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41.
Structural Chemistry - The [4+2] cycloaddition reaction of 1,3-dimethylindole and ortho-quinone methide (obtained from tautomerization of 2,6-dimethylquinone under basic conditions), experimentally... 相似文献
42.
Ibrahim Taha Radwan Mohamed M. Baz Hanem Khater Abeer Mousa Alkhaibari Abdelfattah M. Selim 《Molecules (Basel, Switzerland)》2022,27(8)
(1) Background: Mosquito control with essential oils is a growing demand. This work evaluated the novel larvicidal and adulticidal activity of fennel and green tea oils and their Layered double hydroxides (LDHs) nanohybrid against Culex pipiens (Cx. pipiens) in both laboratory and field conditions and evaluated their effect against non-target organisms; (2) Methods: Two types of nanoclays, MgAl-LDH and NiAl-LDH were synthesized and characterized using PXRD, TEM and SEM, whereas their elemental analysis was accomplished by SEM-EDX; (3) Results: Mg and Ni LDHs were synthesized by the co-precipitation method. The adsorption and desorption of active ingredients were conducted using LC MS/MS, with reference to the SEM-EXD analysis. The desorption process of MgAl-LDH intercalated green tea oil was conducted using ethanol, and reveled significant peaks related to polyphenols and flavonoids like Vanillin, Catechin, Daidzein, Ellagic acid, Naringenin, Myricetin and Syringic acid with concentrations of 0.76, 0.73, 0.67, 0.59, 0.52, 0.44 and 0.42 μg/g, respectively. The larvicidal LC50 values of fennel oil, Mg-LDH-F, and Ni-LDH-F were 843.88, 451.95, 550.12 ppm, respectively, whereas the corresponding values of green tea were 938.93, 530.46, and 769.94 ppm. The larval reduction percentage of fennel oil and Mg-LDH-F reached 90.1 and 96.2%, 24 h PT and their persistence reached five and seven days PT, respectively. The reduction percentage of green tea oil and Mg-LDH-GT reached 88.00 and 92.01%, 24 h PT and their persistence reached five and six days PT, respectively. Against adults, Mg-LDH-GT and Ni-LDH-GT were less effective than green tea oil as their LC95 values were 5.45, 25.90, and 35.39%, respectively. The reduction in adult density PT with fennel oil, Mg-LDH-F, green tea oil, and Mg-LDH-GT reached 83.1, 100, 77.0, and 99.0%, respectively, 24 h PT and were effective for three days. Mg-LDH-GT and Mg-LDH-F increased the predation Cybister tripunctatus (71% and 69%), respectively; (4) Conclusions: For the first time, Mg-LDH-GT and Mg-LDH-F was the best system loaded with relatively good desorption release to its active ingredients and significantly affected Cx. pipiens larvae and adults in both laboratory and field circumstances, and it could be included in mosquito control. 相似文献
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44.
Mahmoud H. Saleh Nidal M. Ershaidat Mais Jamil A. Ahmad Basim N. Bulos Mousa M. Abdul-Gader Jafar 《Optical Review》2017,24(3):260-277
Spectral dispersions of index of refraction \({n(\lambda )}\) and extinction coefficient \({\kappa (\lambda )}\) of undoped amorphous selenium (a-Se) films of three thicknesses (d?≈?0.5, 0.75, and 1.0 µm) were evaluated by analyzing experimental room-temperature normal-incidence transmittance-wavelength (\({{T_{{\text{exp}}}}(\lambda )} - \lambda\)) data (λ =?400–1100 µm) of their air-supported {a-Se film/thick glass slide}-stacks using Swanepoel’s transmission envelope theory of uniform films. Above a wavelength \({{\lambda _c}\,\, \approx \,\,640\;{\text{nm}}}\), as-measured \({{T_{{\text{exp}}}}(\lambda )}\,\, - \,\lambda\) spectra display well-resolved maxima and minima, with minor shrinkage in transparent and weak absorption regions (750–1100 nm). Below \({\lambda _{\text{c}}}\), a smeared sharp decline of \({{T_{{\text{exp}}}}(\lambda )}\) with decreasing λ, signifying strong absorption in a-Se films and existence of band-tail localized states. For λ > λ c, the \({n\,(\lambda )}\, - \,\lambda\) data retrieved from algebraic envelope procedures followed a Sellmeier-like dispersion relation, with the best-fit values of high-frequency dielectric constant \({{\varepsilon _\infty }\, \approx \,\,{\text{4.9}}}\), static index of refraction \({{n_{\text{0}}} = n\left( {E\, \to \,{\text{0}}} \right)\,\, \approx \,\,{\text{2.43}}}\), and resonance wavelength \({{\lambda _0}\, \approx \,490\,\,{\text{nm}}}\), which may be assigned to onset of photogeneration in a-Se. Urbach-like dependency of absorption coefficient \({\alpha (h{{\nu }})}\) of a-Se films on photon energy \({h{{\nu }}}\) was realized with an Urbach-tail breadth of 85 meV. All achieved optical parameters were found to be slightly dependent on film thickness. Findings of present algebraic analysis are consistent with reported literature results obtained on the basis of other optical analytical approaches. 相似文献
45.
