O (0.5%) + FeSO4·7H2O (0.5%) at S1 stage. A single spray of ZnSO4·7H2O (0.5%) + FeSO4·7H2O (0.5%) at S1 stage enhanced the grain and straw yield up to 39.6% and 51.8%, respectively. Similarly, Zn and Fe concentrations showed enhancement in grain (10.9% and 20.4%, respectively) and straw (27.5% and 27.6% respectively) of the lentil. The increase in Zn and Fe uptake by grain was 54.8% and 68.0%, respectively, whereas uptake by straw was 93.6% and 93.7%, respectively. Also the benefit:cost was the highest (1.96) with application of ZnSO4·7H2O (0.5%) + FeSO4·7H2O (0.5%) at S1 stage. Conclusively, the combined use of ZnSO4·7H2O (0.5%) + FeSO4·7H2O (0.5%) at S1 stage can contribute significantly towards yield, Zn and Fe concentration, as well as uptake and the economic returns of lentil to remediate the Zn and Fe deficiency. 相似文献
113.
114.
Al-Jubbori Mushtaq Abed Kassim Huda H. Radhi Fahmi Sh. Attarzadeh Amin Hossain I. Ahmed Imad M. Sharrad Fadhil I. 《Physics of Atomic Nuclei》2019,82(3):201-211
Physics of Atomic Nuclei - The even—even rare-earth nuclei in U(5)—SU(3) region at neutron number (N) = 90, have been systematically studied using the Bohr—Mottelson Model (BM),... 相似文献
115.
Vera Novak Mareile Haertle Peng Zhao Kun Hu Medha Munshi Peter Novak Amir Abduljalil David Alsop 《Magnetic resonance imaging》2009
Background
White matter hyperintensities (WMHs) on MRI have been associated with age, cardiovascular risk factors and falls in the elderly. This study evaluated the relationship between WMHs and dynamics of postural control in older adults without history of falls.Methods
We studied 76 community-living subjects without history of falls (age 64.5±7.3 years). Brain and WMH volume calculations and clinical rating were done on fluid-attenuation inversion recovery (FLAIR) and MP-RAGE MR images on 3 T. Balance was assessed from the center of pressure displacement using the force platform during 3 min of quiet standing using traditional and dynamic measures (using stabilogram-diffusion analysis). Gait speed was measured from 12-min walk.Results
Age-adjusted periventricular and focal WMHs were associated with changes in certain dynamic balance measures, including reduced range of postural sway in anteroposterior direction (fronto-temporal WMHs, P=.045; parieto-occipital WMHs, P=.009) and more irregular long-term mediolateral fluctuations (P=.046). Normal walking speed was not affected by WMHs.Conclusions
Periventricular and focal WMHs affect long-term dynamics of postural control, which requires engagement of feedback mechanisms, and may contribute to mobility decline in the elderly. 相似文献116.
Polycrystalline samples of ternary rare-earth germanides R2Co3Ge5 (R=La, Ce and Pr) have been prepared and investigated by means of magnetic susceptibility, isothermal magnetization, electrical resistivity and specific heat measurements. All these compounds crystallize in orthorhombic U2Co3Si5 structure (space group Ibam). No evidence of magnetic or superconducting transition is observed in any of these compounds down to 2 K. The unit cell volume of Ce2Co3Ge5 deviates from the expected lanthanide contraction, indicating non trivalent state of Ce ions in this compound. The reduced value of effective moment (μeff≈0.95 μB) compared to that expected for trivalent Ce ions further supports valence-fluctuating nature of Ce in Ce2Co3Ge5. The observed temperature dependence of magnetic susceptibility is consistent with the ionic interconfiguration fluctuation (ICF) model. Although no sharp anomaly due to a phase transition is seen, a broad Schottky-type anomaly is observed in the magnetic part of specific heat of Pr2Co3Ge5. An analysis of Cmag data suggests a singlet ground state in Pr2Co3Ge5 separated from the singlet first excited state by 22 K and a doublet second excited state at 73 K. 相似文献
117.
We investigate transverse electromagnetic waves propagating in a plasma influenced by the gravitational field of the Schwarzschild-de
Sitter black hole. Applying 3+1 spacetime split we derive the relativistic two-fluid equations to take account of gravitational
effects due to the event horizon and describe the set of simultaneous linear equations for the perturbations. We use a local
approximation to investigate the one-dimensional radial propagation of Alfvén and high frequency electromagnetic waves. We
derive the dispersion relation for these waves and solve it for the wave number k numerically. 相似文献
118.
119.
Amit Aran Soumika Munshi Vinod K. Beri Arun K. Gupta 《Optics and Lasers in Engineering》2009,47(6):636-643
This paper reports a morphological phase-only correlation technique based on bit-map representation for recognition of color as well as grey images in a hybrid digital-optical correlation architecture. The color image is decomposed into its R, G and B components, and each component is further decomposed into eight disjoint elementary images depending upon the bit-map representation of the color value at each pixel. Bit-map representation of the pixel values of an image reduces the required computational time. A set of twenty-four disjoint wavelet-modified binary phase-only filters (WBPOFs) are generated from these bit-map decomposed images. The target image is similarly decomposed into eight disjoint images each of R, G and B and their digital Fourier transforms multiplied with the corresponding WBPOFs. The product functions thus obtained are added up to form a single resultant product function, whose optical Fourier transformation gives the correlation peaks for the presence of R, G and B components in the image. The single product function overcomes the necessity of obtaining the final optical Fourier transformation of the R, G and B components separately. The novelty of this approach lies in the fact that the WBPOFs synthesized by this procedure are thus able to identify both colored as well as gray images and can tolerate salt-and-pepper noise to a considerable extent. 相似文献
120.
A variety of organosulfur compounds have been selectively oxidized to the corresponding sulfoxides by either H2O2 or HNO3 using a newly developed solid acid catalyst composed of 84.5% of TiO2 and 15.5% of [Ti4H11(PO4)9]·nH2O (n = 1-4). The chemoselective oxidation of sulfides in the presence of vulnerable groups such as -CN, -CC-, -CHO, or -OH, as well as sulfoxidation of substrates like benzothiazole, glycosyl sulfide, and dibenzothiophenes is some of the important attribute of the protocol. Nitric acid, under the present experimental conditions, brings about relatively better selectivity than hydrogen peroxide. 相似文献