Entanglement via permutation symmetry and reflection invariance of angular momentum algebra

We propose an alternative method for computing total angular momentum using su(2)-invariance     

Measurement of permethrin,deltamethrin and malathion pesticide residues in the wheat flour and breads and probabilistic health risk assessment: a case study in Kermanshah,Iran

ABSTRACT

This study was conducted to investigate the residues of pyrethroid and organophosphorus pesticide in flour and breads which were collected from local markets in Kermanshah province, Iran. Four different types of breads and two types of flour samples with high distribution were taken from market and their residues of pesticides were measured. A simple dispersive liquid–liquid microextraction (DLLME) method with solidification of floating organic drop was developed for the measurement. The health risk of these pesticides on adults and children health was assessed by target hazard quotient (THQ) using Monte Carlo simulation (MCS) method. About, 15% and 11.1% of total samples contained detectable levels of deltamethrin and malathion, respectively. None of the tested samples showed any permethrin residue. The results from all samples showed that none of the pesticides exceeded the maximum residue limits (MRLs). About 85% of pesticide residue detections were observed in tropical and mild weather area which is due to high consumption rate of insecticides in these areas. The percentile 95% of THQ is due to bread ingestion content of deltamethrin which was 0.033 and 0.070 for the adults and children, respectively, while this value for malathion was found to be, 0.015 and 0.030, respectively. In the adults and children for both deltamethrin and malathion, the percentile 95% of THQ value were lower than 1 (acceptable level). The non-carcinogenic health risk assessment indicated that bread consumers in Kermanshah province are not at a considerable risk because of deltamethrin and malathion.     

Pattern recognition for rapid T2 mapping with stimulated echo compensation

Indirect echoes (such as stimulated echoes) are a source of signal contamination in multi-echo spin-echo T₂ quantification and can lead to T₂ overestimation if a conventional exponential T₂ decay model is assumed. Recently, nonlinear least square fitting of a slice-resolved extended phase graph (SEPG) signal model has been shown to provide accurate T₂ estimates with indirect echo compensation. However, the iterative nonlinear least square fitting is computationally expensive and the T₂ map generation time is long. In this work, we present a pattern recognition T₂ mapping technique based on the SEPG model that can be performed with a single pre-computed dictionary for any arbitrary echo spacing. Almost identical T₂ and B₁ maps were obtained from in vivo data using the proposed technique compared to conventional iterative nonlinear least square fitting, while the computation time was reduced by more than 14-fold.     

Indole as a reagent for nitrite in aqueous solution

A fairly selective and sensitive spectrophotometric method for the trace determination of nitrite in aqueous solution is described. The titled ion reacts with indole in acidic medium to form a soluble pink-red product, which is measured at 530 nm. Maximum absorbance is achieved in 10 min and remains constant for about 45 min. This method is applicable to water samples containing 0–2 μg/ml with a relative error of 0.0 to–0.8%, and relative standard deviation of 0.3–0.8%, depending on the concentration level. The optimum reaction conditions affecting and related to the color reaction and interferences due to foreign ions have been studied.     

Dipolar cycloaddition reactions of organic azides with some acetylenic compounds

Phenyl azide 1 and several substituted benzyl azides 2a-o underwent 1,3-dipolar cycloaddition reactions with dimethyl acetylenedicarboxylate 3, phenylacetylene 4 and ethyl propiolate 5 to afford the triazoles 6-13. The reactions of these azides with ethyl propiolate were found to be completely regiospecific.     

Minimizing the sum of a linear and a linear fractional function applying conic quadratic representation: continuous and discrete problems

This paper tries to minimize the sum of a linear and a linear fractional function over a closed convex set defined by some linear and conic quadratic constraints. At first, we represent some necessary and sufficient conditions for the pseudoconvexity of the problem. For each of the conditions, under some reasonable assumptions, an appropriate second-order cone programming (SOCP) reformulation of the problem is stated and a new applicable solution procedure is proposed. Efficiency of the proposed reformulations is demonstrated by numerical experiments. Secondly, we limit our attention to binary variables and derive a sufficient condition for SOCP representability. Using the experimental results on random instances, we show that the proposed conic reformulation is more efficient in comparison with the well-known linearization technique and it produces more eligible cuts for the branch and bound algorithm.     

