全文获取类型
收费全文 | 151篇 |
免费 | 3篇 |
国内免费 | 2篇 |
专业分类
化学 | 91篇 |
晶体学 | 1篇 |
力学 | 1篇 |
数学 | 4篇 |
物理学 | 59篇 |
出版年
2023年 | 1篇 |
2022年 | 1篇 |
2020年 | 2篇 |
2019年 | 2篇 |
2018年 | 2篇 |
2017年 | 1篇 |
2016年 | 6篇 |
2014年 | 1篇 |
2013年 | 4篇 |
2012年 | 6篇 |
2011年 | 9篇 |
2010年 | 3篇 |
2009年 | 2篇 |
2008年 | 7篇 |
2007年 | 3篇 |
2006年 | 11篇 |
2005年 | 7篇 |
2004年 | 9篇 |
2003年 | 7篇 |
2002年 | 7篇 |
2001年 | 3篇 |
2000年 | 5篇 |
1999年 | 3篇 |
1997年 | 4篇 |
1996年 | 7篇 |
1995年 | 1篇 |
1994年 | 3篇 |
1993年 | 5篇 |
1992年 | 3篇 |
1991年 | 4篇 |
1990年 | 1篇 |
1989年 | 6篇 |
1988年 | 2篇 |
1987年 | 1篇 |
1985年 | 1篇 |
1984年 | 4篇 |
1983年 | 1篇 |
1980年 | 1篇 |
1979年 | 2篇 |
1978年 | 2篇 |
1977年 | 1篇 |
1975年 | 1篇 |
1974年 | 2篇 |
1970年 | 1篇 |
1962年 | 1篇 |
排序方式: 共有156条查询结果,搜索用时 15 毫秒
21.
CO oxidation over ceria-supported Au22 nanoclusters shows strong dependence on the support shape: the lattice oxygen in CeO2 rods is more reactive than in the cubes and thus make rods a superior support for Au nanoclusters in catalyzing low temperature CO oxidation. 相似文献
22.
Ojifinni RA Gong J Froemming NS Flaherty DW Pan M Henkelman G Mullins CB 《Journal of the American Chemical Society》2008,130(34):11250-11251
Experimental results supported by density functional theory calculations show carbonate formation and reaction on atomic oxygen precovered Au(111). Oxygen mixing is observed in temperature-programmed desorption measurements when a Au(111) precovered with 16O is exposed to isotopically labeled CO2 (C18O2). The presence of 16O18O is attributed to surface carbonate formation and decomposition at surface temperatures ranging from 77-400 K and initial oxygen coverages ranging from 0.18-2.1 ML. A reaction probability on the order of 10(-4) and an activation energy of -0.15+/- 0.08 eV are estimated for this reaction. 相似文献
23.
Ojifinni RA Froemming NS Gong J Pan M Kim TS White JM Henkelman G Mullins CB 《Journal of the American Chemical Society》2008,130(21):6801-6812
Water-oxygen interactions and CO oxidation by water on the oxygen-precovered Au(111) surface were studied by using molecular beam scattering techniques, temperature-programmed desorption (TPD), and density functional theory (DFT) calculations. Water thermally desorbs from the clean Au(111) surface with a peak temperature of approximately 155 K; however, on a surface with preadsorbed atomic oxygen, a second water desorption peak appears at approximately 175 K. DFT calculations suggest that hydroxyl formation and recombination are responsible for this higher temperature desorption feature. TPD spectra support this interpretation by showing oxygen scrambling between water and adsorbed oxygen adatoms upon heating the surface. In further support of these experimental findings, DFT calculations indicate rapid diffusion of surface hydroxyl groups at temperatures as low as 75 K. Regarding the oxidation of carbon monoxide, if a C (16)O beam impinges on a Au(111) surface covered with both atomic oxygen ( (16)O) and isotopically labeled water (H 2 (18)O), both C (16)O (16)O and C (16)O (18)O are produced, even at surface temperatures as low as 77 K. Similar experiments performed by impinging a C (16)O beam on a Au(111) surface covered with isotopic oxygen ( (18)O) and deuterated water (D 2 (16)O) also produce both C (16)O (16)O and C (16)O (18)O but less than that produced by using (16)O and H 2 (18)O. These results unambiguously show the direct involvement and promoting role of water in CO oxidation on oxygen-covered Au(111) at low temperatures. On the basis of our experimental results and DFT calculations, we propose that water dissociates to form hydroxyls (OH and OD), and these hydroxyls react with CO to produce CO 2. Differences in water-oxygen interactions and oxygen scrambling were observed between (18)O/H 2 (16)O and (18)O/D 2 (16)O, the latter producing less scrambling. Similar differences were also observed in water reactivity toward CO oxidation, in which less CO 2 was produced with (16)O/D 2 (16)O than with (16)O/H 2 (16)O. These differences are likely due to primary kinetic isotope effects due to the differences in O-H and O-D bond energies. 相似文献
24.
