Nano-copper chromite (nano-CuCr2O4): a novel and efficient catalyst for the synthesis of biscoumarin and pyrano[c]chromene derivatives in water at room temperature

Research on Chemical Intermediates - A clean, efficient and eco-friendly procedure has been developed using nano-copper chromite (nano-CuCr2O4) as catalyst for the synthesis of biscoumarin and...     

Polyvinylpolypyrrolidone-supported boron trifluoride: a high-loaded, polymer-supported Lewis acid for the Ritter reaction

Abstract  

A Mild and efficient method for preparing amides by reaction of nitriles with benzhydrol and tertiary alcohols is described using polyvinylpolypyrrolidone-supported boron trifluoride. Selective amidation of benzhydrol in the presence of primary benzyl alcohols was also achieved.     

Dust-acoustic solitary waves in a two-temperature electrons with charge fluctuations and nonisothermal ions

In this paper, a modified Korteweg–de Vries (mKdV) equation and Korteweg–de Vries (KdV) equation at critical ion density are derived for dusty plasmas consisting of hot dust fluid, nonisothermal ions and two-temperature electrons. The charge fluctuation dynamics of the dust grains has also been considered. It has been shown that the presence of a second component of electrons modifies the nature of dust acoustic (DA) solitary structures. The effects of two-temperature electrons, obliqueness and external magnetic field on the properties of DA solitary waves are discussed. Numerical investigations show that there exists only rarefactive solitary waves.     

Theory and simulation of cavity quantum electro-dynamics in multi-partite quantum complex systems

The cavity quantum electrodynamics of various complex systems is here analyzed using a general versatile code developed in this research. Such quantum multi-partite systems normally consist of an arbitrary number of quantum dots in interaction with an arbitrary number of cavity modes. As an example, a nine-partition system is simulated under different coupling regimes, consisting of eight emitters interacting with one cavity mode. Two-level emitters (e.g. quantum dots) are assumed to have an arrangement in the form of a linear chain, defining the mutual dipole–dipole interactions. It was observed that plotting the system trajectory in the phase space reveals a chaotic behavior in the so-called ultrastrong-coupling regime. This result is mathematically confirmed by detailed calculation of the Kolmogorov entropy, as a measure of chaotic behavior. In order to study the computational complexity of our code, various multi-partite systems consisting of one to eight quantum dots in interaction with one cavity mode were solved individually. Computation run times and the allocated memory for each system were measured.     

Novel platinum(II) selective membrane electrode based on 1,3-bis(2-cyanobenzene)triazene

A plasticized poly (vinyl chloride) membrane electrode based on 1,3-bis(2-cyanobenzene)triazene (CBT) for highly selective determination of platinum(II) (in PtCl₄²⁻ form) is developed. The electrode showed a good Nernstian response (29.8 ± 0.3 mV decade⁻¹) over a wide concentration range (1.0 × 10⁻⁶ to 1.0 × 10⁻² mol L⁻¹). The limit of detection was 5.0 × 10⁻⁷ mol L⁻¹. The electrode has a response time of about 40 s, and it can be used for at least 1 month without observing any considerable deviation from Nernstian response. The proposed electrode revealed an excellent selectivity toward platinum(II) ion over a wide variety of alkali, alkaline earth, transition, and heavy metal ions, and it could be used in the pH range of 3.2-5.1. The practical utility of the electrode has been demonstrated by its use in determination of platinum ion in, alloy, tap, mineral and river water samples.     

Design of Low-Complexity and High-Speed Coplanar Four-Bit Ripple Carry Adder in QCA Technology

Quantum-dot Cellular Automata (QCA) technology is a suitable technology to replace CMOS technology due to low-power consumption, high-speed and high-density devices. Full adder has an important role in the digital circuit design. This paper presents and evaluates a novel single-layer four-bit QCA Ripple Carry Adder (RCA) circuit. The developed four-bit QCA RCA circuit is based on novel QCA full adder circuit. The developed circuits are simulated using QCADesigner tool version 2.0.3. The simulation results show that the developed circuits have advantages in comparison with existing single-layer and multilayer circuits in terms of cell count, area occupation and circuit latency.     

Head-on collision of ion-acoustic solitary waves in a Thomas-Fermi plasma containing degenerate electrons and positrons

Head-on collision between two ion acoustic solitary waves in a Thomas-Fermi plasma containing degenerate electrons and positrons is investigated using the extended Poincaré-Lighthill-Kuo (PLK) method. The results show that the phase shifts due to the collision are strongly dependent on the positron-to-electron number density ratio, the electron-to-positron Fermi temperature ratio and the ion-to-electron Fermi temperature ratio. The present study might be helpful to understand the excitation of nonlinear ion-acoustic solitary waves in a degenerate plasma such as in superdense white dwarfs.     

Wake potential with mobile positive/negative ions in multicomponent dusty plasmas

We employ the test charge approach to calculate the electrostatic potential for a test charge in a multicomponent dusty plasma, whose constituents are the Boltzmann distributed electrons, mobile positive and negative ions, and immobile positive/negative charged dust particles. By using the modified dielectric constant of the dust-ion-acoustic (DIA) waves, the Debye screening and wake potentials are obtained. It is found that the presence of mobile negative ions significantly modify the DIA speed and the wake potential. The present results are relevant to polar mesosphere and microelectronic in the context of charged particle attraction and repulsion.     

Optimality conditions in optimization problems with convex feasible set using convexificators

In this paper, we consider a nonsmooth optimization problem with a convex feasible set described by constraint functions which are neither convex nor differentiable nor locally Lipschitz necessarily. Utilizing upper regular convexificators, we characterize the normal cone of the feasible set and derive KKT type necessary and sufficient optimality conditions. Under some assumptions, we show that the set of KKT multipliers is bounded. We also characterize the set of optimal solutions and introduce a linear approximation corresponding to the original problem which is useful in checking optimality. The obtained outcomes extend various results existing in the literature to a more general setting.