Coagulation of the Suspended Organic Colloids Using the Electroflocculation Technique

Electroflotation is an unconventional separation process owing its name to the bubbles generation method (i.e., electrolysis of the aqueous medium) caused by the hydrogen and hydroxide development. Collecting the colloidal particles in surface water has been a long-term issue all over the world, because of their adverse influence. In the present research, the electroflocculation technique have been use to collect the humus particles throughout the polluted wastewater. The uses of different chemical additives namely, Al₂(SO₄)₃, Al(OH)₃, CaCl₂, CaO, and Na₂SiO₃ were also successfully examined and enhanced the electroflocculation technique. Although high negatively surface electrical charge of humus causes difficulties in the conventional flocculation and coagulation technique, it enhances the flocculation process when the electroflocculation techniques have been used. The results of both Jar test and electroflocculation technique are further compared. It can be concluded that the polluted water were fully decontaminated (i.e., all of the suspended colloids through the water were removed) by using the electroflocculation technique. The removal rate after electroflocculation test were 91.8%, 98%, 93.5%, 85.3%, 95.4%, and 94% for neutral, Al₂(SO₄)₃, Al(OH)₃, CaCl₂, CaO, and Na₂SiO₃, respectively. While the removal rate after Jar test were 84.8%, 83.79%, 71.44%, 84.83%, 77.09%, and 77.09% for neutral, Al₂(SO₄)₃, Al(OH)₃, CaCl₂, CaO, and Na₂SiO₃, respectively.     

Assessment of terrestrial gamma radiation dose rate (TGRD) of Kelantan State,Malaysia: Relationship between the geological formation and soil type to radiation dose rate

Terrestrial gamma radiation dose rates (TGRD) of Kelantan State were measured in situ using a portable [NaI(TI)] micro roentgen (µR) survey meter. The TGRD rates ranged between 44 and 500 nGy h^?1 with a mean value of 209 ± 8 nGy h^?1. The distribution of these measurements in various districts of the state shows the statistically the influence of geology and soil types on the dose rate values. The data obtained could be used in formulating safety standard and radiological guidelines.     

Comparative study of laser-induced plasma emission of hydrogen from zircaloy-2 samples in atmospheric and low pressure ambient helium gas

An experimental study has been performed to demonstrate the advantage of employing ambient helium gas in the spectral quality improvement of hydrogen emission in laser-induced plasma from zircaloy-2 samples at both atmospheric and low gas pressure. It was further shown that the optimal results achieved in the two pressure regimes require the adoption of different sets of experimental parameters consisting of the laser energy, the focusing lens position and the detection gate delay. A strictly linear calibration line with extrapolated zero intercept was nevertheless exhibited in the case of atmospheric gas pressure only. Additional time-evolution measurement of the emission intensities of hydrogen, helium and zirconium clearly suggests a distinctly different excitation mechanism for hydrogen atoms associated with the presence of ambient helium atoms and their meta-stable excited state. PACS 52.38 Mf     

Some notes on the role of meta-stable excited state of helium atom in laser-induced helium gas breakdown spectroscopy

A study of the experimental results on the plasma emissions of water and ethanol vapor samples, induced by Nd:YAG laser in ambient helium and nitrogen gases at atmospheric pressure, is presented here. The result reveals distinct geometrical and spectral characteristics of the plasma emissions generated in the helium gas when compared to those observed from nitrogen gas plasma. Most remarkable is the narrow line width and low continuum background exhibited by emission lines of the analyte atoms from helium plasma, including the hydrogen emission line which is known to suffer from notorious broadening effects in conventional laser induced breakdown spectroscopy (LIBS). It is further shown on the basis of the measured spatial distributions and time profiles of the emission intensities, that the excellent spectral quality is attained by taking advantage of the meta-stable excited state of helium atoms for the delayed excitation of the hydrogen and other analyte atoms, this allows the detection of those atomic emissions to be performed under more favorable conditions. The result of this study has thus demonstrated the feasibility of achieving high-quality spectrochemical analysis, including hydrogen analysis with laser-induced helium gas breakdown spectroscopy. PACS 52.38.Mf     

