Mechanically Robust,Electrically Conductive Biocomposite Films Using Antimicrobial Chitosan‐Functionalized Graphenes

An effective way of covalently functionalizing graphene with a chitosan polymer via a nitrene chemistry is demonstrated. The biofunctionalized graphene is prepared by the chemical reduction of graphene oxide using a nitrene chemistry, and then covalently grafting chitosan to the graphene surface. The effectiveness of the biofunctionalized graphene as a reinforcing filler (4 wt%) in a chitosan polymer matrix is verified by the dramatic enhancement of the mechanical properties (breaking stress = 330%, Young's modulus = 243%) and the electrical conductivity (0.3 S m^?1) without much loss in the elongation‐at‐break. The reinforcing effect can be explained by both the homogeneous dispersion of graphene within the matrix and the strong bond arising from the intrinsically intimate contact between the graphene and the matrix. The high antimicrobial activity of the biofunctionalized graphene compared with graphene oxide and chemically reduced graphene may be because of the presence of chitosan polymer on the edges of the graphene. The strong, antimicrobial graphene‐filled composite film can be used for food packaging and for coating various biomedical devices, where bacterial surface colonization is undesirable.     

Orientational disorder and geometrical isomeric effect on nonlinear optical properties of poly bis(glycine)cadmium chloride

Poly bis(glycine)cadmium chloride (BGCC) crystals of both undoped and doped with thiourea (Tu) were grown from saturated solutions by a slow evaporation technique. The geometrical isomerism of the octahedral BGCC molecule is investigated using single crystal XRD, powder XRD and FT-IR. The significant difference between the two isomers namely facial (fac) and meridional (mer), is explained in terms of the different point group symmetries of C₃ and C₁, respectively. The loss of point group symmetry from C₃ to C₁ is attributed for the observed powder second-harmonic generation (SHG). Semi-empirical calculations from the optimized geometrical parameters also supported non-linear optical properties of the material.     

Parameter-robust numerical method for a system of singularly perturbed initial value problems

In this work we study a system of M( ≥ 2) first-order singularly perturbed ordinary differential equations with given initial conditions. The leading term of each equation is multiplied by a distinct small positive parameter, which induces overlapping layers. A maximum principle does not, in general, hold for this system. It is discretized using backward Euler difference scheme for which a general convergence result is derived that allows to establish nodal convergence of O(N ^− 1ln N) on the Shishkin mesh and O(N ^− 1) on the Bakhvalov mesh, where N is the number of mesh intervals and the convergence is robust in all of the parameters. Numerical experiments are performed to support the theoretical results.     

High order robust approximations for singularly perturbed semilinear systems

In this paper, a system of M (?2) singularly perturbed semilinear reaction–diffusion equations is considered. To obtain a high order approximation to the solution of this system, we propose a hybrid numerical method that employs a generalized Shishkin mesh with the Numerov discretization in the boundary layer regions and either a non-equidistant generalization of the Numerov discretization or classical central differences in the outer region. It is proved that the method is almost fourth order convergent in the maximum norm uniformly with respect to the perturbation parameter. Numerical experiments support the theoretical results and demonstrate the effectiveness of the method.     

The influence of solar radiations to the physical and structural properties of CR-39

Long chain polymers owe many of their properties to the structural arrangements of their molecules and are extensively used for many industrial and applied sciences. One of such application is their perspective use in the field of solid-state nuclear track detectors. However they are profoundly influenced by low LET radiations exposure and new structural arrangements may emerge. CR-39 is one of the most popular polymeric track detectors, however its aliphatic nature restricts its applications. Thus in the present investigations the damage densities produced by solar radiations to the polymer have been estimated by analyzing the structural, physical and etching properties of the polymer. The polymer is found to be highly sensitive towards solar radiations and great changes in physical and structural properties of polymer have been observed. The sensitivity of the polymer has been found to decrease by 83.40% during eight months.      

Uranium analysis in some food samples collected from Bathinda area of Punjab, India

To strengthen the radiation protection infrastructure in Bathinda, the uranium concentration in daily diet of the residents has been measured and its associated radiation risks were estimated for the adult population. Food samples were collected from major cancer prone areas of the district, from which daily diets were prepared. These diet samples were analyzed using fission track technique. The measured values of the uranium content were found to vary from 0.38 mBq/g in mustard seeds to 4.60 mBq/g in wheat. In case of milk the uranium content is found to vary from 28.57–213.36 mBq/ℓ with mean concentration of 61.35 mBq/ℓ. This leads to a daily dietary intake of 0.90 Bq/day. The measured value of 0.90 Bq d⁻¹, contributes to 1.12 mSv to the cumulative effective dose to the population. This dose is much large than the International Commission for Radiological Protection (ICRP) annual effective dose limit of 1 mSv for the general public [1]. Therefore, it would pose significant health hazard.      

