全文获取类型
收费全文 | 575篇 |
免费 | 10篇 |
专业分类
化学 | 306篇 |
晶体学 | 12篇 |
力学 | 12篇 |
数学 | 86篇 |
物理学 | 169篇 |
出版年
2017年 | 5篇 |
2016年 | 9篇 |
2015年 | 8篇 |
2014年 | 10篇 |
2013年 | 15篇 |
2012年 | 18篇 |
2011年 | 19篇 |
2010年 | 12篇 |
2009年 | 21篇 |
2008年 | 15篇 |
2007年 | 12篇 |
2006年 | 13篇 |
2005年 | 14篇 |
2004年 | 6篇 |
2003年 | 14篇 |
2002年 | 12篇 |
2001年 | 18篇 |
2000年 | 18篇 |
1999年 | 16篇 |
1998年 | 8篇 |
1997年 | 13篇 |
1996年 | 5篇 |
1995年 | 5篇 |
1994年 | 7篇 |
1993年 | 12篇 |
1992年 | 9篇 |
1990年 | 8篇 |
1989年 | 8篇 |
1988年 | 9篇 |
1987年 | 5篇 |
1986年 | 9篇 |
1985年 | 6篇 |
1984年 | 9篇 |
1983年 | 9篇 |
1982年 | 12篇 |
1981年 | 8篇 |
1980年 | 5篇 |
1978年 | 8篇 |
1968年 | 5篇 |
1966年 | 5篇 |
1933年 | 5篇 |
1932年 | 6篇 |
1930年 | 7篇 |
1929年 | 6篇 |
1927年 | 8篇 |
1926年 | 4篇 |
1925年 | 7篇 |
1924年 | 10篇 |
1923年 | 8篇 |
1913年 | 4篇 |
排序方式: 共有585条查询结果,搜索用时 31 毫秒
21.
22.
Huiyun Jiang Yameng Ren Weiwei Zhang Yongzhen Wu Etienne Christophe Socie Brian Irving Carlsen Jacques‐E. Moser He Tian Shaik Mohammed Zakeeruddin Wei‐Hong Zhu Michael Grtzel 《Angewandte Chemie (International ed. in English)》2020,59(24):9324-9329
Dye‐sensitized solar cells (DSSCs) based on CuII/I bipyridyl or phenanthroline complexes as redox shuttles have achieved very high open‐circuit voltages (VOC, more than 1 V). However, their short‐circuit photocurrent density (JSC) has remained modest. Increasing the JSC is expected to extend the spectral response of sensitizers to the red or NIR region while maintaining efficient electron injection in the mesoscopic TiO2 film and fast regeneration by the CuI complex. Herein, we report two new D‐A‐π‐A‐featured sensitizers termed HY63 and HY64 , which employ benzothiadiazole (BT) or phenanthrene‐fused‐quinoxaline (PFQ), respectively, as the auxiliary electron‐withdrawing acceptor moiety. Despite their very similar energy levels and absorption onsets, HY64 ‐based DSSCs outperform their HY63 counterparts, achieving a power conversion efficiency (PCE) of 12.5 %. PFQ is superior to BT in reducing charge recombination resulting in the near‐quantitative collection of photogenerated charge carriers. 相似文献
23.
A. Sen Gupta P. Moser C. Corbel P. Hautojrvi P. Sen 《Crystal Research and Technology》1988,23(2):243-246
GaP single crystals were irradiated by 3 MeV electrons at 20 K to a dose of 4 × 1018 e/cm2. An isochronal annealing in temperature region 77 ÷ 650 K followed the irradiation. Positron lifetime measurement indicated the presence of irradiation-induced vacancies in Ga sublattice. The vacancies disappeared at two stages observed at temperatures 200 ÷ 300 K and 450 ÷ 550 K. 相似文献
24.
Moser DF Bosse T Olson J Moser JL Guzei IA West R 《Journal of the American Chemical Society》2002,124(16):4186-4187
A number of disilanes have been synthesized from a stable silylene, 1 (N,N'-di-tert-butyl-1,3-diaza-2-silacyclopent-4-en-2-ylidene), and a variety of halocarbons. It is proposed that disilane formation is a result of an initial halophilic interaction between the silylene and halocarbon. Formation of disilanes from 1 and CCl4, 2a, CHCl3, 2b, CH2Cl2, 2c, benzyl chloride, 2d, and bromobenzene, 5, are described here. An X-ray crystal structure of 2b was determined. 相似文献
25.
Kempa K Zhou Y Engelbrecht JR Bakshi P Ha HI Moser J Naughton MJ Ulrich J Strasser G Gornik E Unterrainer K 《Physical review letters》2002,88(22):226803
We show theoretically that in quantum wells subjected to a strong magnetic field the intersubband current peaks at magnetic field values, which reveal the underlying specific intersubband scattering mechanism. We have designed and grown a superlattice structure in which such current oscillations are clearly visible, and in which the transition from the purely single-electron to the mixed single- and two-electron scattering regimes can be observed by tuning the applied voltage bias. The measurements were conducted in ultrahigh magnetic fields (up to 45 T) to obtain the full spectrum of the current oscillations. 相似文献
26.
