Isotactic rac‐Lactide Polymerization with Copper Complexes: The Influence of Complex Nuclearity

Diiminopyrrolide copper alkoxide complexes, LCuOR (OR¹=N,N‐dimethylamino ethoxide, OR²=2‐pyridyl methoxide), are active for the polymerization of rac‐lactide at ambient temperature in benzene to yield polymers with M_w/M_n=1.0–1.2. X‐ray diffraction studies showed bridged dinuclear complexes in the solid state for both complexes. While LCuOR¹ provided only atactic polylactide, LCuOR² produced partially isotactic polylactide (P_m=0.7). The difference in stereocontrol is attributed to a dinuclear active species for LCuOR² in contrast to a mononuclear species for LCuOR¹.     

Solvent-free synthesis of polyhydroquinoline and 1,8-dioxodecahydroacridine derivatives through the Hantzsch reaction catalyzed by a natural organic acid: A green method

Solvent-free and high yielding one-pot synthesis of 1,8-dioxodecahydroacridine and polyhydroquinoline derivatives have been described through Hantzsch condensation of various aldehydes, ammonium acetate with cyclic 1,3-dicarbonyl compounds and ethyl acetoacetate in a very simple, efficient, and environmentally benign method using ascorbic acid as a nontoxic organocatalyst.     

Equality statements for Schwarz–Pick type estimates and the pseudo-hyperbolic distance

In the present article we demonstrate that the conclusion on the case of equality for the estimate of Schwarz–Pick type is a property of a distance-nonincreasing holomorphic mapping which is locally defined. Also, while considering existence of branch points, we deal with the topics in terms of the pseudo-hyperbolic distance.     

Méthodes d'approximation et d'itération pour les opérateurs monotones

Sans résumé Mémoire présenté par J. L. Lions     

A two-scale second-moment turbulence closure based on weighted spectrum integration

A two-scale second-moment turbulence closure has been derived based on the weighted integration of the dynamic equation for the covariance spectrum. The goal is to close the Reynolds stress equations with two additional scalar equations that provide separately the scales of the spectral energy transfer and of the turbulence energy dissipation rate. Such a model should provide better prediction of nonequilibrium turbulent flows. The derivation consists of analytical integration of the wave-number-weighted covariance spectrum using a model of the spectral equations with an assumed simple representation of the shape of the energy spectrum. The resulting closure consists of a set of three tensorial equations, one for the Reynolds stress and two for length scale tensors, the latter representing the energy containing- and dissipative eddies respectively. The trace of the two tensor-scale equations leads to a set of two scalar scale parameters. In the equilibrium limit, the model reduces to the standard second-moment single-scale closure. The approach makes it also possible to derive the scale equations in a more systematic manner as compared with the common single-scale and other multi-scale models. The performance of the model in capturing the scale dynamics is illustrated by predictions of several generic homogeneous and inhomogeneous unsteady flows, demonstrating the expected response of the two scale equations. PACS 03.50.De, 04.20-q, 42.65-k     

Poly(ε-caprolactone)-Based Graft Copolymers: Synthesis Methods and Applications in the Biomedical Field: A Review

Synthetic biopolymers are attractive alternatives to biobased polymers, especially because they rarely induce an immune response in a living organism. Poly ε-caprolactone (PCL) is a well-known synthetic aliphatic polyester universally used for many applications, including biomedical and environmental ones. Unlike poly lactic acid (PLA), PCL has no chiral atoms, and it is impossible to play with the stereochemistry to modify its properties. To expand the range of applications for PCL, researchers have investigated the possibility of grafting polymer chains onto the PCL backbone. As the PCL backbone is not functionalized, it must be first functionalized in order to be able to graft reactive groups onto the PCL chain. These reactive groups will then allow the grafting of new reagents and especially new polymer chains. Grafting of polymer chains is mainly carried out by “grafting from” or “grafting onto” methods. In this review we describe the main structures of the graft copolymers produced, their different synthesis methods, and their main characteristics and applications, mainly in the biomedical field.     

Ueber die Quantitative Bestimmung des Wasserstoffhyperoxydes

Ohne Zusammenfassung     

Verwendung des Hydrazinsulfats zur Titerstellung von Jodl?sungen

Ohne Zusammenfassung     

Commercial fire-retarded PET formulations - Relationship between thermal degradation behaviour and fire-retardant action

Many types of fire retardants are used in poly(ethylene terephthalate), PET, formulations, and two commercial fire retardants, Ukanol^® and Phosgard^®, have been shown to improve significantly PET flame-retardancy when used as comonomers. Phosgard incorporates a phosphorus atom within the main chain whereas Ukanol incorporates a phosphorus atom as a pendent substituent. Despite their acknowledged effectiveness, the mode of action of these fire retardants remains unclear, and in this paper we present a comparison of the overall thermal degradation behaviour of PET and Ukanol and Phosgard fire-retarded formulations. DSC and particularly TGA data show that both Ukanol and Phosgard have some stabilising influence on PET degradation, especially under oxidative conditions. TGA and pyrolysis experiments both clearly indicate that neither of the additives acts as a char promoter. Only the Phosgard formulation shows any release of volatile phosphorus species which could act in the gas phase. On the other hand, the most striking feature of the pyrolysis experiments is the macroscopic structure of the chars produced by the fire-retarded formulations, which hints at their fire-retardancy action - an open-cell charred foam was obtained upon charring at 400 °C or 600 °C. This foaming layer between the degrading melt and the flame would lower the amount of fuel available for combustion, and would also limit the feedback of heat to the condensed phase.