全文获取类型
收费全文 | 3070篇 |
免费 | 373篇 |
国内免费 | 222篇 |
专业分类
化学 | 2083篇 |
晶体学 | 43篇 |
力学 | 109篇 |
综合类 | 8篇 |
数学 | 415篇 |
物理学 | 1007篇 |
出版年
2024年 | 6篇 |
2023年 | 40篇 |
2022年 | 69篇 |
2021年 | 95篇 |
2020年 | 111篇 |
2019年 | 103篇 |
2018年 | 92篇 |
2017年 | 84篇 |
2016年 | 129篇 |
2015年 | 160篇 |
2014年 | 143篇 |
2013年 | 260篇 |
2012年 | 270篇 |
2011年 | 273篇 |
2010年 | 162篇 |
2009年 | 150篇 |
2008年 | 194篇 |
2007年 | 186篇 |
2006年 | 139篇 |
2005年 | 135篇 |
2004年 | 91篇 |
2003年 | 110篇 |
2002年 | 72篇 |
2001年 | 76篇 |
2000年 | 60篇 |
1999年 | 49篇 |
1998年 | 46篇 |
1997年 | 36篇 |
1996年 | 46篇 |
1995年 | 30篇 |
1994年 | 36篇 |
1993年 | 36篇 |
1992年 | 24篇 |
1991年 | 24篇 |
1990年 | 10篇 |
1989年 | 27篇 |
1988年 | 15篇 |
1987年 | 9篇 |
1986年 | 20篇 |
1985年 | 10篇 |
1984年 | 12篇 |
1983年 | 3篇 |
1982年 | 5篇 |
1981年 | 2篇 |
1979年 | 2篇 |
1977年 | 3篇 |
1975年 | 3篇 |
1973年 | 3篇 |
1938年 | 1篇 |
1936年 | 1篇 |
排序方式: 共有3665条查询结果,搜索用时 0 毫秒
101.
102.
利用硫杂杯[4]芳烃衍生物与罗丹明乙二胺发生酰化反应,合成了2个具有双罗丹明基团的1,3-硫杂杯[4]罗丹明乙二胺酰胺衍生物.在实验条件下,衍生物与Fe3+均能形成1:1配合物,配合物的形成诱导了衍生物分子中罗丹明基螺环开环,而表现出良好的荧光和比色探针性能.1,3-硫杂杯[4]罗丹明酰胺-2,4-酯对Fe3+的选择性... 相似文献
103.
Marco Castrillón López Jaime Muñz Masquó 《International Journal of Theoretical Physics》2007,46(4):1020-1026
It is proved that the Euler–Lagrange equations of a Yang-Mills type Lagragian is independent with respect to the chosen pairing
in the Lie algebra. Moreover, the Hamilton-Cartan equations of these Lagrangians are obtained and proved to be also independent
with respect to the pairing.
PACS Numbers 2003: 02.20.Qs, 02.20.Sv, 02.20.Tw, 02.40.Ma, 02.40.Vh, 11.10.Ef, 11.15.Kc
Mathematics Subject Classification 2000: Primary 70S15, Secondary 58A20, 58E15, 58E30, 70S05, 70S10, 81T13 相似文献
104.
中国散裂中子源一期工程的直线加速器,共有8套数字化射频低电平控制单元,射频低电平的本地控制属于EPICS的异构系统,无法直接与EPICS客户端进行通信。通过在射频低电平本地控制上位机程序中嵌入一个C#类型的EPICS服务器程序,实现了使用EPICS客户端对射频低电平系统的远程控制, 从而把射频低电平控制系统接入基于EPICS框架的控制系统中。直线射频低电平远程控制投入在线运行以来,运行稳定可靠。 相似文献
105.
We investigated the properties of low-lying states in 94Mo within the framework of the proton-neutron interacting boson model (IBM-2), with special focus on the characteristics of mixed-symmetry states. We calculated level energies and M1 and E2 transition strengths. The IBM-2 results agree with the available quantitative and qualitative experimental data on 94Mo. The properties of mixed-symmetry states can be well described by IBM-2 given that the energy of the d proton boson is different from that of the neutron boson, especially for the transition of B(M1; 4 2 + → 4 1 + ). 相似文献
106.
