Development of nanostructured polyaniline dispersed smart anticorrosive composite coatings

Modern engineering science and nanotechnology have hastened the development of high performance corrosion‐resistant coatings having a broad spectrum of effectivity under a wider range of hostile environments. The formulation of such coating systems is expected to cause a major revolution in the corrosion world. Conducting polymers have recently proved to be an effective alternative to phosphate–chromate pretreatment that is hazardous due to toxic hexavalent chromium. Moreover, improvements in environmental impact can be achieved by utilizing nanostructured particulates in coating and eliminating the requirement of toxic solvents. The paper reports some preliminary investigations on the corrosion resistance performance of nanostructured methyl orange (MO)‐doped polyaniline (PANI)/castor oil polyurethane (COPU) composite coatings on mild steel (MS). The nanostructure of the MO‐PANI was confirmed by transmission electron microscopy (TEM). The corrosion protective performance was evaluated by physico‐mechanical properties, corrosion rate, and open circuit potential measurements. These coatings were found to act as “corrosion sensors” by exhibiting different colors when placed in acid as well as alkaline media. The protective behavior of coatings was attributed to the formation of a passive iron oxide/dopant layer at the metal‐coating interface that impedes the penetration of the corrosive ions. Copyright © 2008 John Wiley & Sons, Ltd.     

Janerin Induces Cell Cycle Arrest at the G2/M Phase and Promotes Apoptosis Involving the MAPK Pathway in THP-1, Leukemic Cell Line

Janerin is a cytotoxic sesquiterpene lactone that has been isolated and characterized from different species of the Centaurea genus. In this study, janerin was isolated form Centaurothamnus maximus, and its cytotoxic molecular mechanism was studied in THP-1 human leukemic cells. Janerin inhibited the proliferation of THP-1 cells in a dose-dependent manner. Janerin caused the cell cycle arrest at the G2/M phase by decreasing the CDK1/Cyclin-B complex. Subsequently, we found that janerin promoted THP-1 cell death through apoptosis as indicated by flow cytometry. Moreover, apoptosis induction was confirmed by the upregulation of Bax, cleaved PARP-1, and cleaved caspase 3 and the downregulation of an anti-apoptotic Bcl-2 biomarker. In addition, immunoblotting indicated a dose dependent upregulation of P38-MAPK and ERK1/2 phosphorylation during janerin treatment. In conclusion, we have demonstrated for the first time that janerin may be capable of inducing cell cycle arrest and apoptosis through the MAPK pathway, which would be one of the mechanisms underlying its anticancer activity. As a result, janerin has the potential to be used as a therapeutic agent for leukemia.     

Synthesis, magnetic and dielectric properties of Er-Ni doped Sr-hexaferrite nanomaterials for applications in High density recording media and microwave devices

A sol-gel combustion method has been successfully employed for the synthesis of Sr-hexaferrite nanomaterials doped with Er³⁺ and Ni²⁺ at strontium and iron sites, respectively. The X-ray diffraction analysis confirmed the single magnetoplumbite phase and the crystallite size was found to be in the range of 14-16 nm, suitable for obtaining signal-to-noise ratio in the high density recording media. The magnetic properties such as saturation magnetization (M_s), remanence (M_r) and coercivity (H_c) were calculated from hysteresis loops. M_s, M_r and H_c are observed to increase with the Er-Ni content. The dielectric constant (ε´) and dielectric loss (tan δ) is found to decrease with the increase in frequency and is explained on the basis of Maxwell-Wagner and Koops theory. The decrease in dielectric constant and dielectric loss but increase in saturation magnetization and remanence with Er-Ni content suggests that the materials are suitable for applications in microwave devices and high density recording media .     

MHD natural convective flow through a porous medium in a square cavity filled with liquid gallium

This article contains a computational study of free convective flow through a square enclosure filled with liquid gallium saturated porous medium in the presence of a uniform inclined magnetic field. Lower boundary of enclosure is considered to be heated uniformly, upper horizontal boundary is taken insulated, left wall of the cavity is heated linearly, and right wall is heated linearly or taken cold. Navier–Stokes equations governing the flow problem are first exposed to penalty method to eliminate the pressure terms and then Galerkin FEM is employed to solve reduced equations. Grid independent results are achieved and shown in tabular form for numerous ranges of physical flow parameters. To ensure the accuracy of developed code, computed results are compared with those available in earlier studies through figures. It is found that the strength of streamlines circulation is increased due to increase in Darcy number while imposition of vertical magnetic field instead of horizontal magnetic field causes slow rate of increase in strength of streamlines circulation. Whereas, in the case of linearly heated right wall, the average Nusselt number is an increasing function of the Darcy number, and vertical magnetic field causes higher values for average Nusselt number as compared to horizontal magnetic field along bottom and side walls of cavity. Contrarily, in the case of cold right wall, the horizontal magnetic field results in higher values of average Nusselt number as compared to the vertical magnetic field case, and the average Nusselt number reduces as we move along lower and right boundary while increases along left wall with increase in distance.     

