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61.
A metal ion indicator, Alizarin Red S, was tested for its potential use in uranium selective optode membrane. The water-soluble indicator was lipophilized in the form of an ion pair with tetraoctylammonium bromide, and subsequently immobilized on a triacetyl cellulose membrane. The membrane responds to uranium ions, giving a color change from yellow to violet in acetate buffer pH 5. This optode has a linear range of (1.70-18.7) × 10−5 M of UO22+ ions with a limit of detection of 5 × 10−6 M. The response time of optode was within 6 min depending on the concentration of UO22+ ions. The sensor can readily be regenerated with hydrochloric acid solution (0.01 M). The optode is fully reversible. 相似文献
62.
Heidari Mozhgan Ghaffarinejad Ali Omidinia Eskandar 《Journal of Solid State Electrochemistry》2022,26(6):1445-1454
Journal of Solid State Electrochemistry - Screening for hepatitis B is one of the most severe liver virus infections in the world, and due to the effect of early detection and treatment of... 相似文献
63.
Mozhgan Masoudi Mohammad Anary-Abbasinejad Alireza Maleki 《Journal of the Iranian Chemical Society》2017,14(11):2299-2304
An efficient one-pot synthesis of 2H-pyrroline derivatives by a four-component reaction between carbon disulfide, aniline, arylglyoxals and β-enaminocarbonyls in acetonitrile at room temperature under mild reaction conditions is reported. The addition reaction has been done to access broad range of 5-hydroxy-4-phenylcarbamodithioate 2-H pyrroline derivatives after about 6 h stirring. All reactions were performed in acetonitrile at room temperature. Reactions are clean, and products were isolated by simple filtration. 相似文献
64.
Ecohydrological models vary in their sensitivity to forcing data and use available information to different extents. We focus on the impact of forcing precision on ecohydrological model behavior particularly by quantizing, or binning, time-series forcing variables. We use rate-distortion theory to quantize time-series forcing variables to different precisions. We evaluate the effect of different combinations of quantized shortwave radiation, air temperature, vapor pressure deficit, and wind speed on simulated heat and carbon fluxes for a multi-layer canopy model, which is forced and validated with eddy covariance flux tower observation data. We find that the model is more sensitive to radiation than meteorological forcing input, but model responses also vary with seasonal conditions and different combinations of quantized inputs. While any level of quantization impacts carbon flux similarly, specific levels of quantization influence heat fluxes to different degrees. This study introduces a method to optimally simplify forcing time series, often without significantly decreasing model performance, and could be applied within a sensitivity analysis framework to better understand how models use available information. 相似文献
65.
Shahamirian Mozhgan Szatylowicz Halina Krygowski Tadeusz M. 《Structural chemistry》2017,28(5):1563-1572
Structural Chemistry - An application of two independent quantum chemistry-based concepts, a substituent effect stabilization energy (SESE) and a charge of the substituent active region (cSAR), for... 相似文献
66.
Pd(II) salen complex covalently anchored to multi‐walled carbon nanotubes as a heterogeneous and reusable precatalyst for Mizoroki–Heck and Hiyama cross‐coupling reactions
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A Pd(II) salen complex anchored to multi‐walled carbon nanotubes showed excellent catalytic activity and stability for the Mizoroki–Heck and Hiyama cross‐couplings of aryl halides with olefins and phenylsiloxanes. Furthermore, the heterogeneous catalyst could be reused up to four times with the catalytic activity being recovered easily after simple manipulations. Copyright © 2014 John Wiley & Sons, Ltd. 相似文献
67.
Meissam Noroozifar Mozhgan Khorasani-Motlagh Mojtaba Bemanadi Parizi Reza Akbari 《Ionics》2013,19(9):1317-1327
A novel biosensor has been constructed by incorporating modified nanosized natural zeolite and 3-hydroxypropanaminium acetate (HPAA) as a novel room temperature ionic liquid, supported on multiwalled carbon nanotube (MWCNTs) and employed for the simultaneous determination of dopamine (DA) and uric acid (UA). A detailed investigation by transmission electron microscopy and electrochemistry is performed in order to elucidate the preparation process and properties of the composites. The voltammetric studies using the modified carbon paste electrode show two well-resolved anodic peaks for DA and UA with a potential difference of 160 mV, revealing the possibility of the simultaneous electrochemical detection of these compounds. The modified carbon paste electrode shows good conductivity, stability, and extraction effect due to the synergic action of HPAA, MWCNTs, and iron ion-doped natrolite zeolite. Under optimized conditions, the peak currents are linear from 8.12?×?10?7 to 3.01?×?10?4?mol?L?1 and from 9.31?×?10?7 to 3.36?×?10?4?mol?L?1 with detection limits of 1.16?×?10?7 and 1.33?×?10?7?mol?L?1 for DA and UA using the differential pulse voltammetric method, respectively. Finally, the modified carbon paste electrode proved to have good sensitivity and stability and is successfully applied for the simultaneous determination of DA and UA in human blood serum and urine samples. 相似文献
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69.
Russian Journal of General Chemistry - In this study, the reaction of 1-alkyl-5-nitro-1H-benzoimidazoles and 1-alkyl-5-nitro-1H-indazoles with benzofuran and benzothiophen derivatives has led to... 相似文献
70.
Mozhgan Khorasani-Motlagh Nasser Safari Hamid Reza Khavasi Meissam Noroozifar Hashem Shahroosvand Mahtab Biabani 《Journal of chemical crystallography》2007,37(7):457-461
Exposure of dichloromethane solution of [OEOPFe(BF4)], where OEOP is the monoanion of octaethyloxoporphyrin, to dioxygen results in its transformation into the μ-oxo bridged compound, [(OEOPFe)2O)](BF4)2. The molecular structure of the title compound, [(OEOPFe)2O](BF4)2, was determined by single-crystal X-ray diffraction. It contains a binuclear centrosymmetric [(OEOPFe)2O]2+ cation (the bridging O atom lies on an inversion centre) and two tetrafluoroborate anions. The Fe atom is five-coordinate to four N atoms of the porphyrin ring and to one bridging O atom. The compound is characterized by an average Fe–N bond length of 2.064 Å. The Fe–O bond distance is 1.7665(11) Å and the Fe–O–Fe bond angle is 180.0° and the two porphyrin rings are parallel. Crystal data: crystal system, monoclinic, a = 8.867(3), b = 26.104(9), c = 15.748(6) Å, β = 105.40(3)°, space group, P21/c, V = 3514(2) Å3, Z = 2. 相似文献