Comparison of one- and two-dimensional detectors on simulated and spin-stand readback waveforms

Shingled writing (SW) and two-dimensional magnetic recording (TDMR) are two complementary candidate technologies proposed to extend the life of magnetic recording. SW enables the writing of narrow tracks with a wider writer by shingling the tracks; each track partially overlaps the preceding track leaving only a fraction of that track on the medium. TDMR is the companion technology to SW that enables reading of narrower tracks with a wider reader. In this work we compare the performances of 1D and 2D detectors in the shingled writing environment, using both comprehensive channel models and spin-stand readback.     

Gas counter for low temperature Conversion Electron M?ssbauer Spectroscopy experiments

The operation of a gas counter, designed for Conversion Electron M?ssbauer Spectroscopy measurement at low temperature, has been investigated. The experimental setup is described and tested with two pure gases, He and Ne, and two mixtures, He-5%CH₄ and He-5%N₂. The impacts on the counter performances of the applied voltage, the gas composition and pressure as well as the gas renewing are investigated between 41?K and 300?K. This investigation is made using ¹¹⁹Sn M?ssbauer source and metallic tin absorber. The appropriate operating conditions of the present counter have been established for temperatures down to 41?K for both pure gases, and 61 and 85?K for He-5%N₂ and He-5%CH₄ respectively.     

Quantum‐Chemical Study of the FeNCN Conversion‐Reaction Mechanism in Lithium‐ and Sodium‐Ion Batteries

We report a computational study on 3d transition‐metal (Cr, Mn, Fe, and Co) carbodiimides in Li‐ and Na‐ion batteries. The obtained cell voltages semi‐quantitatively fit the experiments, highlighting the practicality of PBE+U as an approach for modeling the conversion‐reaction mechanism of the FeNCN archetype with lithium and sodium. Also, the calculated voltage profiles agree satisfactorily with experiment both for full (Li‐ion battery) and partial (Na‐ion battery) discharge, even though experimental atomistic knowledge is missing up to now. Moreover, we rationalize the structural preference of intermediate ternaries and their characteristic lowering in the voltage profile using chemical‐bonding and Mulliken‐charge analysis. The formation of such ternary intermediates for the lithiation of FeNCN and the contribution of at least one ternary intermediate is also confirmed experimentally. This theoretical approach, aided by experimental findings, supports the atomistic exploration of electrode materials governed by conversion reactions.     

Theoretical Calculations and Experimental Verification of the Antibacterial Potential of Some Monocyclic β-Lactams Containing Two Synergetic Buried Antibacterial Pharmacophore Sites

A new series of N-thiazole, 3-phenyl, 4-substituted phenyl azetidine-2-ones 4(a–h) have been synthesized in good yields starting from 2-aminothiazole 1. In the first step, then Schiff's bases 3(a–h) are prepared by the condensation of 2-aminothiazole 1 with different aryl aldehydes 2(a–h). Finally, monocyclic β-lactams, i.e. substituted azetidinones 4(a–h), were the products formed using three different methods by the dehydrative cyclocondensation of 3(a–h) with phenyl acetyl chloride in dioxane, phenyl acetic acid–thionyl chloride in dichloromethane and phenyl acetic acid–phosphorus oxychloride in dichloromethane in the presence of triethylamine. We found that latter method is the best as compared with the former two methods. The synthesized molecules 4(a–h) were screened for their antibacterial activity against four microorganisms: Staphylococcus aureus (Gram positive), Pseudomonas vulgaris (Gram positive), Pseudomonas aeruginosa (Gram negative), and Escherichia coli (Gram negative). Their antibacterial activities are reported, and on the basis of the screening data available, attempt is also made to elucidate the structure–activity relationship.

Supplemental materials are available for this article. Go to the publisher's online edition of Phosphorus, Sulfur, and Silicon and the Related Elements to view the free supplemental file.     

Exploration of the effects of chloride ions on the analysis of polar compounds at low concentrations by hydrophilic interaction liquid chromatography coupled to a charged aerosol detector: Application to tromethamine

In this study, we discuss the origin of the slightly increased response of the charged aerosol detector when low-concentration polar drugs formulated with sodium chloride are analyzed by hydrophilic interaction liquid chromatography coupled to the charged aerosol detector. In the case of tromethamine mixed with saline solutions, we investigated several levels including the mobile phase, sample matrix, and detection. We show that the analysis of the rich-salted sample results in both interactions with the mobile phase modifiers and the stationary phase during the run time. With 150 mM NaCl as a compounding solution, a slight increase in the tromethamine peak area was observed (<5.5%). Our study suggests that chloride ions in excess sequentially interact firstly with the counterions from the organic modifiers and secondly with the analyte via the stationary phase and the contribution of hydrophilic interaction liquid chromatography retention mechanisms. Because of these effects, the hydrophilic interaction liquid chromatography-charged aerosol detector analysis of drugs in saline solutions requires particular attention, and a correction factor for quantitative purposes that accounts for formulation ions remains appropriate.     

Theoretical study of ground state and high-pressure phase of platinum carbide

We report local density-functional calculations using the full-potential linearized muffin-tin orbital method (FP-LMTO) for platinum carbide (PtC) in the, rock-salt (B1), zinc-blende (B3), wurtzite (B4), nickel-arsenide (B8) and PbO (B10) structures. The ground state properties such as the equilibrium lattice constant, elastic constants, the bulk modulus and its pressure derivative of PtC in these phases are determined and compared with available experimental and theoretical data.Our calculations show that the ground state phase of PtC to be zinc-blende (B3) structure at zero pressure and the nickel-arsenide (B8) structure is a high-pressure phase. The transition pressures at which this compound undergoes the structural phase transition from (B3) to (B8) and from (B3) to (B1) are found to be 34.25 and 51.28 GPa, respectively. The highest bulk modulus values in the nickel-arsenide (B8), zinc-blende (B3), rock-salt (B1) and PbO (B10) structures indicate that PtC is a hard material.     

A new look at CMRH and its relation to GMRES

CMRH is a Krylov subspace method which uses the Hessenberg process to produce a basis of a Krylov method, and minimizes a quasiresidual. This method produces convergence curves which are very close to those of GMRES, but using fewer operations and storage. In this paper we present new analysis which explains why CMRH has this good convergence behavior. Numerical examples illustrate the new bounds.     

Existence and stability for some partial neutral functional differential equations with infinite delay

In this paper, we study a class of partial neutral functional differential equations with infinite delay. We suppose that the linear part is not necessarily densely defined but satisfies the resolvent estimates of the Hille-Yosida theorem. We give some sufficient conditions ensuring the existence, uniqueness and regularity of solutions. A principle of linearized stability is also established in the autonomous case. To illustrate our abstract results, we conclude this work by an example.     

Fluctuations in a SIS epidemic model with variable size population

In an epidemiological model, time spent in one compartment is often modeled by a delay in the model. In general the presence of delay in differential equations can change the stability of an equilibrium to instability and causes the appearance of oscillatory solutions.In this paper we consider a SIS epidemiological model with demographic effects: birth, mortality and mortality caused by infection. The delay is the period of infection. We define the concept of oscillation in the sense that solutions of the model studied fluctuate around a steady state. Our goal is to show that in this model, there are oscillating solutions for certain parameters values. We determine a large set of initial data for which solutions of this model are slowly oscillating.     

Approximation polynomiale des jets de Whitney ∂‾-plats de classe M

We study the problem of global approximation by polynomials in Whitney $\stackrel{￣}{?}$-flat jet classes on irregular compacts of ${\mathbb{C}}^N$.