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21.
Thermogravimetric (TG) investigations of organotin(IV) carboxylates with the general formula RmSnL4−m (where R=CH3, C2H5, n‐C4H9, C6H5, cyclo‐C6H11, n‐C8H17, m=2, 3, and L=para‐nitrophenylethanoate anion) have been performed. Derivative thermogravimetry (DTG) and differential thermal analysis (DTA) techniques, Horowitz‐Metzger method and the fundamental thermodynamic relations are used to evaluate the thermokinetic parameters of each thermal degradation pattern. Results reveal that the thermal stability is functional to Sn C and Sn O bonds. In the case of R2SnL2, activation energy, reaction order and pre‐exponential factor associated with the bulk degradation processes increase as the alkane chain length increases. Hence, Oct2SnL2 is thermally more stable than Bu2SnL2, which in turn is more resistant to thermal dissociation than Et2SnL2. The same phenomenon is not observed for R3SnL compounds because their degradation is highly irregular. Furthermore, R2SnL2 has larger values of kinetic parameters than those of corresponding triorganotin(IV) para‐nitrophenylethanotes. Thermodynamic parameters of these compounds also reinforce the above facts. 相似文献
22.
Saqib Ali Syed Usman Ahmad Saira Shahzadi Sadiq‐ur‐Rehman Masood Parvez Muhammad Mazhar 《应用有机金属化学》2005,19(1):201-201
Me2Sn(S2CN(CH2)5)Cl contains five‐coordinated tin with a bidentate dithiocarbamate ligand spanning equatorial and axial positions in a distorted trigonal bipyramidal geometry. Copyright © 2005 John Wiley & Sons, Ltd. 相似文献
23.
Abstract (4-Methylpiperidine-dithiocarbamato-S,S′)triphenyltin(IV) derivative of 4-methyl-1-piperidine carbodithioic acid (4-MePCDTA) have been synthesized and characterized
by elemental, IR, multinuclear NMR (1H and 13C) and mass spectrometric studies. The crystal structure of the complex has been determined by X-ray single crystal analysis,
which shows unsymmetrical nature of the ligand towards coordination to tin. It crystallizes in monoclinic P21/c space group with the crystal cell parameters: a = 10.1863(10) ?, b = 21.200(2) ?, c = 11.7332(11) ?, β = 111.2020(10)°, Z = 4 and V = 2,362.2(4) ?3. The tin atom is coordinated to the two sulfur atoms of the dithiocarbamate ligand and three carbon atoms of the phenyl groups
are in distorted trigonal bipyramid geometry. This complex was tested for its antimicrobial activity against six different
plant and human pathogens. The screening results show that the complex exhibit higher antibacterial and antifungal activity
than the free ligand.
Index abstract
Synthesis, Spectroscopy, in vitro Biological Activity and X-Ray Structure of (4-Methylpiperidine-dithiocarbamato-S,S′)triphenyltin(IV)
Saira Shahzadi, Saqib Ali and Mohammmed Fettouhi
4-Methyl-1-piperidine carbodithioic acid behaves as anisobidentate ligand and chelates the tin atom by means of sulfur atoms
giving cis-trigonal bipyramid geometry around the tin atom.
Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users. 相似文献
24.
Saddam Saqib Wajid Zaman Fazal Ullah Imran Majeed Asma Ayaz Muhammad Farooq Hussain Munis 《应用有机金属化学》2019,33(11)
The ever‐increasing resistance of plant microbes towards fungicides and bactericides has been causing serious threat to plant production in recent years. For the development of an effective antifungal agent, we introduce a novel hydrothermal protocol for synthesis of chitosan iron oxide nanoparticles (CH‐Fe2O3 NPs) using acetate buffer of low pH 5.0 for intermolecular interaction of Fe2O3 NPs and CH. The composite structure and elemental elucidation were carried out by using X‐ray power diffraction (XRD), Scanning Electron Microscopy (SEM), Energy Dispersive X‐ray (EDX), Transmission Electron Microscopy (TEM), Fourier Transformed Infrared Spectroscopy (FTIR) and Ultraviolet Visible Absorption Spectroscopy (UV–vis spectroscopy). Additionally, antifungal activity was evaluated both In vitro and In vivo against Rhizopus oryzae which is causing fruit rot disease of strawberry. We compared different concentrations (0.25%, 0.50%, 075% and 1%) of CH‐Fe2O3 NPs and 50% synthetic fungicide (Matalyxal Mancozab) to figure out suitable concentration for application in the field. XRD analysis showed a high crystalline nature of the NPs with average size of 52 nanometer (nm). SEM images revealed spherical shape with size range of 50–70 nm, whereas, TEM also revealed spherical shape, size ranging from 0 nm to 80 nm. EDX and FTIR results revealed presence of CH on surface of Fe2O3 NPs. The band gap measurement showed peak 317–318 nm for bare Fe2O3 NPs and CH‐Fe2O3 NPs respectively. Antifungal activity in both In vitro and In vivo significantly increased with increase in concentration. The overall results revealed high synergetic antifungal potential of organometallic CH‐Fe2O3 NPs against Rhizopus oryzae and suggest the use of CH‐Fe2O3 NPs against other Phyto‐pathological diseases due to biodegradable nature. 相似文献
25.
