首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   3153篇
  免费   187篇
  国内免费   43篇
化学   2253篇
晶体学   35篇
力学   124篇
综合类   2篇
数学   362篇
物理学   607篇
  2024年   38篇
  2023年   64篇
  2022年   354篇
  2021年   298篇
  2020年   179篇
  2019年   168篇
  2018年   148篇
  2017年   124篇
  2016年   196篇
  2015年   128篇
  2014年   139篇
  2013年   239篇
  2012年   209篇
  2011年   238篇
  2010年   132篇
  2009年   113篇
  2008年   128篇
  2007年   111篇
  2006年   77篇
  2005年   62篇
  2004年   37篇
  2003年   35篇
  2002年   34篇
  2001年   13篇
  2000年   12篇
  1999年   6篇
  1998年   9篇
  1997年   5篇
  1996年   8篇
  1995年   10篇
  1994年   3篇
  1993年   5篇
  1992年   3篇
  1991年   3篇
  1989年   6篇
  1988年   5篇
  1987年   4篇
  1986年   5篇
  1985年   4篇
  1984年   2篇
  1983年   2篇
  1982年   2篇
  1981年   3篇
  1979年   2篇
  1976年   3篇
  1973年   2篇
  1971年   2篇
  1969年   2篇
  1968年   3篇
  1964年   1篇
排序方式: 共有3383条查询结果,搜索用时 0 毫秒
71.
Journal of Thermal Analysis and Calorimetry -  相似文献   
72.
Journal of Thermal Analysis and Calorimetry - The purpose of this study is to measure and document the maximum level of broadband radiofrequency electromagnetic radiations in the vicinity of...  相似文献   
73.
Journal of Thermal Analysis and Calorimetry - A numerical model is developed to study the effects of temperature-dependent viscosity on heat transfer in magnetohydrodynamic flow of micropolar fluid...  相似文献   
74.
The simple and effective method for the novel synthesis of Pt-based nanoparticle was presented with high efficiency. The sensitive catalyst for the simultaneous detection of catechol and hydroquinone was prepared by depositing ternary metal complex on fluorine-doped tin-oxide (FTO). The composition and morphology of nanomaterials were characterized by TEM, HRTEM, XRD, XPS, and EDS (energy dispersive spectroscopy). The size of the Pt-based nanomaterial was about 5±1 nm. The electrochemical performance of the modified catalyst was studied by CV, DPV, and EIS. The modified PtNiCu@FTO catalyst possessed good electro-oxidation activity for hydroquinone and catechol and used for simultaneous detection of catechol and hydroquinone at scan rate of 20 mV s−1 (vs. Ag/AgCl). Detection responses were found in the ranges of 5–2900 μM for hydroquinone and 5–3000 μM for catechol. The detection limits (LOD) for HQ and CC were observed as 0.35 and 0.29 μM, respectively. The sensitivity of HQ and CC were 1515.55 and 1485 μA mM−1 cm−2, respectively. The prepared nanomaterial were effectively applied for the determination of CC and HQ in real samples.  相似文献   
75.
Journal of Thermal Analysis and Calorimetry - High heat generation from electronic devices needs to cool down properly to prevent overheating. Loop heat pipe (LHP) is one of the excellent cooling...  相似文献   
76.
77.
Dopamine (DA) is an important neurotransmitter, which is created and released from the central nervous system. It plays a crucial role in human activities, like cognition, emotions, and response to anything. Maladjustment of DA in human blood serum results in different neural diseases, like Parkinson's and Schizophrenia. Consequently, researchers have started working on DA detection in blood serum, which is undoubtedly a hot research area. Electrochemical sensing techniques are more promising to detect DA in real samples. However, utilizing conventional electrodes for selective determination of DA encounters numerous problems due to the coexistence of other materials, such as uric acid and ascorbic acid, which have an oxidation potential close to DA. To overcome such problems, researchers have put their focus on the modification of bare electrodes. The aim of this review is to present recent advances in modifications of most used bare electrodes with carbonaceous materials, especially graphene, its derivatives, and carbon nanotubes, for electrochemical detection of DA. A brief discussion about the mechanistic phenomena at the electrode interface has also been included in this review.  相似文献   
78.
The central idea of this paper is to construct a new mechanism for the solution of Abel’s type singular integral equations that is to say the two-step Laplace decomposition algorithm. The two-step Laplace decomposition algorithm (TSLDA) is an innovative adjustment in the Laplace decomposition algorithm (LDA) and makes the calculation much simpler. In this piece of writing, we merge the Laplace transform and decomposition method and present a novel move toward solving Abel’s singular integral equations.  相似文献   
79.
Journal of Radioanalytical and Nuclear Chemistry - We measured excitation functions for the production of the 108m,108g,109g,110m,110g,111gIn, the 109g,111mCd, and the 105g,106m,110m,111gAg in...  相似文献   
80.
ABSTRACT: BACKGROUND: Pyrethroids are widely used for the control of pests and insects, as pyrethroids are believed to pose very little risk to human health and environment. However, exposure to the pyrethroids exceeding the label directions might adversely affect human health and environment. Hence a careful selection of environment friendly household product is required that must contain exactly the label claimed pyrethroids amount. RESULTS: A sensitive and robust TLC-densitometric method for simultaneous quantification of commonly used synthetic pyrethroids including esbiothrin, alpha-cypermethrin and cis/trans permethrin in agricultural and domestic products has been developed and validated. TLC aluminum plates, precoated with 0.2 mm thick layer of silica gel 60 F-254, were used for chromatographic process. Densitometric analysis of chromatoplates was carried out in absorbance mode at corresponding lamdamax of each pyrethroid. Equally valid common mobile phase for all pyrethroids consisted of hexane-dichloromethane-ethylacetate-formic acid (8:1.5:0.4:0.1 v/v/v/v) which provided sharp and symmetrical peaks of esbiothrin, alpha-cypermethrin, trans-permethrin and cis-permethrin, at Rf 0.31, 0.53, 0.6 and 0.65, respectively. Linear regression data for respective calibration curves showed a good linearity for all pyrethroids with r = 0.991-0.996. Limits of detection (LOD) and limits of quantification (LOQ) for all pyrethroids were found in the range of 1.6-2.8 and 4.9-8.5 ng/spot, respectively. CONCLUSIONS: The developed method is applicable for separating the mixture of pyrethroids and at the same time, it is also valid for separating their isomers. The method is reproducible, precise and accurate for the quantitative determination of pyrethroids in agricultural and domestic products.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号