Russian Journal of Applied Chemistry - Industrial by product dumped from iron making industry (slag) has been modified by various chemical agents, particularly, paraffin wax, liquid nitrile... 相似文献
46.
In this paper, the effect of making swirling flow inside an annulus on the subcooled boiling heat transfer has been studied and discussed both experimentally and numerically. The Eulerian-Eulerian model and control volume technique have been used for numerical modeling of the problem. The experimental results show that the critical heat flux values are enhanced by making swirling flow. The experimental and numerical results also indicate that by making swirling flow inside the annulus, the subcooled boiling heat transfer coefficients are increased. Moreover, the experimental and numerical values of the boiling heat transfer coefficients show good agreement with each other. 相似文献
47.
Diana Dahliah Ahmad A. Mousa R. Khenata S. Bin Omran Raed Jaradat 《Phase Transitions》2018,91(3):271-283
Ab initio calculations based on the density functional theory within the full-potential linearized augmented plane wave method were carried out to investigate the structural stabilities of the different crystallographic phases, the pressure-induced phase transition and the electronic properties of the platinum carbide (PtC) compound. The zinc-blende (ZB), rock-salt (RS), cesium chloride (CsCl), wurtzite (WZ), nickel arsenide (NiAs), lead monoxide (PbO) and the tungsten carbide (WC) phases were considered. The exchange and correlation potential was treated by the generalized-gradient approximation using the Perde–Burke–Ernzerhof parameterization. The thermodynamic properties such as variation of the bulk modulus, lattice constant, heat capacity, thermal expansion and Debye temperature versus pressures and temperatures are investigated. The band structure results show the metallic character of the PtC compound in all the considered phases and the present study also shows that the PtC compound crystallizes in the ZB phase at ambient conditions. The theoretical transition pressures from the ZB to RS for the NiAs, PbO and CsCl transformations were also computed. 相似文献
48.
M. Sayed A.A. Mousa 《Communications in Nonlinear Science & Numerical Simulation》2012,17(12):5201-5216
The influence of the quadratic and cubic terms on non-linear dynamic characteristics of the angle-ply composite laminated rectangular plate with parametric and external excitations is investigated. The method of multiple time scale perturbation is applied to solve the non-linear differential equations describing the system up to and including the second-order approximation. All possible resonance cases are extracted and investigated at this approximation order. Two cases of the sub-harmonic resonances cases (Ω2 ? 2ω1 and Ω2 ? 2ω2) in the presence of 1:2 internal resonance ω2 ? 2ω1 are considered. The stability of the system is investigated using both frequency response equations and phase-plane method. It is quite clear that some of the simultaneous resonance cases are undesirable in the design of such system as they represent some of the worst behavior of the system. Such cases should be avoided as working conditions for the system. Some recommendations regarding the different parameters of the system are reported. Comparison with the available published work is reported. 相似文献
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50.
A series of compounds 3a-d,i-n with two or three 1,2,3-thiadiazole rings, useful for photocrosslinking processes, was prepared from the di- or triketones 1a-d,i-n via the corresponding hydrazones 2a-d,i-n by applying the Hurd-Mori method. A special synthetic sequence, 1e, 2e, 3e, 3f/3g , was elaborated for the olefinic system 3h. 相似文献