Aggregation and microenvironmental properties of gemini and conventional mixed surfactants systems: A fluorometric study

Aggregation behavior of cationic gemini (hexanediyl-1,5-bis(dimethylcettylammonium bromide) (16-5-16)) surfactant with conventional single chain surfactants cetyltrimethylammonium bromide (CTAB) and tetradecyltrimethylammonium bromide (TTAB) were studied with the help of fluorescence measurements. Fluorescence probe is a proficient technique for examining the surfactant-surfactant interaction and aggregation. The micelle aggregation number (N _agg) was measured using steady-state fluorescence quenching method. The micelle aggregation numbers of binary combinations fall between those of constituent surfactants. The micropolarity (I ₁/I ₃), binding constant (K _sv) and dielectric constant (D _exp) of mixed systems were determined from the ratio of peaks intensity in the pyrene fluorescence spectrum. The I ₁/I ₃ values were found to be more than >1, showing more polar environment around pyrene in the mixed micelle as compared to the pure micelles.     

The Smart 2-(2-Fluorobenzoyl)-N-(2-Methoxyphenyl)Hydrazinecarbothioamide Functionalized as Ni(II) Sensor in Micromolar Concentration Level and its Application in Live Cell Imaging

In recent years, fluorescent probes for the detection of environmentally and biologically important metal cations have received extensive attention for designing and development of fluorescent chemosensors. Herein, we report the photophysical results of 2-(2-fluorobenzoyl)-N-(2-methoxyphenyl) hydrazinecarbothioamide (4) functionalized as Ni (II) sensor in micromolar concentration level. Through fluorescence titration at 488 nm, we were confirmed that ligand 4 showed the remarkable emission by complexation between 4 and Ni (II) while it appeared no emission in case of the competitive ions (Cr³⁺, Fe²⁺, Co²⁺, Ba²⁺, Cu²⁺, Ca²⁺, Na⁺, K⁺, Cu⁺, Cs⁺). Furthermore, ligand 4 exhibited no toxicity with precise cell permeability toward normal living cells using L929 cell lines in bio imaging experiment investigated through confocal fluorescence microscope. The non-toxic behavior of ligand 4 (assessed by MTT assay) and its ability to track the Ni²⁺ in living cells suggest its possibility to use in biological system as nickel sensor.

Cascade-exciton model analysis of level density parameter dependence in proton induced fission cross sections of some sub-actinide nuclei

Fission cross sections strongly depend on the ratio of the level density parameter in fission to neutron emission, a_f/a_n. In this work, a cascade-exciton model implemented in the code CEM95 has been used to observe this effect for proton induced fission cross sections of tungsten, lead and bismuth. The method was employed using different level density parameter ratios for each fission cross section calculation. The calculated fission cross sections are compared with the available experimental data in the literature. It has been observed that a change of the ratio of the level density parameter, a_f/a_n, is necessary with the incident energy of the proton, to best estimate the fission cross sections in CEM95.     

Analytical and semi-analytical solutions to flows of two immiscible Maxwell fluids between moving plates

Unsteady flows of two immiscible Maxwell fluids in a rectangular channel bounded by two moving parallel plates are studied. The fluid motion is generated by a time-dependent pressure gradient and by the translational motions of the channel walls in their planes. Analytical solutions for velocity and shear stress fields have been obtained by using the Laplace transform coupled with the finite sine-Fourier transform. These analytical solutions are new in the literature and the method developed in this paper can be generalized to unsteady flows of n-layers of immiscible fluids. By using the Laplace transform and classical method for ordinary differential equations, the second form of the Laplace transforms of velocity and shear stress are determined. For the numerical Laplace inversion, two accuracy numerical algorithms, namely the Talbot algorithm and the improved Talbot algorithm are used.     

Influence of thermophoretic diffusion of nanoparticles with Joule heating in flow of Maxwell nanofluid

The aspects of activation energy in magnetized Maxwell nanofluid flow with Brownian movement and thermophoretic diffusion have been elaborated here. Furthermore, Joule heating, variable conductivity and chemical reaction are scrutinized. The Buongiorno nanofluid thought is ratify to incorporate the importance of thermophoretic and Brownian diffusion. The attained ODEs have been solved via homotopic algorithm. The performance of operational variables is inspected. The Maxwell temperature field for Eckert number and variable conductivity factor have similar trend. The fluid concentration exaggerates for activation energy and decelerates for Brownian motion parameter. Furthermore, the brilliant outcomes attained and associated with possible existing prose accurately.     

