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91.
Oxidative electrochemical detection is used for liquid chromatographic separation of polynuclear aromatic hydrocarbons (PAH's). The amperometric response is shown to be dependent on the working potential, ionic strength, flow rate, pH, temperature and pretreatment of the glassy carbon electrode surface. These experimental factors were optimized by choosing the maximum signal-to-noise ratio for anthracene and benz(a)-anthracene. The figures of merit (sensitivity, limit of detection and linear dynamic range) of six PAH's are reported and compared with ultraviolet absorption detection. Varying the applied potential gives the capability for selective detection. 相似文献
92.
Tungstate sulfuric acid (TSA)/KMnO4 as a novel heterogeneous system for rapid deoximation 总被引:1,自引:0,他引:1
Neat chlorosulfonic acid reacts with anhydrous sodium tungstate to give tungstate sulfuric acid (TSA), a new dibasic inorganic solid acid in which two sulfuric acid molecules connect to a tungstate moiety via a covalent bond. A variety of oximes were oxidized to their parent carbonyl compounds under mild conditions with excellent yields in short times by a heterogeneous wet TSA/KMnO4 in dichloromethane system. 相似文献
93.
94.
95.
Morteza Moniri 《Archive for Mathematical Logic》2010,49(3):291-300
In this paper we prove conservation theorems for theories of classical first-order arithmetic over their intuitionistic version.
We also prove generalized conservation results for intuitionistic theories when certain weak forms of the principle of excluded
middle are added to them. Members of two families of subsystems of Heyting arithmetic and Buss-Harnik’s theories of intuitionistic
bounded arithmetic are the intuitionistic theories we consider. For the first group, we use a method described by Leivant
based on the negative translation combined with a variant of Friedman’s translation. For the second group, we use Avigad’s
forcing method. 相似文献
96.
Morteza Sadeghi Homayoon Moadel Somaieh Khatti Behnam Ghalei 《Journal of Macromolecular Science: Physics》2013,52(6):1128-1135
The sorption behaviors of sulfuric, perchloric, and phosphoric acids in polybenzimidazole membranes have been investigated. The results of sorption isotherms are consistent with the general form of a dual-mode sorption isotherm. The dual-mode sorption parameters were found using a least-squares program by fitting experimental data to a dual-mode equation. Results indicate a correlation between permeant properties like acidity, size, and the affinity constant in Langmuir-mode sorption species. Moreover, the results show that the size of the permeants has the dominant effect on Henry's constant. The obtained results for , site saturation constant, in Langmuir-mode sorption in the case of perchloric and phosphoric acids, reveals that the two acid molecules interact with two N?H basic groups in the polybenzimidazole repeat units. But in the case of sulfuric acid, it is shown that sulfuric acid neutralizes some of the basic groups in the polymer by its strong second hydrogen and the obtained value for was 1.25. 相似文献
97.
98.
Ali Rahmatpour Mahdi Abdollahi Mehrdad Shojaee 《Journal of Macromolecular Science: Physics》2013,52(3):523-531
A blend/clay nanocomposites of 50/50 (wt%) NR/SBR was prepared via mixing the latex of a 50/50 NR/SBR blend with an aqueous clay dispersion and co‐coagulating the mixture. The structure of the nanocomposite was characterized by transmission electron microscopy (TEM) and X-ray diffraction (XRD). Nanocomposites containing less than 10 phr clay showed a fully exfoliated structure. After increasing the clay content to 10 phr, both nonexfoliated (stacked layers) and exfoliated structures were observed in the nanocomposites. The results of mechanical tests showed that the nanocomposites presented better mechanical properties than clay‐free NR/SBR blend vulcanizate. Furthermore, tensile strength, tensile strain at break, and hardness (shore A) increased with increasing clay content, up to 6 phr, and then remained almost constant. 相似文献
99.
Let G be a non-abelian group and Z(G) be the center of G. The non-commuting graph Γ G associated to G is the graph whose vertex set is G?Z(G) and two distinct elements x, y are adjacent if and only if xy ≠ yx. We prove that if G and H are non-abelian nilpotent groups with irregular isomorphic non-commuting graphs, then |G| = |H|. 相似文献
100.
In this note we show that if Gis a finitely generated soluble group, then every infinite subset of Gcontains two elements generating a nilpotent group of class at most kif and only if Gis finite by a group in which every two generator subgroup is nilpotent of class at most k. 相似文献