Spin-polarized electron–electron quantum bilayers: Finite width effect

We study the effect of finite width on the ground-state of a spin-polarized electron–electron quantum bilayers (EEBL) system at temperature T=0. Correlations among carriers are treated beyond the static mean-field theories by using the quantum or dynamical version of Singwi, Tosi, Land and Sjölander (qSTLS) theory. Numerical results are presented for the pair-correlation function, the ground-state energy, the static density susceptibility, and the static local-field correction factor as a function of density parameter r_sl and interlayer spacing d. Interestingly, we find that the inclusion of finite width lowered the critical density, for the onset of Wigner crystal (WC) ground-state, as compared to the similar recent study of spin-polarized EEBL system without finite width effect. Further, spin-polarization effect is seen to introduce a marked change in the ground-state energy of the EEBL system as compared to the results of unpolarized EEBL system with finite width. Results of ground-state energies are also compared with the recent diffusion Monte Carlo (DMC) and variational Monte Carlo (VMC) simulation studies of spin-polarized EEBL system with zero width.     

A multicriteria optimization model of portfolio rebalancing with transaction costs in fuzzy environment

In this paper we propose multicriteria credibilistic framework for portfolio rebalancing (adjusting) problem with fuzzy parameters considering return, risk and liquidity as key financial criteria. The portfolio risk is characterized by a risk curve that represents each likely loss of the portfolio return and the corresponding chance of its occurrence rather than a single pre-set level of the loss. Furthermore, we consider an investment market scenario where, at the end of a typical time period, the investor would like to modify his existing portfolio by buying and/or selling assets in response to changing market conditions. We assume that the investor pays transaction costs based on incremental discount schemes associated with the buying and/or selling of assets, which are adjusted in the net return of the portfolio. A hybrid intelligent algorithm that integrates fuzzy simulation with a real-coded genetic algorithm is developed to solve the portfolio rebalancing (adjusting) problem. The proposed solution approach is useful particularly for the cases where fuzzy parameters of the problem are characterized by general functional forms.     

Can CH⋅⋅⋅π Interactions Be Used To Design Single‐Chain Magnets?

This theoretical study suggests that CH???π stacking interactions between monomeric units can be used to design novel single‐chain magnets (SCMs), as the sign of coupling is predictable and such chains inherently yield negative axial anisotropy, a condition often difficult to achieve in conventional SCMs.     

Evolution of regulatory aspects of genotoxic impurities in pharmaceuticals: Survival of the fittest

The genotoxic impurities (GIs) are carcinogenic hence its management during synthesis of pharmaceuticals is very important to be detected even in trace level for the safe use of the drugs. The presence of drug substance/drug product DNA-reactive impurities poses a significant problem for drug regulators as well as industry. There are several regulatory guidelines and position papers focused on controlling the amount of impurities within the specified limits. The present compilation gives an account of updated information about GIs and reviews the regulatory aspects for GIs in active pharmaceutical ingredients/drug formulations. A detailed discussion about control strategies in the context of GIs is also described precisely. The analysis of GIs is a challenging and complex aspect of the drug development process. Control and determination of these impurities at ppm or ppb levels are significant challenges for analysts, therefore the approaches for the analysis of GIs have also been discussed.     

High-index contrast grating based broadband out-coupler on SOI

An efficient broadband out-coupler on silicon-on-insulator (SOI) with high-index contrast grating (HCG) is proposed. The presence of a silicon-air (high-index contrast) grating on the top silicon layer in SOI allows a strong interaction between the guided mode and the grating. The broadband design of the out-coupler is presented by optimising the various grating parameters. The design analysis and simulation of such an out-coupler is performed with finite difference method. Coupling efficiency of 54% is achieved over an ultra-wide wavelength range from 1500 nm to 1650 nm.     

Design and analysis of nano-deep corrugated waveguide grating-based dual-resonant filters in visible and infra-red regions

A theoretical analysis of nano-deep corrugated long-period waveguide gratings on a SU-8 polymer-based channel waveguide with NOA61 optical epoxy coated upper- and lower cladding is presented. The transmission spectra of the gratings show strong rejection bands both at visible (at wavelength region of 450?460 nm) and infra-red (at wavelength region of 1530?1540 nm) regions when a grating period of ?68 μm with optimized grating tooth height is considered. Phase-matching graphs are studied to find the relationship between resonance wavelength and grating period. These results show that the grating parameters significantly affect the characteristics of transmission spectra as well as the resonance wavelength of the grating. Long-period waveguide grating-based band pass filter made by use of same polymer materials are also designed and analyzed. These types of waveguide grating-based filters can widely be used for visible and infra-red wavelength sensing applications.     

Design of a Hybrid Fiber-Optic Network Using 3-D Optical Code Sequences

We present the design of a 3-dimensional (3-D) noncoherent optical hybrid network. We also report the design of a new family of 3-D codes for fiber optic hybrid networks. We show that the hybrid network allows for shorter bit times and a higher number of users, given a set chip rate, compared to previously conceived networks. These newly designed hybrid single-pulse-per-row (HSPR) codes have very low autocorrelation side-lobes and very small cross-correlation peaks. We compare the performance of our hybrid model using our codes with the Optical Orthogonal Codes (OOCs) and Temporal/Spatial (T/S) codes and show that the new network can support a greater number of users and higher data rates than those using OOCs and T/S codes.     

On the general solution for a class of charged fluid spheres

We have derived all the charged fluid spheres described by a space-time with its hypersurfaces t = const. as spheroids subject to a particular form of electric field intensity. Only one out of the four solutions so obtained is reducible to its uncharged counterpart in the absence of the charge.     

Island models and the catalytic oxidation of carbon monoxide and carbon monoxide-olefin mixtures

Simple kinetic models which take account of the formation of islands of adsorbate on a catalyst surface are proposed, and are compared with an elementary step model for CO oxidation and oxidation of a CO-butene or CO-propylene mixture. The island models give fits to data from step change transient experiments which are comparable with the elementary step model, and give better fits to steady-state and continuously oscillating data (the latter with hydrocarbon present). Theoretical predictions of chaotic behaviour in CO oxidation can be obtained with the island models. Comparisons between island models suggest that islands of CO have the most significant effect on simulations at the experimental conditions.     

Crystal structure of ethyl (2Z)-2-(3-methoxy-4-acetyloxy benzylidene)-7-methyl-3-oxo-5-phenyl-2,3-dihydro-5H-[1,3]thiazolo[3,2-a]pyrimidine-6-carboxylate

The title compound, C₂₆H₂₄N₂O₆S, (I), crystallizes in the monoclinic space group, P2₁/c, with cell parameters a = 16.248(1), b = 7.927(1), c = 19.371(4) ?, β = 105.295(2)°, Z = 4. The central pyrimidine ring in the compound (I) is significantly puckered, assuming a screw-boat conformation. The C11–C16 benzene ring stands vertical while thiazole and C18–C23 benzene rings are coplanar to the mean plane of pyrimidine ring having dihedral angles of 87.48(12), 3.63(11) and 0.94(12)°, respectively. In the absence of potential hydrogen bonding interaction, the crystal packing is influenced by intramolecular C-H…S interaction and intermolecular C-H…π interactions.