全文获取类型
收费全文 | 6833篇 |
免费 | 316篇 |
国内免费 | 63篇 |
专业分类
化学 | 4725篇 |
晶体学 | 67篇 |
力学 | 265篇 |
综合类 | 2篇 |
数学 | 728篇 |
物理学 | 1425篇 |
出版年
2024年 | 37篇 |
2023年 | 82篇 |
2022年 | 501篇 |
2021年 | 438篇 |
2020年 | 293篇 |
2019年 | 271篇 |
2018年 | 277篇 |
2017年 | 227篇 |
2016年 | 323篇 |
2015年 | 254篇 |
2014年 | 283篇 |
2013年 | 510篇 |
2012年 | 425篇 |
2011年 | 480篇 |
2010年 | 278篇 |
2009年 | 250篇 |
2008年 | 265篇 |
2007年 | 272篇 |
2006年 | 196篇 |
2005年 | 187篇 |
2004年 | 114篇 |
2003年 | 125篇 |
2002年 | 122篇 |
2001年 | 89篇 |
2000年 | 63篇 |
1999年 | 65篇 |
1998年 | 34篇 |
1997年 | 31篇 |
1996年 | 51篇 |
1995年 | 47篇 |
1994年 | 29篇 |
1993年 | 37篇 |
1992年 | 37篇 |
1991年 | 43篇 |
1990年 | 21篇 |
1989年 | 26篇 |
1988年 | 33篇 |
1987年 | 30篇 |
1986年 | 29篇 |
1985年 | 42篇 |
1984年 | 25篇 |
1983年 | 25篇 |
1982年 | 24篇 |
1981年 | 14篇 |
1980年 | 29篇 |
1979年 | 23篇 |
1978年 | 28篇 |
1977年 | 28篇 |
1976年 | 21篇 |
1973年 | 12篇 |
排序方式: 共有7212条查询结果,搜索用时 15 毫秒
91.
Optogalvanic spectra of some 30 transitions of calcium originating from the ground state as well as from several excited states (4s4p 1,3P, 4s3d 1,3D, 4s5p 3P, 3d4p 3D, 3F) have been investigated using laser-irradiation of a low-current glow discharge in a thermionic diode. The influence of various experimental parameters such as bias field, oven temperature and buffer gas pressure on the spectra are reported. Seven previously unreported transitions are recorded including four forbidden transitions which violate the J selection rules. An interesting anomaly observed in the non-statistical population of the 4s3d 3D3,2,1 multiplet is discussed where the populations of 3D3:3D2:3D1 are in the ratio of 94:5:1. A possible explanation is based on avoided crossing between potential energy curves of the Ca-Ar molecule. 相似文献
92.
Expressions are obtained for the cross sections for scattering of high-energy (E
v
Mc2, where M is the nucleon mass) neutrinos and antineutrinos by free polarized nucleons with currents of the second kind taken into account. The effect of the axial-tensor form factor FT of these currents on the spin asymmetry coefficients AL and AS and on the charge asymmetry coefficient
is considered. It is shown that experimental study of the energy dependence of these coefficients can improve the accuracy of the bounds on the form factor.Russian University of the Friendship of Nations. Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 1, pp. 36–40, January, 1993. 相似文献
93.
M. Niaz Khan Jean-Pierre Fleury Philippe Baumlin Christian Hubschwerlen 《Tetrahedron》1985,41(22):5341-5345
Amides or vinylogous amides react with tosyl chloride-pyridine to form activated intermediates which condense with Fischer's base or their vinylogs to give carbocyanine structures. Under the same conditions formylated Fischer's base reacts with vinylogous Fischer's bases to give trinuclear carbocyanines in good yields. Their structure and the limitations of this route are discussed. 相似文献
94.