Reddy CM Nelson RK Sylva SP Xu L Peacock EA Raghuraman B Mullins OC 《Journal of chromatography. A》2007,1148(1):100-107
Comprehensive two-dimensional gas chromatography with flame ionization detection (GC x GC-FID) was used to measure alkene-based drilling fluids in crude oils. Compared to one-dimensional gas chromatography, GC x GC-FID is more robust for detecting alkenes due to the increased resolution afforded by second dimension separations. Using GC x GC-FID to analyze four oil samples from one reservoir contaminated with the same drilling fluid, C(15), C(16), C(17), C(18) and C(20) alkenes were identified. The drilling fluid that contaminated these samples also differed from another commercially obtained fluid, which only contained C(16) and C(18) alkenes. These results should motivate the petroleum industry to consider GC x GC-FID for measuring drilling fluids. 相似文献
25.
Hoang S Berglund SP Hahn NT Bard AJ Mullins CB 《Journal of the American Chemical Society》2012,134(8):3659-3662
We report a synergistic effect involving hydrogenation and nitridation cotreatment of TiO(2) nanowire (NW) arrays that improves the water photo-oxidation performance under visible light illumination. The visible light (>420 nm) photocurrent of the cotreated TiO(2) is 0.16 mA/cm(2) and accounts for 41% of the total photocurrent under simulated AM 1.5 G illumination. Electron paramagnetic resonance (EPR) spectroscopy reveals that the concentration of Ti(3+) species in the bulk of the TiO(2) following hydrogenation and nitridation cotreatment is significantly higher than that of the sample treated solely with ammonia. It is believed that the interaction between the N-dopant and Ti(3+) is the key to the extension of the active spectrum and the superior visible light water photo-oxidation activity of the hydrogenation and nitridation cotreated TiO(2) NW arrays. 相似文献
26.
Highly oriented thin films of cerium oxide with variable ratio of Ce3+/Ce4+ were grown on Ru(0 0 0 1) single crystal surface and loaded with a fixed, low coverage of Rh. The chemisorption of NO on the resulting model catalyst was studied by soft X-ray photoemission which yielded the relative quantities of N containing species on the surface as a function of temperature, and by thermal desorption which yielded the relative yields of NO and N2 desorbed. It is found that the ability of the reduced Rh clusters to dissociate NO depends upon the oxidation state of the ceria upon which it is deposited, and for highly reduced ceria surfaces effectively 100% of Rh-adsorbed NO dissociates by 350 K. Possible causes of this surprising behavior are discussed. 相似文献
27.
A direct dissociation mechanism has been traditionally assigned to molecular beam data that exhibit an increase in the initial adsorption probability with increasing kinetic energy. Yet, recent experiments of nitrogen and oxygen adsorption provide support for an alternative high kinetic energy pathway in which incident energy assists in surmounting barriers to molecular chemisorption on a surface as the first step to dissociation. Moreover, systems for which the experimental evidence supports such a mechanism also demonstrate that molecularly chemisorbed intermediates can be spectroscopically observed at low temperatures and coverages from exposure to a gas in thermal equilibrium at room temperature. Likewise, such observations have not been measured for systems which are consistent with direct dissociation. A consideration of this trend regarding the existence of molecularly chemisorbed states and the implications for the dominant, dissociative chemisorption pathway at high kinetic energy is presented for a number of gas surface systems. 相似文献
28.
R. Wadsworth P. Regan S. M. Mullins G. J. Gyapong D. L. Watson P. J. Nolan M. J. Godfrey I. Jenkins Y. J. He B. J. Varley J. Simpso W. Gelletly 《Zeitschrift für Physik A Hadrons and Nuclei》1989,333(4):411-412
The states in the yrast band of132 Sm have been identified for the first time up to Jπ=16+. The yrast band of130Nd has also been extended from Jπ=16+ to 24+. The energy of the first 2+ state in132Sm indicates that the quadrupole deformation ε2 ~ 0.3 and is still increasing as the neutron number N decreases across the samarium isotopes. The results for130Nd allow the (h2/11)2 proton crossing frequency to be determined as ω=0.325 ± 0.005 MeV/?. This result is compared with cranked shell model predictions. 相似文献
29.
R. Wadsworth P. Regan S. M. Mullins G. J. Gyapong D. L. Watson P. J. Nolan M. J. Godfrey I. Jenkins Y. J. He B. J. Varley W. Gelletly J. Simpson 《Zeitschrift für Physik A Hadrons and Nuclei》1989,333(4):409-410
A rotational band of nine γ-rays has been observed in133Sm. The moment of inertia of the band indicates that it has a higher deformation than expected for states in nuclei in this region. The properties are such that it can be interpreted as being due to the odd neutron occupying the ν i2/13 nn intruder orbital. This is the first evidence for the occupation of this orbital in nuclei with neutron number N<73. 相似文献
30.