Current Reversal Due to Coupling Between Asymmetrical Driving Force and Ratchet Potential

Transport of a Brownian particle moving in a periodic potential is investigated in the presence of an asymmetric unbiased external force. The asymmetry of the external force and the asymmetry of the potential are the two ways of inducing a net current. It is found that the competition of the spatial asymmetry of potential with the temporal asymmetry of the external force leads to the phenomena like current reversal. The competition between the two opposite driving factors is a necessary but not a sufficient condition for current reversals.     

In situ observation of NaBi(WO4)2 dendrite growth and the study on microstructure of solidification

The dendrite growth process of transparent NaBi(WO4)2 with small prandtl and high melting point was studied by using the in-situ observation system. According to the dynamic images and detailed information, there are two kinds of restriction effect on the dendrite growth, the competition between arms and branches and the convection in the melt. The dendrite growth rate was time dependent, and the rate of arm growth reached the maximum 5.8 mm/s in the diffusive-advective region and rapidly decreased in the diffusive-convective region. The growth rate of branch had the same change trends as the arm's. Based on the EPMA-EDS data of solidification structure of quenched NaBi(WO4)2 melt, it was found that there were component differences from stoichiometric concentration in the melt near the interface during the growth process.     

火焰辐射及偶丝导热对热电偶测温影响的数值分析

本文利用层流同向扩散乙烯火焰的数值模拟结果,根据所得的火焰温度场、气体速度场、火焰辐射场,分析火焰辐射、热电偶偶丝导热对热电偶测温的影响.结果表明在火焰的低温区火焰辐射要大于节点向外辐射,节点得到的能量要高于节点损失的能量,因此在火焰的低温区节点温度要高于当地的气体温度;同时直径为100μm的热电偶存在较大的导热,对节点温度测量有较大的影响.     

The Influence of the Renormalization Condition to the Equation of State of the Nuclear Matter

In the relativistic σ-ω model, the influences of the parameters b, c, d in the potential U(σ) = (1/2!)bo2 - -(1/3!)cσ3 (1/4!)dσ4 to the incompressibility, effective mass and binding energy of the nuclear matter are studied in detail.The calculation of equation of state of nuclear matter shows that the values of b, c, d depend on the renormalization condition, we also find that a soft equation of state of nuclear matter can be obtained in a suitable renormalization condition, and the experimental incompressibility coefficient can be reproduced. These results are also used to study the thermal properties of hot A-resonant nuclear matter.self-interaction of σ meson, renormalization, hot and dense hadronic matter ``     

超细激光束准直器设计的新数学模型

为了获取长距离超细激光束，采用几何能量守恒法设计出一种衍射光学元件，推导出高斯光入射时衍射光学元件位相函数。根据建立的数学模型，设计超细激光束准直器，并模拟高斯光入射时出射激光束的光斑形状及光强分布，最后计算了能量利用率。     

Influence of Process Parameters on the Reaction Kinetics of the Chromium‐Catalyzed Trimerization of Ethylene

In this paper we report the results of an extensive experimental kinetic study carried out on the novel ethylene trimerization catalyst system, comprising the chromium source [CrCl₃(thf)₃] (thf=tetrahydrofuran), a Ph₂P‐N(iPr)‐P(Ph)‐N(iPr)H (PNPNH) ligand (Ph=phenyl, iPr=isopropyl), and triethylaluminum (AlEt₃) as activator. It could be shown that the initial activity shows a first‐order dependency on the ethylene concentration. Also, a first‐order dependency was found for the catalyst concentration. The initial activity follows a typical Arrhenius behavior with an experimentally determined activation energy of 52.6 kJ mol^?1. At elevated temperatures (ca. 80 °C), a significant deactivation was observed, which can be tentatively traced back to a ligand rearrangement in the presence of AlEt₃. After a fast initial phase, a pronounced ‘kink’ in the ethylene‐uptake curve is observed, followed by a slow, almost linear, further increase of the total ethylene consumption. The catalyst composition, in particular the ligand/chromium and the cocatalyst/chromium molar ratio, has a strong impact on the catalytic performance of the trimerization of ethylene.     

基于LED的色度学实验研究

作为环保、节能、可智能控制的新型光源,发光二极管（LED）广泛应用于人们的现代生活、生产中,更有望替代传统的照明光源。以三基色LED为光源,制作了三路独立可调恒流电源,通过调节三基色光的不同配比实现加法混色,研究设计了加法混色的色度学实验,既可以直接观察混色后的实验现象,又能通过测量光谱数据得到色度参数。LED光源环保...     

Chiral N-phosphonyl imine chemistry:asymmetric additions of glycine enolate to diphenyl diamine-based phosphonyl imines

Diphenyl diamine-based phosphonyl imines attached by the N-isopropyl group in the auxiliary have been synthesized in good yields under convenient reaction conditions.These new chiral N-phosphonyl imines can react with glycine enolate smoothly to give chiral α-β diamino esters in good yields(72%-90%) and up to excellent diastereoselectivity(>99:1 dr).By treatment with HBr,the chiral auxiliary can be readily removed.The absolute structure has been unambiguously determined by converting a product to a known sa...     

深圳某电厂H型钢桩沉桩与效果测试

在上部为花岗岩块石填土、下部为相对软弱的粘性土 ,地下水与海水相通的地区进行大型工程建设 ,主要建 (构 )筑物采用桩基础是安全可靠的措施 ,但采用何种桩型、沉桩时怎样才能顺利穿过花岗岩块石填土是一个值得研究的课题。采用潜孔锤引孔穿过花岗岩块石填土 ,往孔内回填碎石 ,然后打H型钢桩 ,在深圳某电厂地基处理中获得了较好的效果     

顶空气相色谱-质谱联用结合同位素峰形校正检索技术鉴别芝麻油风味成分

采用顶空气相色谱-质谱联用(GC-MS)仪结合同位素峰形校正检索技术鉴别了市售芝麻油风味成分中的71种化合物,占总检出化合物的90.2%。检出化合物可分为吡嗪、吡咯、吡啶、噻唑、噻吩、吲哚、唑、呋喃、醛类和酚类等,其中醛、酚、吡嗪和呋喃类化合物的含量较高,分别占风味成分含量的37.4%,20.1%,10.0%和6.7%。同位素峰形校正检索技术在低分辨率质谱上可对化合物的相对分子质量实现精确测量,从而为低分辨率四极杆质谱确定化合物的元素组成和解析化合物结构提供了重要依据,同时也为芝麻油的成分分析提供了新的技术手段。