Influence of Interfacial Engineering on Stability of Emulsions Stabilized with Soy Protein Isolate

The objectives of this study were to examine the influence interfacial composition on environmental stresses stability of oil in water emulsions. An electrostatic layer-by-layer deposition method was used to create the multilayered interfacial membranes with different compositions: (i) primary emulsion (Soy protein Isolate); (ii) secondary emulsion (Soy protein Isolate – OSA-starch); (iii) tertiary emulsion (Soy protein isolate – OSA-starch – chitosan). Fourier transform-infrared (FTIR) and scanning electron microscopy (SEM) results confirmed the adsorption of charged polyelectrolyte onto oppositely charge polyelectrolyte-coated oil droplets. The stability of primary, secondary, and tertiary emulsions to thermal treatment (30 min at 30–90°C), pH (3–7) and NaCl (0–500 mM) were determined using ζ-potential, particle diameter, and microstructure analysis. Primary emulsions were unstable at pH 4–7, salt concentrations, and thermal treatments. Secondary emulsions were stable to creaming and droplet aggregation at pH 3–5, at ≤50 mM NaCl, and unstable at thermal treatments, whereas tertiary emulsions were stable at all salt concentrations, thermal treatments, and at pH 3–6. These results demonstrate that these polymers can be used to engineer oil in water emulsion systems and improve the emulsion stability to environmental stresses.     

Transport properties in mixtures involving carbon dioxide at low and moderate density: test of several intermolecular potential energies and comparison with experiment

It is the purpose of this paper to extract unlike intermolecular potential energies of five carbon dioxide-based binary gas mixtures including CO₂–He, CO₂–Ne, CO₂–Ar, CO₂–Kr, and CO₂–Xe from viscosity data and compare the calculated potentials with other models potential energy reported in literature. Then, dilute transport properties consisting of viscosity, diffusion coefficient, thermal diffusion factor, and thermal conductivity of aforementioned mixtures are calculated from the calculated potential energies and compared with literature data. Rather accurate correlations for the viscosity coefficient of afore-cited mixtures embracing the temperature range 200 K < T < 3273.15 K is reproduced from the present unlike intermolecular potentials energy. Our estimated accuracies for the viscosity are to within ±2%. In addition, the calculated potential energies are used to present smooth correlations for other transport properties. The accuracies of the binary diffusion coefficients are of the order of ±3%. Finally, the unlike interaction energy and the calculated low density viscosity have been employed to calculate high density viscosities using Vesovic–Wakeham method.     

(Benzyl isocyanide)gold(I) pyrimidine‐2‐thiolate complex: Synthesis and biological activity

The reaction of [(Me₂S)AuCl] with an equimolar amount of benzyl isocyanide (PhCH₂NC) ligand led to the formation of complex [(PhCH₂NC)AuCl] ( 1 ). The solid‐state structure of 1 was determined using the X‐ray diffraction method. Through a salt metathesis reaction, the chloride ligand in 1 was replaced by pyrimidine‐2‐thiolate (SpyN^?) to afford the complex [(PhCH₂NC)Au(η¹‐S‐Spy)] ( 2 ), which was characterized spectroscopically. The cytotoxic activities of 1 and 2 were evaluated against three human cancer cell lines: ovarian carcinoma (SKOV3), lung carcinoma (A549) and breast carcinoma (MCF‐7). Complex 2 showed higher cytotoxicity than cisplatin against SKOV3 and MCF‐7 cancer cell lines. It showed a strong anti‐proliferative activity with IC₅₀ of 7.80, 6.26 and 6.14 μM, compared with that measured for cisplatin which was 7.62, 12.36 and 11.47 μM, against A549, SKOV3 and MCF‐7 cell lines, respectively. The induction of cellular apoptosis by 2 was also studied on MCF‐7 cell line. Our results indicated that 2 could induce apoptosis in cancerous cells in a dose‐dependent manner.