Multi-echo spiral and echo-planar (EPI) imaging sequences were compared in functional imaging experiments at 3 Tesla. Both sequence types allow calculation of the effective transversal relaxation time T(2)* and the initial signal intensity I(0). These parameters can be used in evaluation of the functional signal with respect to inflow effects and other vascular sources. Prior to functional magnetic resonance imaging (fMRI) experiments T(2)* measurements in the human brain were performed with single- and multi-echo FLASH (fast low angle shot) and compared with EPI und spiral imaging sequences. These experiments resulted in T(2)* values ranging from 42.9 to 53.8 ms in a ROI including white and gray matter and CSF in a prefrontal brain region, and allowed validation of the quantitative results of the fast single-shot techniques. In functional experiments with motor stimulation mean absolute T(2)* increases during stimulation of 1.1 +/- 0.6 ms and 1.4 +/- 0.9 ms were found with multi-echo EPI and spiral imaging, respectively, averaged over the activated pixels. In addition, absolute T(2)* values and the size of activated areas obtained with both sequences are comparable. In these investigations spiral imaging allowed higher spatial resolution due to more efficient use of available gradient performance. 相似文献
27.
Kolbitsch C Lorenz IH Hörmann C Hinteregger M Löckinger A Moser PL Kremser C Schocke M Felber S Pfeiffer KP Benzer A 《Magnetic resonance imaging》2002,20(7):535-541
Conflicting results reported on the effects of hyperoxia on cerebral hemodynamics have been attributed mainly to methodical and species differences. In the present study contrast-enhanced magnetic resonance imaging (MRI) perfusion measurement was used to analyze the influence of hyperoxia (fraction of inspired oxygen (FiO2) = 1.0) on regional cerebral blood flow (rCBF) and regional cerebral blood volume (rCBV) in awake, normoventilating volunteers (n = 19). Furthermore, the experiment was repeated in 20 volunteers for transcranial Doppler sonography (TCD) measurement of cerebral blood flow velocity in the middle cerebral artery (CBFV(MCA)). When compared to normoxia (FiO2 = 0.21), hyperoxia heterogeneously influenced rCBV (4.95 +/- 0.02 to 12.87 +/- 0.08 mL/100g (FiO2 = 0.21) vs. 4.50 +/- 0.02 to 13.09 +/- 0.09 mL/100g (FiO2 = 1.0). In contrast, hyperoxia diminished rCBF in all regions (68.08 +/- 0.38 to 199.58 +/- 1.58 mL/100g/min (FiO2 = 0.21) vs. 58.63 +/- 0.32 to 175.16 +/- 1.51 mL/100g/min (FiO2 = 1.0)) except in parietal and left frontal gray matter. CBFV(MCA) remained unchanged regardless of the inspired oxygen fraction (62 +/- 9 cm/s (FiO2 = 0.21) vs. 64 +/- 8 cm/s (FiO2 = 1.0)). Finding CBFV(MCA) unchanged during hyperoxia is consistent with the present study's unchanged rCBF in parietal and left frontal gray matter. In these fronto-parietal regions predominantly fed by the middle cerebral artery, the vasoconstrictor effect of oxygen was probably counteracted by increased perfusion of foci of neuronal activity controlling general behavior and arousal. 相似文献
28.
Moser J Boscá F Lovell WW Castell JV Miranda MA Hye A 《Journal of photochemistry and photobiology. B, Biology》2000,58(1):13-19
Carprofen is a non-steroidal antiinflammatory drug with marked photosensitising properties. In order to elucidate the mechanisms underlying the phenomenon of drug-protein photobinding, mixtures of the drug and human serum albumin were irradiated under different experimental conditions. After irradiation and subsequent gel-filtration chromatography of the photomixture, the eluting protein fraction was analysed by means of fluorescence spectroscopy. The formation of drug-protein photoadducts could be evidenced by the characteristic emission properties of the carbazole chromophore. The photobinding of the drug to human serum albumin appears to involve the formation of aryl radicals resulting from carbon-halogen photocleavage. This mechanistic interpretation is supported by the observed variations in the intensity of the fluorescence spectra, which can be correlated with the lower quantum yield emission of chlorocarbazoles as compared to non-halogenated analogues. The results from laser flash photolysis studies are also in agreement with this proposal. 相似文献
29.
Diode-pumped passively mode-locked Nd:YAG laser with 10-W average power in a diffraction-limited beam 总被引:2,自引:0,他引:2
Spühler GJ Paschotta R Keller U Moser M Dymott MJ Kopf D Meyer J Weingarten KJ Kmetec JD Alexander J Truong G 《Optics letters》1999,24(8):528-530
We present a passively mode-locked Nd:YAG laser with 10.7-W average output power in a diffraction-limited beam. Stable self-starting mode locking with a pulse duration of 16 ps and a pulse energy of 120 nJ is obtained with a semiconductor saturable-absorber mirror. The laser is directly side pumped with two 20-W diode bars. Single-pass frequency doubling in an external 5-mm-thick KTP crystal yields 3.2-W average power at 532 nm. 相似文献
30.
Thomas Moser 《Compositio Mathematica》1999,117(2):123-152
Let X be an arbitrary variety over a finite field k and p=char k,n N. We will construct a complex of étale sheaves on X together with trace isomorphism from the highest étale cohomology group of this complex onto Z/pnZ such that for every constructible Z/pnZ-sheaf on X the Yoneda pairing is a nondegenerate pairing of finite groups. If X is smooth, this complex is the Gersten resolution of the logarithmic de Rham–Witt sheaf introduced by Gros and Suwa. The proof is based on the special case proven by Milne when the sheaf is constant and X is smooth, as well as on a purity theorem which in turn follows from a theorem about the cohomological dimension of Ci-fields due to Kato and Kuzumaki. If the existence of the Lichtenbaum complex is proven, the theorem will be the p-part of a general duality theorem for varieties over finite fields. 相似文献