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11.
ZnO-ZnF2-B2O3 glasses containing small concentrations of TiO2 ranging from 0 to 0.6 mol% were prepared. Dielectric properties (constant ε′, loss tan δ, ac conductivity σac over a moderately wide range of frequency and temperature at room temperature in air medium) of these glasses have been studied. The results of these studies were analyzed with the aid of data on optical absorption, ESR and IR spectra of these glasses. The analysis suggests that when the concentration of TiO2>0.2 mol%, the titanium ions, in addition to Ti4+ state, co-exist in Ti3+ state, act as modifiers and reduce the breakdown strength. 相似文献
12.
A. Bharathi S. Jemima Balaselvi S. Kalavathi G. L. N. Reddy V. Sankara Sastry Y. Hariharan T. S. Radhakrishnan 《Physica C: Superconductivity and its Applications》2002,370(4):211-218
Successful replacement of B by C in the series MgB2−xCx for values of x upto 0.3 is reported. Resistivity and ac susceptibility measurements have been carried out in the samples. Solubility of carbon, inferred from the observed change in the lattice parameter with carbon content indicates that carbon substitutes upto x=0.30 into the MgB2 lattice. The superconducting transition temperature, Tc measured both by zero resistivity and the onset of the diamagnetic signal shows a systematic decrease with increase in carbon content upto x=0.30, beyond which the volume fraction decreases drastically. The temperature dependence of resistivity in the normal state fits to the Bloch–Gruneisen formula for all the carbon compositions studied. The Debye temperature, θD, extracted from the fit, is seen to decrease with carbon content from 900 to 525 K, whereas the electron–phonon interaction parameter, λ, obtained from the McMillan equation using the measured Tc and θD, is seen to increase monotonically from 0.8 in MgB2 to 0.9 in the x=0.50 sample. The ratio of the resistivities between 300 and 40 K versus Tc is seen to follow the Testardi correlation for the C substituted samples. The decrease in Tc is argued to mainly arise due to large decrease in θD with C concentration and a decrease in the hole density of states at N(EF). 相似文献
13.
G A V Ramanamurthy K Ramachandra Rao Y Rama Krishna P Venkateswarlu K Bhaskara Rao P V Ramana Rao S Venkata Ratnam V Seshagiri Rao G J Nagaraju S Bhuloka Reddy 《Pramana》2001,56(5):697-703
The Measurement of K
β
K
/α
intensity ratios are measured in some 3d shell elements by using a 2 MeV proton beam along with a high resolution Si(Li) detector. The present Measurement of K
β
K
/α
intensity ratios are in good agreement with Scofield modified theoretical values, thus supporting the basic assumptions in
that theory. From the present Measurement of K
β
K
/α
intensity ratios, it is evident that due to chemical effects, the experimental Measurement of K
β
K
/α
intensity ratios will be increased while they will be decreased due to the presence of simultaneous M-shell vacancies which are produced due to proton excitation. 相似文献
14.
Orientational order parameter S is evaluated in the nematic phase of six liquid crystal compounds, N-(p-n-propyl benzylidene)-p-n-alkoxy anilines, 3.Om and N-(p-n-propyloxy benzylidene)-p-n-alkoxy anilines, 3O.Om compounds with m = 6, 7 and 8, using different methods. The techniques employed are S from birefringence δn, Haller's approximation from (1?T/Tc) β, effective geometry parameter αg and Vuks’ scaling factor SC. The values of S obtained using the above methods are compared with one another and with the results on a number of liquid crystals; the liquid crystals favor isotropic Vuks’ method. 相似文献
15.
Ning Zhang Zhongquan Zheng Steven Eckels Venkata B. Nadella Xiaoyang Sun 《Particle & Particle Systems Characterization》2009,26(4):199-209
We inject a large number of newly created nano‐particle aggregates into a chamber for the purpose of removing harmful contents in an indoor environment. This study is to experimentally and numerically investigate transient response of particle distributions to particle injections. A room‐sized chamber of 4 m × 2.1 m × 2.4 m is connected to a specially designed particle‐injection system, with two Optical Particle Counters used to simultaneously measure particle‐number densities with the size range from 0.3 μm to 10 μm at the inlet and in the chamber. A velocity probe measures the flow that is up to 1 m/s. An Euler‐type particulate‐phase‐transport model is developed and validated by comparing with experimental data. The study shows that the transient behavior of particle distributions is determined by many factors, including particle size, particle settling speed, sampling location, and velocity distribution. Particle number densities decrease in time more quickly for large particles than for small particles, and locations farther downstream in the chamber correlate more weakly with the inlet injection. 相似文献
16.
N K Porwal R M Kadam Y Babu M D Sastry M D Aggarwal Putcha Venkateswarlu 《Pramana》1997,48(4):929-935
Photo-induced charge transfer and its kinetics were investigated in Bi12SiO20 in 10–300 K temperature range, using EPR of Fe3+ centre, underin situ illumination with copper vapour laser (CVL). The decay kinetics was found to follow double exponential behaviour. Relaxation
of the photo-induced electron transfer to the preillumination condition occurred even at 10 K. Shallow traps were, therefore,
associated with the electron trapping, leading to a better understanding of the fast photorefractive response of BSO. 相似文献
17.
