全文获取类型
收费全文 | 692篇 |
免费 | 33篇 |
国内免费 | 15篇 |
专业分类
化学 | 485篇 |
晶体学 | 2篇 |
力学 | 44篇 |
数学 | 89篇 |
物理学 | 120篇 |
出版年
2023年 | 2篇 |
2022年 | 9篇 |
2021年 | 14篇 |
2020年 | 32篇 |
2019年 | 28篇 |
2018年 | 38篇 |
2017年 | 34篇 |
2016年 | 61篇 |
2015年 | 39篇 |
2014年 | 45篇 |
2013年 | 102篇 |
2012年 | 55篇 |
2011年 | 75篇 |
2010年 | 32篇 |
2009年 | 37篇 |
2008年 | 28篇 |
2007年 | 25篇 |
2006年 | 11篇 |
2005年 | 14篇 |
2004年 | 11篇 |
2003年 | 18篇 |
2002年 | 11篇 |
2001年 | 4篇 |
2000年 | 2篇 |
1996年 | 1篇 |
1995年 | 1篇 |
1994年 | 2篇 |
1990年 | 2篇 |
1989年 | 1篇 |
1988年 | 1篇 |
1987年 | 2篇 |
1984年 | 1篇 |
1976年 | 2篇 |
排序方式: 共有740条查询结果,搜索用时 203 毫秒
81.
Saeed Balalaie Morteza Ashouriha Frank Rominger Hamid Reza Bijanzadeh 《Molecular diversity》2013,17(1):55-61
A three-component reaction of 3-formyl chromones, dialkyl acetylenedicarboxylate, and isocyanides in the presence of $\text{ POCl}_{3}$ was used as a highly efficient and practical approach for the synthesis of 3-amino-5-chromenyl-butenolides. High yields and high bond forming efficiency, and simple operations are the advantages of this method. Graphical abstract 相似文献
82.
Qamar Salamat Yadollah Yamini Morteza Moradi Abolfazl Farahani Neda Feizi 《Journal of separation science》2019,42(8):1620-1628
In the present study, a supramolecular solvent was formed from reverse micelle aggregates of octanol. The proposed supramolecular solvent was used for rapid extraction of some antidepressants drugs including amitriptyline, imipramine, desipramine, maprotiline, sertraline, and doxepin from biological samples. Alkanol‐based supramolecular solvents have a unique array of physicochemical properties, making them a very attractive alternative to replace organic solvents in analytical extractions. The parameters affecting the extraction of target analytes (i.e., the volume of tetrahydrofuran and octanol as the major components comprising the supramolecular solvent, chain length of alkanols, sample solution pH, salt addition, and ultrasonic time) were investigated and optimized by factor by factor optimization method. Under the optimum conditions, preconcentration factors of 470, 490, 460, 385, 370, and 430 were obtained for amitriptyline, doxepin, imipramine, desipramine, maprotiline, and sertraline, respectively. The linear ranges and coefficients of determination (R2) were obtained in the range of 0.01–100 μg/L and 0.9974–0.9991, respectively. Also the limits of detection (S/N = 3) of 0.003–0.03 μg/L, and precisions (n = 5) of 4.9–8.9% were calculated. Finally, the method was successfully applied for the extraction of antidepressant drugs in biological samples, and relative recoveries in the range of 91–102% were obtained. 相似文献
83.
Morteza Mohseni 《International Journal of Theoretical Physics》2008,47(4):1079-1082
We introduce a Lagrangian which can be varied to give both the equation of motion and world-line deviations of spinning particles
simultaneously. 相似文献
84.
S. Akbari M. Dalirrooyfard K. Ehsani K. Ozeki R. Sherkati 《Journal of Graph Theory》2020,93(4):483-502
Let be a graph and be a mapping. The graph is said to be - avoiding if there exists an orientation of such that for every , where denotes the out-degree of in the directed graph with respect to . In this paper it is shown that if is bipartite and for every , then is -avoiding. The bound is best possible. For every graph , we conjecture that if for every , then is -avoiding. We also argue about this conjecture for the best possibility of the conditions and also show some partial solutions. 相似文献
85.
86.
This review gives an overview of the electrochemical investigations about the properties of various types of graphene composites in the ethanol oxidation. Various routes to provide appropriate graphene‐based materials required electrochemical techniques for investigation of different types of the materials as well as their performance and efficacy in ethanol oxidation are discussed in detail. Furthermore, it is demonstrated that the incorporation of suitable materials, e. g. noble metals (graphene‐supported binary and ternary metal nanoparticles), metal oxides, conductive polymer, etc, with graphene results in excellent electrocatalytic activity, superb durability and selectivity in ethanol oxidation. Immobilization of electrocatalytically active NPs on graphene supports using physical approaches is considered as an effective route to prepare direct ethanol fuel cell (DEFC) anode catalysts. 相似文献
87.
88.
First-principles calculations including dispersion correction are carried out to investigate pristine and Na-decorated graphene-like BC3 (h-BC3) for their application as methane storage materials. Structural optimization shows that the methane is physisorbed on the pristine sheet via van der Waals forces with adsorption energy of ?2.7 kcal/mol. It was found that unlike the pristine graphene, sodium decorated sheet can effectively interact with the CH4 molecule, so that each metal atom bound on sheet may adsorb up to four CH4. Furthermore, no bond dissociation was observed for the adsorption of CH4 on Na-decorated h-BC3, which means that decorated sheet can act as a storage device for methane safety storage. The results indicate that decoration of the Na atom on surface of sheet induces significant changes in electronic properties of the sheet and its E g is unchanged after adsorption of CH4 molecules. Theoretical methane storage capacity of Na-decorated BC3 nanosheet could approach 18.1 wt%. 相似文献
89.
90.
Nafiseh Mansouriieh Mahmoud Reza Sohrabi Morteza Khosravi 《Arabian Journal of Chemistry》2019,12(8):2524-2532
This study synthesized bimetallic Fe/Ni nanoparticles and used them for catalytic degradation of profenofos, an organophosphorus pesticide. This novel bimetallic catalyst (Fe/Ni) was characterized by scanning electron microscopy (SEM), energy-dispersive X-ray analysis spectroscopy (EDAX) and X-ray diffraction (XRD). The bimetallic nano-catalyst was prepared at diameters of 20–50 nm and was shown to effectively degrade profenofos. A three-factor central composite design combined with response surface methodology was used to maximize profenofos removal using the bimetallic system. A quadratic model was built to predict degradation efficiency. ANOVA was used to determine the significance of the variables and interactions between them. Good correlation between the experimental and predicted values was confirmed by the high F-value (16.38), very low P-value (<0.0001), non-significant lack of fit, an appropriate coefficient of determination (R2 = 0.936) and adequate precision (14.75). The highest removal rate attained was 94.51%. 相似文献