Physical, electrical and dielectric properties of Ca-substituted strontium hexaferrite (SrFe12O19) nanoparticles synthesized by co-precipitation method

Calcium substituted strontium hexaferrite Ca_xSr_1−xFe₁₂O₁₉ (x=0.0−0.6) nanoparticles are synthesized by chemical co-precipitation method. The synthesized samples are characterized by Fourier Transform Infrared (FTIR), X-ray diffraction (XRD), Scanning Electron Microscopy, Transmission Electron Microscopy, DC electrical resistivity and dielectric measurements. FTIR data of uncalcined sample shows that nitrate ions are present which disappeared on calcination at 920 °C. The XRD data shows that a single hexagonal magnetoplumbite phase is formed in samples in which the calcium content, x, is ≤0.20. However, a nonmagnetic phase (α-Fe₂O₃) in addition to the hexagonal phase is also present in samples with x>0.20. The average crystallite size is found between 17 and 29 nm. The DC electrical resistivity increases with increase of calcium content up to level of x=0.2 but decreased on further addition of calcium. The enhanced resistivity of the calcium doped material has potential applications in microwave devices. The variations of dielectric constant and dielectric loss angle are explained on the basis of Maxwell-Wagner and Koops models.     

Numerical study of unsteady MHD oblique stagnation point flow and heat transfer due to an oscillating stream

The unsteady stagnation point flow impinging obliquely on a flat plate in presence of a uniform applied magnetic field due to an oscillating stream has been studied. The governing partial differential equations are transformed into dimensionless form and the stream function is expressed in terms of Hiemenz and tangential components. The dimensionless partial differential equations are solved numerically by using well-known implicit finite difference scheme named as Keller-box method. The obtained results are compared with those available in the literature. It is observed that the results are in excellent agreement with the previous studies. The effects of pertinent parameters involved in the problem namely magnetic parameter, Prandtl number and impinging angle on flow and heat transfer characteristics are illustrated through graphs. It is observed that the influence of magnetic field strength increases the fluid velocity and by the increase of obliqueness parameter, the skin friction increases.     

Applications of Raman spectroscopy in dentistry part II: Soft tissue analysis

Raman spectroscopy is rapidly moving from an experimental technique for the analysis of biological molecules to a tool for the real-time clinical diagnosis and in situ evaluation of the oral tissue in medical and dental research. The purpose of this study is to identify various applications of Raman spectroscopy, to evaluate the contemporary status, and to explore future directions in the field of dentistry. Several in-depth applications are presented to illustrate Raman spectroscopy in early diagnosis of soft tissue abnormalities. Raman spectroscopy allows researchers to analyze histological and biochemical composition of biological tissues. The technique not only demonstrates its role in the disclosure of dysplasia and malignancy, but also in performing guided biopsies, diagnosing sialoliths, and assessment of surgical margins. Raman spectroscopy is used to identify the molecular structures and their components to give substantial information about the chemical structure properties of these molecules. In this article, we acquaint the utilization of Raman spectroscopy in analyzing the soft tissues in relation to dentistry.     

Goos–Hänchen Shift from Cold and Hot Atomic Media Using Kerr Nonlinearity

We study and examine the Goos–Hänchen shifts of a propagating probe light field in a four-level tripodtype cold and hot atomic medium. The behavior of Goos–Hänchen shifts is studied in reflection and transmission beams in the presence of the coherent Kerr effect and the Doppler broadening effect. We observe that these shifts can be controlled by the relative propagation direction of the control field to that of the probe field.     

Transmitter Diversity Gain Technique Aided Irregular Channel Coding for Mobile Video Transmission

The reliable transmission of multimedia information that is coded through highly compression efficient encoders is a challenging task. This article presents the iterative convergence performance of IrRegular Convolutional Codes (IRCCs) with the aid of the multidimensional Sphere Packing (SP) modulation assisted Differential Space Time Spreading Codes (IRCC-SP-DSTS) scheme for the transmission of H.264/Advanced Video Coding (AVC) compressed video coded stream. In this article, three different regular and irregular error protection schemes are presented. In the presented Regular Error Protection (REP) scheme, all of the partitions of the video sequence are regular error protected with a rate of 3/4 IRCC. In Irregular Error Protection scheme-1 (IREP-1) the H.264/AVC partitions are prioritized as A, B & C, respectively. Whereas, in Irregular Error Protection scheme-2 (IREP-2), the H.264/AVC partitions are prioritized as B, A, and C, respectively. The performance of the iterative paradigm of an inner IRCC and outer Rate-1 Precoder is analyzed by the EXtrinsic Information Transfer (EXIT) Chart and the Quality of Experience (QoE) performance of the proposed mechanism is evaluated using the Bit Error Rate (BER) metric and Peak Signal to Noise Ratio (PSNR)-based objective quality metric. More specifically, it is concluded that the proposed IREP-2 scheme exhibits a gain of 1 dB Eb/N0 with reference to the IREP-1 and Eb/N0 gain of 0.6 dB with reference to the REP scheme over the PSNR degradation of 1 dB.     

Chemical synthesis of zinc oxide nanorods for enhanced hydrogen gas sensing

Zinc oxide(ZnO) nanorods are prepared using equimolar solution of zinc nitrate((Zn(NO3)2) and hexamethylenetetramine(C6H12N4) by the hydrothermal technique at 80 C for 12 h. Epitaxial growth is explored by X-ray diffraction(XRD) patterns, revealing that the ZnO nanorods have a hexagonal(wurtzite) structure. Absorption spectra of ZnO are measured by UV–visible spectrometer. The surface morphology is investigated by field emission scanning electron microscopy(FESEM). The synthesized ZnO nanorods are used for detecting the 150 C hydrogen gas with a concentration over 1000 ppm. The obtained results show a reversible response. The influence of operating temperature on hydrogen gas detecting characteristic of ZnO nanorods is also investigated.