S. Kalavathi J. Janaki Awadhesh Mani V. Sankara Sastry 《Solid State Communications》2006,139(7):334-338
Some new members of a ruthenocuprate(2212) series have been synthesized by Mn substitution for Ru in Gd1.4Ce0.6Sr2RuCu2O10. Characterization by x-ray diffraction (XRD) phase analysis has been carried out. Changes in structural features on substitution, including a significant change in lattice parameter for a very low substitution level, have been observed. Four-probe resistivity studies indicate the coexistence of superconductivity and magnetism for the pristine compound and a semiconductor-like upturn in resistivity and the absence of superconductivity even for very low levels of Mn substitution. AC susceptibility measurements show a progressive suppression of the magnetic transition temperature as well as a smearing of the magnetic transition as a function of Mn substitution. Possible reasons for the absence of superconductivity have been discussed. 相似文献
18.
P. Saravanan G. Venkata RamanaK. Srinivasa Rao B. SreedharV.T.P. Vinod V. Chandrasekaran 《Journal of magnetism and magnetic materials》2011,323(15):2083-2089
Self-assembled Sm-Co nanoparticles in the form of spherical aggregates (referred as nanospheres) with diameter ranging from 50 to 180 nm were achieved by means of polyol technique. The size distribution of the Sm-Co nanospheres can be regulated close to ∼100 nm by controlling the molar ratio of Sm:Co precursor. The spherical aggregates exhibited Sm2Co7 phase as a major constituent; while the aggregates obtained at higher Co concentration showed co-existence of Co-phase with Sm2Co7 phase. Upon annealing, the biphasic nature of nanospheres (Sm2Co7/Co) transformed into Sm2Co17 structure. By varying the Sm:Co precursor ratio from 1:5 to 1:9, the coercivity (Hc) and magnetization (Ms) values of the as-synthesized nanospheres can be tuned from 336 to 140 Oe and from 63.7 to 108 emu/g, respectively, and these values significantly improved after annealing. Maximum values of Hc (1050 Oe) at the Sm:Co molar ratio of 1:5 and Ms of 184.6 emu/g at the Sm:Co molar ratio of 1:9 were achieved in the annealed samples. 相似文献
19.
T. Raghavendra RaoCh. Rama Krishna U.S. Udayachandran ThampyCh. Venkata Reddy Y.P. ReddyP. Sambasiva Rao R.V.S.S.N. Ravikumar 《Physica B: Condensed Matter》2011,406(11):2132-2137
The effect of Li2O content in vanadyl doped 20ZnO+xLi2O+(30−x)Na2O+50B2O3 (5≤x≥25) glasses has been studied with respect to their physical and structural properties. The absence of sharp peaks in XRD spectra of these glass samples confirms the amorphous nature. The physical parameters like density, refractive index, ionic concentration and electronic polarizability vary non-linearly with x mol% depending on the diffusivities of alkali ions. EPR and optical absorption spectra reveal that the resonance signals are characteristics of VO2+ ions in tetragonally compressed octahedral site. Spin-Hamiltonian, crystal field, tetragonal field and bonding parameters are found to be in good agreement with the other reported glass systems. The tetragonal distortion (g⊥-g∥) and Dt reveals that their values vary non-linearly with Li2O content and reaches a minimum at x=10 mol%. An anomaly of character has been observed in all the properties of vanadyl doped glass systems, which gives a clear indication of mixed alkali effect. 相似文献
20.
P. NareshG. Naga Raju Ch. Srinivasa RaoS.V.G.V.A. Prasad V. Ravi KumarN. Veeraiah 《Physica B: Condensed Matter》2012,407(4):712-718
The glasses of the composition 10ZnO-30ZnF2-60B2O3 doped with different concentrations of CoO were prepared. Differential scanning calorimetric (DSC) studies, optical absorption, photoluminescence and infrared spectra of these glasses have been carried out. DSC studies have indicated that the resistance of the glass against devitrification increases with the increase in the concentration of CoO. Optical absorption spectra have exhibited one octahedral band due to 4T1g(F)→2T1g(H) and two tetrahedral bands due to 4A2(4F)→4T1(4P) 4A2(4F)→4T1(4F) transitions of Co2+ ions at about 525, 570 and 1400 nm, respectively. As the concentration of CoO is increased the tetrahedral bands are observed to grow at the expense of octahedral band. The luminescence spectra have exhibited two emission bands in the spectral regions of 600-700 nm and 800-900 nm due to 4T1(4P)→4A2(4F) and 4T1(4P)→4T2(4F) tetrahedral transitions of Co2+ ions, respectively. With the increasing content of cobalt ions in the glass matrix, the half width and intensity of these bands are observed to increase. The analysis of the results of these two spectra coupled with IR spectra has indicated that as the concentration of CoO is increased in the glass matrix, the tetrahedral occupancy of cobalt ions dominates over the octahedral occupancy and increase the rigidity of the glass network. 相似文献