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81.
Frontispiece: Proton Order–Disorder Phenomena in a Hydrogen‐Bonded Rhodium–η5‐Semiquinone Complex: A Possible Dielectric Response Mechanism 下载免费PDF全文
Dr. Minoru Mitsumi Kazunari Ezaki Yuuki Komatsu Prof. Dr. Koshiro Toriumi Dr. Tatsuya Miyatou Prof. Dr. Motohiro Mizuno Nobuaki Azuma Prof. Dr. Yuji Miyazaki Prof. Dr. Motohiro Nakano Prof. Dr. Yasutaka Kitagawa Dr. Takayasu Hanashima Dr. Ryoji Kiyanagi Dr. Takashi Ohhara Prof. Dr. Kazuhiro Nakasuji 《Chemistry (Weinheim an der Bergstrasse, Germany)》2015,21(27)
82.
83.
Shingo Atobe Motohiro Sonoda Yuki Suzuki Takuya Yamamoto Haruna Masuno Hiroyuki Shinohara Akiya Ogawa 《Research on Chemical Intermediates》2013,39(1):359-370
Palladium-catalyzed oxidative homocoupling of terminal acetylenes, in air, occurred in the presence of 1-(2-pyridylethynyl)-2-(2-thienylethynyl)benzene as ligand, affording the corresponding conjugated diynes. 相似文献
84.
Dr. Graham N. Newton Dr. Norihisa Hoshino Dr. Takuto Matsumoto Dr. Takuya Shiga Prof. Motohiro Nakano Prof. Hiroyuki Nojiri Prof. Wolfgang Wernsdorfer Prof. Yuji Furukawa Prof. Hiroki Oshio 《Chemistry (Weinheim an der Bergstrasse, Germany)》2016,22(40):14205-14212
Here we report the synthesis, structure and detailed characterisation of three n‐membered oxovanadium rings, Nan[(V=O)nNan(H2O)n(α, β, or γ‐CD)2]?m H2O (n=6, 7, or 8), prepared by the reactions of (V=O)SO4?x H2O with α, β, or γ‐cyclodextrins (CDs) and NaOH in water. Their alternating heterometallic vanadium/sodium cyclic core structures were sandwiched between two CD moieties such that O‐Na‐O groups separated the neighbouring vanadyl ions. Antiferromagnetic interactions between the S=1/2 vanadyl ions led to S=0 ground states for the even‐membered rings, but to two quasi‐degenerate S=1/2 states for the spin‐frustrated heptanuclear cluster. 相似文献
85.
Motohiro Sobajima 《Journal of Evolution Equations》2014,14(2):461-475
The m-accretivity and m-sectoriality of the minimal and maximal realizations of second-order elliptic operators of the form ${Au=-{\rm div}(a \nabla u)+F\cdot \nabla u +Vu}$ in ${L^p(\mathbb{R}^N)}$ are shown, where the coefficients a, F and V are unbounded. The result may be regarded as an endpoint assertion of the previous result in Sobajima (J Evol Equ 12:957–971, 2012) and an improvement of that in Metafune et al. (Forum Math 22:583–601, 2010). Moreover, an L p -generalization of Kato’s self-adjoint problem in Kato (1981, Appendix 2) is discussed. The proof is based on Sobajima (J Evol Equ 12:957–971, 2012). As examples, the operators ${-\Delta \pm |x|^{\beta-1}x \cdot \nabla +c|x|^{\gamma}}$ are also dealt with, which are mentioned in Metafune et al. (Forum Math 22:583–601, 2010). 相似文献
86.
Motohiro Sonoda Shoko Kinoshita Thanh Luu Hiroshi Fukuda Koji Miki Rui Umeda 《合成通讯》2013,43(18):3315-3323
Selective lithiation of 3-bromothiophene was accomplished under controlled conditions without formation of undesired thienyllithium compounds. A thienyl Grignard reagent derived from 2-bromo-3-iodothiophene was transformed into 2-bromo-3-formylthiophene in high selectivity by formylation with dimethylformamide (DMF) at optimal reaction temperature. 相似文献
87.
Ouardi S Fecher GH Kozina X Stryganyuk G Balke B Felser C Ikenaga E Sugiyama T Kawamura N Suzuki M Kobayashi K 《Physical review letters》2011,107(3):036402
This study reports on the linear dichroism in angular-resolved photoemission from the valence band of the Heusler compounds NiTi0.9Sc0.1Sn and NiMnSb. High-resolution photoelectron spectroscopy was performed with an excitation energy of hν = 7.938 keV. The linear polarization of the photons was changed using an in-vacuum diamond phase retarder. The valence band spectra exhibit the typical structure expected from first-principles calculations of the electronic structure of these compounds. Noticeable linear dichroism is found in the valence band of both materials, and this allows for a symmetry analysis of the contributing states. The differences in the spectra are found to be caused by symmetry-dependent angular asymmetry parameters, and these occur even in polycrystalline samples without preferential crystallographic orientation. 相似文献
88.
89.
Shuzo Akiyama Shinichi Nakatsuji Toshihiko Hamamura Motohiro Kataoka Masazumi Nakagawa 《Tetrahedron letters》1979,20(30):2809-2812
A convenient synthesis of α,β- and α,β,γ,δ-unsaturated aldehydes using readily accessible 4-(t-butylthio)-3-buten-2-one as synthon was described. 相似文献
90.
Osamu Takahashi Katsuyoshi Yamasaki Kazuyoshi Ueda Motohiro Nishio 《Tetrahedron》2008,64(24):5773-5778
Ab initio MO calculations were carried out, at the MP2/6-311++G(d,p)//MP2/6-311G(d,p) level, to investigate the Gibbs energy of conformational isomers of (R)-α-phellandrene and related 5-alkyl-1,3-cyclohexadienes. It has been found that the conformer bearing the 5-alkyl group in axial orientation is more stable than the equatorial congener. The result is consistent with experimental evidence that the axial-isopropyl conformer prevails in the conformational equilibrium of α-phellandrene. The reason for the stability of the folded conformer has been sought in the context of the CH/π hydrogen bond. A number of short non-bond distances have been disclosed in the axial conformers, between CHs in the 5-alkyl group and sp2-carbons of the cyclohexadiene ring. We suggest that the stability of the folded conformation often observed in conjugated diene compounds of natural origin, such as α-phellandrene and levopimaric acid, is attributed to an attractive molecular force, the CH/π hydrogen bond. 相似文献