Afif Ahmed Radenahmad Nikdalila Rahman Seikh Mohammad Habibur Torino Nico Saqib Muhammad Hossain Shahzad Park Jun-Young Azad Abul Kalam 《Journal of Solid State Electrochemistry》2022,26(1):111-120
Journal of Solid State Electrochemistry - Protonic ceramic fuel cells have become extremely interesting due to their high power output at the intermediate temperature range... 相似文献
26.
Four mononuclear copper(II) and zinc(II) complexes were synthesized by the reaction of copper and zinc salts with 3,4-dichlorophenylactic acid, 2-bromophenylactic acid, biphenylacetic acid (O-donor ligand) and bipyridine (N-donor ligands) having the general formulae [(L)2Cu(bp)(H2O)] ( 1 ), [(BpA)2Cu(bp)] ( 2 ), [(L)2Zn(bp)(H2O)] ( 3 ) and [(L*)2Zn(bp)] ( 4 ) (L = 3,4-dichlorophenylacetate, L* = 2-bromophenylacetate bp = bipyridine, and BpA = biphenylacetate). Structures of all compounds were characterized through FT-IR spectroscopy and X-ray diffraction analysis. FT-IR spectra of all complexes confirmed the binding mode of Cu-O and Zn-O. XRD data revealed that complexes 1 – 3 exhibited distorted octahedral arrangement, whereas complex 4 has a distorted tetrahedral environment. Micellization behavior was examined with anionic surfactant (SDS) by conductance measurement as well as absorption spectral analysis. DNA binding study was assessed through viscosity measurement and UV/Vis spectrophotometry. DPPH free radical scavenging assay was measured by UV/Vis spectrophotometry. The results showed nice biological potential of all the complexes. 相似文献
27.
Saira Shahzadi Saqib Ali Amin Badshah Farkhanda Shaheen Fiaz Ahmed Mohammed Fettouhi 《Journal of chemical crystallography》2006,36(9):567-570
The complex bis(4-methylpiperidine-dithiocarbamato-S,S′)-palladium(II) was synthesized by the reaction of 4-methyl-1-piperidine dithiocarbamic acid with palladium(II) chloride. Its structure was determined by X-ray crystal diffraction analysis. It crystallizes in the monoclinic P21/c space group with the crystal cell parameters a=8.6491(8) ?, b=18.7305(16) ?, c=11.9933(10) ?, β=107.074(1)°, V=1857.3(3) ?3 and Z=4. The palladium (II) ion is bonded to four sulfur atoms, belonging to two dithiocarbamate ligands, in a distorted square planar geometry. The X-ray data suggest a pronounced electronic delocalization in the two NCS2 moieties. 相似文献
28.
Muhammad Hanif Mukhtiar Hussain Moazzam H. Bhatti Saqib Ali Helen S. Evans 《Structural chemistry》2008,19(5):777-784
Four new complexes, [Ph3Sn(isopropylACDA)] (1), [Ph2SnCl(isopropylACDA)] (2), [Ph3Sn(secbutylACDA)] (3), and [Ph2SnCl(secbutylACDA)] (4), have been prepared from reaction between N-alkylated 2-amino-1-cyclopentene-1-carbodithioic acids (ACDA) with Ph2SnCl2 and Ph3SnCl in 1:1 ratio. All complexes are characterized by FTIR, multinuclear NMR (1H, 13C, and 119Sn) and mass spectrometry. In all complexes, the S–H proton has been removed and coordination takes place through the carbodithioate
moiety. The 119Sn NMR data are consistent with five coordination of tin atom in solution. Complexes 2, 3, and 4 have also been confirmed by single X-ray crystallography. All three crystals are triclinic with space group P − 1. In complexes 2 and 4, the geometry around tin atom is distorted trigonal bipyramidal while in 3 the geometry is in between distorted tetrahedral and trigonal bipyramid. In all three structures, ligands are asymmetrically
coordinated to tin atom. In addition, crystal structures are further stabilized by N–H···S hydrogen bonding. 相似文献
29.
Khalifa S. Al-Khalifa Rasha AlSheikh Moahmmed T. Al-Hariri Hosam El-Sayyad Maher S. Alqurashi Saqib Ali Amr S. Bugshan 《Molecules (Basel, Switzerland)》2021,26(21)
This study aimed to evaluate the antimicrobial effect of Thymoquinone (TQ) on four different oral microorganisms. Minimum Bactericidal Concentration (MBC), Minimum Inhibition Concentration (MIC), Broth microdilution, and Well diffusion tests were used to determine the optimum antimicrobial concentrations of TQ against Streptococcus salivarius, Streptococcus oralis, Streptococcus mutans, and Staphylococcus aureus over 1, 3, 6, 12 and 24 h. Chlorhexidine 0.12% was selected as a positive control. The inhibitory effect of TQ on bacterial growth was most noticeable with S. salivarius, while the least affected was S. aureus. TQ’s MBC and MIC for S. oralis and S. aureus were comparable 2 mg/mL and 3 mg/mL, respectively. S. salivarius was most resistant to TQ and displayed a value of 5 mg/mL and 4 mg/mL for MIC and MBC, respectively. The viable count of different strains after exposure to TQ’s MBC values was most noticeable with S. aureus followed by S. oralis and S. mutans, while S. salivarius was least affected. This study emphasized the promising antimicrobial effect of TQ against the four main oral microorganisms. It has a potential preventive effect against dental caries as well as other oral diseases. 相似文献
30.
Abida Kalsoom M. Mazhar Saqib Ali M. F. Mahon K. C. Molloy M. Iqbal Chaudry 《应用有机金属化学》1997,11(1):47-55