Atom beam sputtered Mo2C films as a diffusion barrier for copper metallization

The saddle field fast atom beam sputtered (ABS) 50 nm thick molybdenum carbide (Mo₂C) films as a diffusion barrier for copper metallization were investigated. To study the diffusion barrier properties of Mo₂C films, the as-deposited and annealed samples were characterized using four probes, X-ray diffraction, field enhanced scanning electron microscopy, energy dispersive X-ray analysis, atomic force microscopy and Rutherford back scattering techniques. The amorphous structure of the barrier films along with presence of carbon atoms at the molybdenum carbide-silicon interface is understood to reduce effective grain boundaries and responsible for increased thermal stability of Cu/Mo₂C/Si structure. The lowest resistivity of the as-deposited molybdenum carbide barrier films was ∼29 μΩ cm. The low carbon containing molybdenum carbide was found thermally stable up to 700 °C, therefore can potentially be used as a diffusion barrier for copper metallization.     

Ladder climbing on the anharmonic intermolecular potential in an amino acid microcrystal via an intense monocycle terahertz pulse

We experimentally demonstrated 20 ladder climbing steps on the anharmonic intermolecular potential in the amino-acid microcrystals with an intense monocycle terahertz pulse. Absorption spectra show the suppression of the peak and enhancement of the low-frequency absorption for the incident electric field amplitude. These results are reproduced by simulations based on coherent transition processes between quantum levels in the anharmonic potential. The appearance of such nonlinearity allows us to control macroscopic motion via a phase-controlled terahertz pulse.     

Computational framework for the prediction of transcription factor binding sites by multiple data integration

Background

Activation of extracellular signal-regulated protein kinase (ERK), a member of mitogen-activated protein kinase (MAPK) family, has been proposed to mediate neurite outgrowth-promoting effects of several neurotrophic factors in vitro. However, the precise activity of ERK during axonal regeneration in vivo remains unclear. Peripheral axotomy has been shown to activate ERK in the cell bodies of primary afferent neurons and associated satellite cells. Nevertheless, whether ERK is also activated in the axons and surrounded Schwann cells which also play a key role in the regeneration process has not been clarified.

Results

Phosphorylation of ERK in the sciatic nerve in several time-points after crush injury has been examined. Higher phosphorylation of ERK was observed in the proximal and distal nerve stumps compared to the contralateral intact nerve from one day to one month after crush. The activation of ERK was mainly localized in the axons of the proximal segments. In the distal segments, however, active ERK was predominantly found in Schwann cells forming Bungner's bands.

Conclusion

The findings indicate that ERK is activated in both the proximal and distal nerve stumps following nerve injury. The role of activated ERK in Wallerian degeneration and subsequent regeneration in vivo remains to be elucidated.     

The influence of particle shape,volume fraction and distribution on post-necking deformation and fracture in uniaxial tension of AA5754 sheet materials

Finite element analysis was performed over a small particle field, edge constraint plane strain post-necking model. The aim is to understand the roles of particle shape, volume fraction and distribution over the post-necking deformation and fracture of AA5754-O sheet materials. For models containing one single particle, the post-necking deformation decreases when the particle varies from circular to elliptical. The inter-particle spacing, the major parameter of distribution to determine whether a pair of particles belongs to a stringer or not, was varied for models with two particles of circular or elliptical shape. The general trend is that the post-necking deformation and fracture strains decrease with decreasing spacing between particles. There is considerable difference in terms of both fracture topographies and strains for models containing 16 particles when distributions varied from random/uniform to stringer distributions. The post-necking deformation and fracture strains monotonically decrease with particle volume fractions for models with 4–64 particles of random or stringer distribution. This indicates that the post-necking behavior for AA5754-O alloys where the matrix material is rather ductile is not solely controlled by a single or pair of particles although they may become initiation places of damage. Multiple damaging sources such as stringers or large particles can act cooperatively and speed up the damaging propagation of the material, and therefore produce small post-necking deformation and early fracture. The center clustering of particles can be beneficial for post-necking behavior and bendability of sheet materials.