Pulsed Gradient Spin Echo Nuclear Magnetic Resonance Measurement and Simulation of Two-Fluid Taylor Vortex Flow in a Vertically Oriented Taylor–Couette Device

Magnetic resonance microscopy and Ansys Fluent^? computational fluid dynamics simulation have been used to classify Taylor vortex flows (TVF) for several single fluid and axially stratified two-fluid systems in a vertically oriented Taylor–Couette device. A Rheo-NMR (nuclear magnetic resonance) Couette system (Magritek Ltd, New Zealand) with a 1.05-mm gap was used to evaluate the transition from Couette flow to TVF in 1.65 cSt silicone oil, 1 cSt deionized water, and 0.65 cSt silicone oil. The rotation rate at which instability onset occurred agreed between experiment and simulation, as did the critical wavelength. Velocities were mapped for axially stratified two-fluid systems. The vortex containing the two-fluid interface was found to form with a significantly longer wavelength than that observed in the pure fluids. For experiments and simulations in the TVF regime, a region with no secondary flows was found at the interface, indicating interface stabilization by surface tension forces.     

Effect of thermal history on the ionic conductivity of block copolymer electrolytes

We have studied the effect of thermal history on ionic conductivity of block copolymer electrolytes. Previous work on block copolymer electrolytes composed of polystyrene‐b‐poly(ethylene oxide) (SEO) and lithium bis(trifluoromethanesulfone) imide (LiTFSI) salt was restricted to lamellar morphologies. This study addresses both cylindrical and lamellar morphologies. The conductivity of low molecular weight samples decreases after they are annealed. In contrast, the conductivity of high molecular weight samples is generally unaffected by annealing. These results are explained in the context of connectivity and composition of the conducting phase. © 2013 Wiley Periodicals, Inc. J. Polym. Sci. Part B: Polym. Phys. 2013 , 51, 927–934     

Concerted and stepwise proton-coupled electron transfers in aquo/hydroxo complex couples in water: oxidative electrochemistry of [Os(II)(bpy)(2)(py)(OH(2))](2+)

Successive oxidation of transition metal(II) aqua complexes (M(II)OH(2) to M(III)OH) is a domain in which proton-coupled electron transfer reactions are extremely common. The mechanism of these PCET reactions-concerted or stepwise-is an important issue in the understanding and design of natural or artificial systems catalyzing the formation of dioxygen by four-electron oxidation of water. Concerted proton-coupled electron transfer from an aqua metal(II) to a hydroxo metal(III) complex requires the close proximity of a proton-accepting group with a pK value between those of the aqua complexes. Otherwise, stepwise electron-proton or proton-electron pathways involving high-energy intermediates are followed. Concerted proton-electron pathways involving water as proton-acceptor or proton-donor group are inefficient. Cyclic voltammetry of the title complex in buffered aqueous solution and re-examination of previous results for the same complex attached to an electrode surface are used to establish these conclusions, which provide a starting point on the route to higher degrees of oxidation, such as those involved in the catalysis of water oxidation.     

Gamma and electron spectroscopy of transfermium isotopes at Dubna: Results and plans

Detailed spectroscopic information of excited nuclear states in deformed transfermium nuclei is scarce. Most of the information available today has been obtained from investigations of fine-structure α-decay. Although α decay gives access to hindrance factors and lifetimes which are strongly correlated to shell/subshell closures and the presence of isomers, only the combined use of γ and conversion electron spectroscopy allows the precise determination of excitation energy, spin and parity of nuclear levels.     

Symmetric Graph Designs

We introduce the notion of a symmetric graph design which is a common generalization of symmetric BIBDs and of orthogonal double covers. Revised: January 21, 1999     

The numerical integration of relative equilibrium solutions. The nonlinear Schrodinger equation

We analyse different error propagation mechanisms for conservativeand nonconservative time-integrators of nonlinear Schrödingerequations. We use a geometric approach based on interpretingwaves as relative equilibria.     

Pairwise Balanced Designs with Consecutive Block Sizes

This paper deals with existence for pairwise balanced designs with block sizes 5,6 and 7, block sizes 6,7 and 8 and block sizes 7,8 and 9 and some consequences of these results.     

Effect of molecular weight on conductivity of polymer electrolytes

The ionic conductivity, σ, of mixtures of poly(ethylene oxide) (PEO) and lithium bis(trifluoromethanesulfone)imide (LiTFSI) was measured as a function of molecular weight of the PEO chains, M, over the range 0.2-5000 kg/mol. Our data are consistent with an expression σ = σ₀ + K/M proposed by Shi and Vincent [Solid State Ionics 60 (1993)] where σ₀ and K are exponential and linear functions of inverse temperature respectively. Explicit expressions for σ₀ and K are provided.