Preparation of alkaline polymer catalyst by radiation induced grafting for transesterification of triacetin under neural network optimized conditions

A simple and flexible method was used to develop new alkaline polymer catalyst through radiation induced grafting of glycidylmethacrylate (GMA) onto polyethylene/polypropylene (PE/PP) nonwoven sheet followed by amination reaction and alkalisation. The chemical structure and morphology of catalyst was evaluated by Fourier transform-infrared (FTIR), scanning electron microscopy (SEM), X-ray diffraction (XRD) and thermal gravimetric analyzer (TGA). The catalyst was examined for the transesterification of triacetin/methanol mixtures in a batch mode and the obtained methyl ester was detected by GC-MS. In order to optimize the reaction parameters towards getting the higher yield, an artificial neural network (ANN) was used to develop a non-linear model correlating the four independent reaction parameters including catalyst dosage, triacetin/methanol molar ratio, reaction time and temperature. The maximum conversion obtained via the simulated annealing (SA) algorithm was 86.2% at the optimal conditions of 5.01 wt% catalyst dosage, triacetin/methanol 1:12 molar ratio, 8 h reaction time and 62.8°C temperature. Upon using these optimal conditions in the experimental reaction, the conversion of as high as 85% was achieved. These results suggest that the simply modified low cost PE/PP fibrous sheet has a potential to catalyze biodiesel production. Moreover, the combined ANN-SA modelling method is highly effective in predicting the conversion of transesterification reaction and optimizing its parameters.     

Ethylene Conversion to Higher Hydrocarbon over Copper Loaded BZSM-5 in the Presence of Oxygen

The successful production of higher hydrocarbons from methane depends on the stability or the oxidation rate of the intermediate products. The performances of the BZSM-5 and the modified BZSM-5 catalysts were tested for ethylene conversion into higher hydrocarbons. The catalytic experiments were carried out in a fixed-bed micro reactor at atmospheric pressure. The catalysts were characterized using XRD, NH3-TPD, and IR for their structure and acidity. The result suggests that BZSM-5 is a weak acid. The introduction of copper into BZSM-5 improved the acidity of BZSM-5. The conversion of ethylene toward higher hydrocarbons is dependent on the acidity of the catalyst. Only weaker acid site is required to convert ethylene to higher hydrocarbons. The loading of Cu on BZSM-5 improved the selectivity for higher hydrocarbons especially at low percentage. The reactivity of ethylene is dependent on the amount of acidity as well as the presence of metal on the catalyst surface. Cu1%BZSM-5 is capable of converting ethylene to higher hydrocarbons. The balances between the metal and acid sites influence the performance of ethylene conversion and higher hydrocarbon selectivity. Higher loading of Cu leads to the formation of COx.     

XRD and TPR Studies of Cu-Al Hydrotalcite Derived Highly Dispersed Mixed Metal Oxides

A series of Cu/Al catalysts, containing different proportions of copper and aluminium, have been prepared by coprecipitation using metal nitrate precursors and Na₂CO₃. The dried precipitate catalyst precursors were characterized by X-ray diffraction (XRD) to show the presence of Cu-Al binary hydrotalcite-like phase. The dried precipitates were calcined at 873 K for 3 h. The calcined catalysts were characterized by XRD and temperature-programmed reduction (TPR) methods to show the presence of unidentified mixed oxides. The results showed that the extent of metal-support interaction increased with copper loading due to the mixed oxides formed from the hydrotalcite-type phase during calcination. High dispersion of the mixed metal oxides was indicated by comparison with similar studies on Cu-Al catalysts, prepared by similar methods, whose precursors showed no hydrotalcite formation.