Harmonic and intermodulation performance of hearing aids under large sound pressure levels

A mathematical model for the input-output functions of the hearing aids is presented. The model, basically a sine-series function, can easily yield closed-form expressions for the amplitudes of the harmonic and intermodulation components of the output when the input is formed of multitone large sound pressure levels. The special case of two-tone equal-amplitude incident pressure level is considered in detail. The results show that the third-order intermodulation component is always higher than the third-harmonic component. The results also show that the input-output functions exhibiting peak clipping exhibit the worst harmonic and intermodulation performance for large sound pressure levels. The simple wide-dynamic range compression (WDRC) input-output function exhibits the best harmonic and intermodulation distortion performance under large sound pressure levels. These results are consistent with the previously reported observations and reveal that there is a correlation between intelligibility of high-level speech and the harmonic and intermodulation performance of the hearing aid under large sound pressure levels.     

Estimation of the Reliability of a Stress–Strength System from Poisson Half Logistic Distribution

This paper discussed the estimation of stress-strength reliability parameter R=P(Y<X) based on complete samples when the stress-strength are two independent Poisson half logistic random variables (PHLD). We have addressed the estimation of R in the general case and when the scale parameter is common. The classical and Bayesian estimation (BE) techniques of R are studied. The maximum likelihood estimator (MLE) and its asymptotic distributions are obtained; an approximate asymptotic confidence interval of R is computed using the asymptotic distribution. The non-parametric percentile bootstrap and student’s bootstrap confidence interval of R are discussed. The Bayes estimators of R are computed using a gamma prior and discussed under various loss functions such as the square error loss function (SEL), absolute error loss function (AEL), linear exponential error loss function (LINEX), generalized entropy error loss function (GEL) and maximum a posteriori (MAP). The Metropolis–Hastings algorithm is used to estimate the posterior distributions of the estimators of R. The highest posterior density (HPD) credible interval is constructed based on the SEL. Monte Carlo simulations are used to numerically analyze the performance of the MLE and Bayes estimators, the results were quite satisfactory based on their mean square error (MSE) and confidence interval. Finally, we used two real data studies to demonstrate the performance of the proposed estimation techniques in practice and to illustrate how PHLD is a good candidate in reliability studies.     

Zn-Co bimetallic supported ZSM-5 catalyst for phosgene-free synthesis of hexamethylene–1,6–diisocyanate by thermal decomposition of hexamethylene–1,6–dicarbamate

A set of mono-and bimetallic(Zn-Co) supported ZSM-5 catalysts was first prepared by PEG-additive method. The physicochemical properties of the catalysts were investigated by FTIR, XPS, XRD, N_2adsorption-desorption measurements, SEM, EDS and NH3-TPD techniques. The physicochemical properties showed that the Zn Co_2O_4 spinel oxide was formed on the ZSM-5 support and provided effectual synergetic effect between Zn and Co species for the bimetallic catalyst. Furthermore, bimetallic supported ZSM-5 catalyst exhibited weak, moderate and strong acidic sites, while the monometallic supported ZSM-5 catalyst showed only weak and moderate or strong acidic sites. Their catalytic performances for thermal decomposition of hexamethylene–1,6–dicarbamate(HDC) to hexamethylene–1,6–diisocyanate(HDI) were then studied. It was found that the bimetallic supported ZSM-5 catalysts,especially Zn-2Co/ZSM-5 catalyst showed excellent catalytic performance due to the good synergetic effect between Co and Zn species, which provided a suitable contribution of acidic sites. HDC conversion of 100% with HDI selectivity of 91.2% and by-products selectivity of 1.3% could be achieved within short reaction time of 2.5 h over Zn-2Co/ZSM-5 catalyst.     

Efficiency analysis of thermosyphon solar flat plate collector with low mass concentrations of ND–Co3O4 hybrid nanofluids: an experimental study

Journal of Thermal Analysis and Calorimetry - In the present study, the thermal efficiency, convective heat transfer and friction factor analysis are investigated for a flat plate solar collector...