Dillmore WS Yousaf MN Mrksich M 《Langmuir : the ACS journal of surfaces and colloids》2004,20(17):7223-7231
This work describes a chemically well defined method for patterning ligands to self-assembled monolayers (SAMs) of alkanethiolates on gold. This method begins with monolayers presenting a nitroveratryloxycarbonyl (NVOC)-protected hydroquinone which is photochemically irradiated to reveal a hydroquinone group. The resulting hydroquinone is then oxidized to the corresponding benzoquinone, providing a site for the Diels-Alder mediated immobilization of ligands. The rate constant for the photochemical deprotection is 0.032 s(-1) (with an intensity of approximately 100 mW/cm(2) between 355 and 375 nm), corresponding to a half-life of 21 s. The hydroquinone is oxidized to the benzoquinone using either electrochemical or chemical oxidation and then functionalized by reaction with a cyclopentadiene-tagged ligand. Two methods for patterning the immobilization of ligands are described. In the first, the substrate is illuminated through a mask to generate a pattern of hydroquinone groups, which are elaborated with ligands. In the second method, an optical microscope fit with a programmable translational stage is used to write patterns of deprotection which are then again elaborated with ligands. This technique is characterized by the use of well-defined chemical reactions to control the regions and densities of ligand immobilization and will be important for a range of applications that require patterned ligands for biospecific interactions. 相似文献
95.
Usnic acid, a lichen substance, has a wide range of pharmaceutical applications, including antibiotic, antimycotic, antifeedant, antitubercular, antitumor, and analgesic activities. Some products containing usnic acid are marketed as weight control supplements; however, hepatotoxicity and acute liver failures were reported as severe side effects. The usnic acid content present in the plant materials and market products was analyzed by reversed-phase high-pressure liquid chromatography with a photodiode array detector at 233 nm. A Waters XTerra RP18 (150 x 4.6 mm; 5 microm particle size) column was the stationary phase; mobile phase was aqueous 0.1% acetic acid and acetonitrile gradient at flow rate of 1.0 mL/min. The temperature was held constant at 30 degrees C. The retention time of usnic acid was approximately 13.3 min. Acetone extraction of the samples took place with sonication. The precision of the method was confirmed by a standard deviation below 3.0% (n=3) and usnic acid recovery was 99.0%. Limit of detection was 0.4 microg/mL and the response was linear from 1.4 to 570.0 microg/mL with a correlation coefficient (R2) of 0.9991. The content of usnic acid in 4 raw materials and 22 finished products was analyzed. 相似文献
96.
Fused pyrazolopyrimidines. I. Pyrazolo[4,3-e]-v-triazolo[1,5-a]pyrimidine. A new heterocyclic system
Misbahul Ain Khan Antonio Carlos Carreira Freitas 《Journal of heterocyclic chemistry》1980,17(7):1603-1604
5-Azido-4-cyano-1-phenylpyrazole reacts with benzylcyanide in the presence of sodium methoxide to give the title ring system. 相似文献
97.
R. I. Kureshy N. H. Khan S. H. R. Abdi P. Iyer A. K. Bhatt 《Journal of molecular catalysis. A, Chemical》1997,120(1-3):101-108
A series of new dissymmetric chiral Schiff base complexes has been obtained by a systematic condensation of (1S,2S)(+)-diaminocyclohexane and 3-acetyl-4-hydroxy-6-methyl-2-pyrone with salicylaldehyde, 5-chloro-, 5-methoxy-and 5-nitrosalicylaldehyde and by subsequent metallation with manganese and ruthenium. The characterization of the complexes 1–8 was accomplished by physico chemical studies viz. microanalysis, IR-, UV/VIS-, and CD spectral studies, optical rotation, molar conductance measurements and cyclic voltammetry. Enantioselective epoxidation of non functionalised olefins, viz. cis-stilbene, trans-3-nonene and trans-4-octene with iodosyl benzene as oxidant was demonstrated in the presence of catalytic amounts of chiral Mn(III) and Ru(III) dissymmetric Schiff base complexes. Good optical yields of epoxides were obtained for the catalyst 4 with the substrates trans-3-nonene and cis-stilbene. 相似文献
98.
99.
JPC – Journal of Planar Chromatography – Modern TLC - 相似文献
100.
The effect of addition of sodium anthranilate to 5 mM micellar solutions of gemini surfactant 1,4-bis(N-hexadecyl-N,N-dimethylammonium)butane dibromide is investigated by 1H NMR. The solubilization site of anthranilate anion near the micellar surface is inferred. In the micelles, the An− ions intercalate among the surfactant headgroups producing morphological changes. 相似文献