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921.
922.
923.
The absolute from Zataria multiflora was explored for enzyme inhibition, insect repellent, and insecticidal activities. GC-MS of the absolute of fresh plant showed that thymol is the major constituent while carvacrol is the major constituent in the absolute of dried plant. 相似文献
924.
Iqbal K Malik A Mukhtar N Anis I Khan SN Choudhary MI 《Chemical & pharmaceutical bulletin》2004,52(7):785-789
Three C-alkylated flavonoids 7-O-alpha-D-glucopyranosyl-3,5-dihydroxy-3'-(4"-acetoxyl-3"-methylbutyl)-6,4'-dimethoxyflavone (1), 7-O-alpha-D-glucopyranosyl-3,4'-dihydroxy-3'-(4"-acetoxyl-3"-methylbutyl)-5,6-dimethoxyflavone (2), 3,7,4'-trihydroxy-3'-(8"-acetoxy-7"-methyloctyl)-5,6-dimethoxyflavone (3) and a trans-clerodane type diterpenoid (-)-6beta-hydroxy-5beta,8beta,9beta,10alpha-cleroda-3,13-dien-16,15-olid-18-oic acid (4) are reported from Duranta repens along with (+)-hardwickiic acid (5) and (+)-3,13-clerodadien-16,15-olid-18-oic acid (6), isolated for the first time from this species. Their structures were established on the basis of the spectral methods, especially two dimensional (2D) NMR spectroscopy. 相似文献
925.
The ethyl acetate soluble part of the chloroform extract of Pulicaria gnaphalodes belonging to the family Asteraceae afforded a new sesquiterpene-dimer of guaiane class named as gnapholide and anabsinthin of the same skeleton. The structures of both the compounds were elucidated with the aid of spectroscopic techniques including 2D NMR. 相似文献
926.
A new triterpene named as alysinol 3alpha, 22beta-dihydroxyolean-12-ene [structure: see text] along with known compounds usnic acid, methyl 2,4-dihydroxy-3,6-dimethyl benzoate, 3-hydroxy benzoic acid, stigmasterol, poriferasterol and ursolic acid have been isolated from Alysicarpus monolifer. The structure of [structure: see text] has been established through spectroscopic techniques. 相似文献
927.
We have developed an accurate and highly efficient method for upscaling and simulation of immiscible displacements in three-dimensional
(3D) heterogeneous reservoirs, which is an extension of the technique that we developed previously for 2D systems. The method
utilizes wavelet transformations (WTs) to upscale the geological model of a reservoir, based on the spatial distribution of
the single-phase permeabilities and the locations of the wells in the reservoir. It generates a non-uniform grid in which
the resolved structure of the fine grid around the wells, as well as in the high-permeability sectors, are preserved, but
the rest of the grid is upscaled. A robust uplayering procedure is used to reduce the number of the layers, and the WTs are
used to upscale each layer areally. To demonstrate the method’s accuracy and efficiency, we have applied it to the geological
model of a highly heterogeneous reservoir put forward in the tenth Society of Petroleum Engineers comparative solution project
(the SPE-10 model), and carried out simulation of waterflooding in the upscaled model. Various upscaling scenarios were examined,
and although some of them resulted in efficient simulations and accurate predictions, the results when non-uniform upscaling
is used based on the WT technique are in excellent agreement with the solution of the same problem in the fine grid of the
SPE-10 model. Most importantly, the speed-up factors that we obtain are several orders of magnitude. Hence, the method renders
it unnecessary to use massively parallel computations for such problems. 相似文献
928.
929.
Saeed‐ur‐Rehman Muhammad Arshad Masood Ahmad Khalid Masud Abdul Ghani Nasima Arshad Ammad Hussain Qureshi Sohail Akhtar Ghauri 《中国化学会会志》2000,47(3):501-508
Some of the bis‐complexes of a derivative of phenhomazine (dibenzo[b,f][1:5]diazocine‐6:12‐dione; PHZD) with Ni(II), Cu(II), Co(II), Cd(II), Zn(II) and Hg(II) of the general formula M(PHZD)2X2 [where X = C1, Br and I], were prepared and identified. These complexes have been characterised on the basis of elemental analysis, and spectroscopic, magnetic and conductance data. The thermal mode of decomposition and thermal stability of these complexes was investigated on the basis of the respective thermal curves in a static air atmosphere. The thermoanalytical investigations indicate that these complexes undergo two‐step changes as temperature is raised, except for Cd(II) and Hg(II) complexes, with the formation of metal oxides as end product. The degradation mechanism of the complexes has also been proposed. 相似文献
930.
Bilal Akram Dr. Wenxiong Shi Hao Zhang Shaheed Ullah Muhammad Khurram Prof. Dr. Xun Wang 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(22):8575-8579
A single-step solution-based strategy is used to obtain 2D Janus-like free-standing ultrathin nanosheets build from two structurally unrelated species, that is, polyoxomolybdate (POM) and CoO. A controlled 2D-to-1D morphological transition was achieved by judiciously adjusting the solvent choice. These POM-CoO heterostructures can behave as an ideal catalyst for the epoxidation of styrene. Benefiting from their amphiphilic nature, these 2D POM-CoO nanosheets have also been used as surfactant to emulsify immiscible solvents. It is anticipated that structurally diverse polyoxometalates will offer promise as design elements for variety of structurally and compositionally tunable van der Waals integrated heteromaterials having a broad range applications. 相似文献