A method of contrast enhancement of optical coherence tomography (OCT) images based on least squares fitting and histogram matching is presented. Several different functions are adopted as the probability density functions of the gray levels to fit the normalized histogram of an OCT image and histogram matching is used to enhance the OCT image automatically. The effectiveness of the method is proved by the experimental results. 相似文献
107.
本文运用密度泛函理论DFT-B3LYP方法,对铑、碘元素采用相对论校正赝势基组SDD,对C、O、H采用6-311+G(2d,p)基组,计算研究了顺式羰基铑碘络合物催化甲醇羰基化制乙酸反应的微观机理,优化了各反应物、中间体和过渡态的构型特征,用频率分析方法和内禀反应坐标方法对过渡态进行了验证,运用Kozuch撰写的能量跨度模型获得循环反应的动力学信息,确定了决定循环反应速率的决速过渡态和决速中间体,并利用转化频率评估了催化性能与温度的变化关系. 相似文献
108.
Renal Clearable Luminescent WSe2 for Radioprotection of Nontargeted Tissues during Radiotherapy 下载免费PDF全文
Haixia Liu Junying Wang Yaqi Jing Jiang Yang Xueting Bai Xiaoyu Mu Fujuan Xu Xuhui Xue Lingfang Liu Yuan‐Ming Sun Qiang Liu Haitao Dai Changlong Liu Xiao‐Dong Zhang 《Particle & Particle Systems Characterization》2017,34(6)
High‐energy ionizing radiation is widely used in medical diagnosis and cancer radiation therapy. However, high‐energy radiation can also impose significant damages in healthy tissues during medical treatments via direct DNA damages and indirect damages from production of reactive oxygen species (ROS). Therefore, it is urgent to develop highly effective radioprotectants with low toxicities that can meet the increasing needs for alleviating the adverse effects from cancer radiation therapy and nuclear emergency. In this work, strongly catalytic ultrasmall (sub‐5 nm) cysteine‐protected WSe2 dots are employed to protect healthy tissues against radiation via diminishing radiation‐induced free radicals. The WSe2 dots with high surface activities can recover radiation‐induced DNA damages and eliminate the excessive ROS generated from radiation. In vivo experiments confirm that the survival rate of mice treated with WSe2 dots is significantly elevated with radiation damages postponed under exposure to high‐dose ionizing radiation. Furthermore, the free radicals in major organs and hematological system can be appreciably omitted, suggesting their unique role as free radical scavengers. These WSe2 dots in ultrasmall size show rapid renal clearance of ≈74% injection dose via urine excretion in 24 h and do not cause any apparent toxicity in vivo for up to 30 d. 相似文献
109.
Rožič B Tzitzios V Karatairi E Tkalec U Nounesis G Kutnjak Z Cordoyiannis G Rosso R Virga EG Muševič I Kralj S 《The European physical journal. E, Soft matter》2011,34(2):1-11
We have studied theoretically and experimentally the effects of various types of nanoparticles (NPs) on the temperature stability range [Formula: see text] T (BP) of liquid-crystalline (LC) blue phases. Using a mesoscopic Landau-de Gennes type approach we obtain that the defect core replacement (DCR) mechanism yields in the diluted regime [Formula: see text] T (BP)(x) [Formula: see text] 1/(1 - xb) , where x stands for the concentration of NPs and b is a constant. Our calculations suggest that the DCR mechanism is efficient if a local NP environment resembles the core structure of disclinations, which represent the characteristic property of BP structures. These predictions are in line with high-resolution ac calorimetry and optical polarising microscopy experiments using the CE8 LC and CdSe or aerosil NPs. In mixtures with CdSe NPs of 3.5nm diameter and hydrophobic coating the BPIII stability range has been extended up to 20K. On the contrary, the effect of aerosil silica nanoparticles of 7.0nm diameter and hydrophilic coating is very weak. 相似文献
110.
Efficient and accurate integration of stochastic (partial) differential equations with multiplicative noise can be obtained through a split-step scheme, which separates the integration of the deterministic part from that of the stochastic part, the latter being performed by sampling exactly the solution of the associated Fokker-Planck equation. We demonstrate the computational power of this method by applying it to the most absorbing phase transitions for which Langevin equations have been proposed. This provides precise estimates of the associated scaling exponents, clarifying the classification of these nonequilibrium problems, and confirms or refutes some existing theories. 相似文献