Effect of secondary orientation on notch-tip plasticity in superalloy single crystals

Numerical and experimental evolutions of slip fields in notched Ni-Base Single Crystal superalloy tensile specimens are presented as a function of secondary crystallographic orientation. The numerical predictions based on three-dimensional anisotropic elasticity and crystal plasticity are compared with experimental observations. The results illustrate the strong dependence of the slip patterns and the plastic zone size and shape on the secondary orientation of notches, which can have important consequences on crack initiation. Specific orientations or non-symmetric notch geometries lead to non-symmetric patterns on both sides of the sample. The computations show that strongly different plastic zones are expected in the core of the sample and at free surfaces. The ability of the anisotropic elastic model to anticipate the plastic domains, based on identifying dominant slip systems, is confirmed by the crystal plasticity computations, at low load levels. An important observation is that kink shear banding is a real deformation mode operating at crack tips and notches in high strength nickel-based single crystal superalloys for specific orientations.     

Numerical investigation of premixed combustion in a porous burner with integrated heat exchanger

In this paper, we perform a numerical analysis of a two-dimensional axisymmetric problem arising in premixed combustion in a porous burner with integrated heat exchanger. The physical domain consists of two zones, porous and heat exchanger zones. Two dimensional Navier–Stokes equations, gas and solid energy equations, and chemical species transport equations are solved and heat release is described by a multistep kinetics mechanism. The solid matrix is modeled as a gray medium, and the finite volume method is used to solve the radiative transfer equation to calculate the local radiation source/sink in the solid phase energy equation. Special attention is given to model heat transfer between the hot gas and the heat exchanger tube. Thus, the corresponding terms are added to the energy equations of the flow and the solid matrix. Gas and solid temperature profiles and species mole fractions on the burner centerline, predicted 2D temperature fields, species concentrations and streamlines are presented. Calculated results for temperature profiles are compared to experimental data. It is shown that there is good agreement between the numerical solutions and the experimental data and it is concluded that the developed numerical program is an excellent tool to investigate combustion in porous burner.     

Evaluation of Native and Chemically Modified Sargassum glaucescens for Continuous Biosorption of Co(II)

In the present study, biosorption of stable cobalt was studied in an up-flow fixed-bed column using the brown alga Sargassum glaucescens treated with formaldehyde (FA) or MgCl₂. Notable increase in cobalt removal was observed for FA-treated biosorbent with 2.7 and 1.4 times higher dynamic capacity (DC) and uptake capacity (UC) than native alga, respectively. Consequently, FA-treated S. glaucescens was selected for further investigations. In particle size experiments, the DCs of 0.5–1 and 1–2 mm particles were both equal to 27.6 mg/g, and corresponding UCs were 34 and 38 mg/g, respectively. The maximum DC was obtained at residence time of 2.5 min. Studying the effect of additional ions indicated partial effect of Na⁺ and K⁺ ions on DC and UC, Mg²⁺ reduced highly the DC and slightly the UC while heavy metal ions (Ni²⁺, Cd²⁺, Cu²⁺, Zn²⁺, Pb²⁺ and Cr³⁺) caused decrease in both DC and UC about 1.5–4.7 and 1.8–3.2 times, respectively. Moreover, the column regeneration studies were carried out for four sorption–desorption cycles. The DC and the UC highly decreased in the second cycle, partially decreased or remained constant in the third and in the fourth one.     

Quintessence Reconstruction of Interacting HDE in a Non-Flat Universe

In this paper we consider quintessence reconstruction of interacting holographic dark energy in a non-fiat background. As system＇s IR cutoff we choose the radius of the event horizon measured on the sphere of the horizon, defined as L = at（t）. To this end we construct a quintessence model by a real, single scalar field. Evolution of the potential, V（φ）, as well as the dynamics of the scalar field, φ, is obtained according to the respective holographic dark energy. The reconstructed potentials show a cosmological constant behavior for the present time. We constrain the model parameters in a fiat universe by using the observational data, and applying the Monte Carlo Markov chain simulation. We obtain the best fit values of the holographic dark energy model and the interacting parameters as c=1.0576-0.6632-0.6632^＋0.3010＋0.3052 and ζ =0.2433-0.2251-.2251^＋0.6373＋0.6373 , respectively. From the data fitting results we also find that the model can cross the phantom line in the present universe where the best fit value of the dark energy equation of state is WD=-1.2429.     

Essentiality and Injectivity

Essentiality is an important notion closely related to injectivity. Depending on a class M\mathcal M of morphisms of a category A{\mathcal A}, three different types of essentiality are considered in literature. Each has its own benefits in regards with the behaviour of M\mathcal M-injectivity. In this paper we intend to study these different notions of essentiality and to investigate their relations to injectivity and among themselves. We will see, among other things, that although these essential extensions are not necessarily equivalent, they behave almost equivalently with regard to injectivity.     

Numerical simulation of methane partial oxidation in the burner and combustion chamber of autothermal reformer

This study aims to model the methane partial oxidation process in the burner and combustion chamber of autothermal reactor. The numerical simulation based on this model offers a powerful tool that can assist in reactor design and optimization and scale up of the process saving expensive pilot work. The steady-state governing equations were solved using the SIMPLE algorithm and the effect of turbulence on the mean flow field was accounted for using the RNG k–ε model. A two-step reaction mechanism was used for the gas combustion with CO as the intermediate species. The reaction rates were modeled using an Eddy-Dissipation Model. In terms of the geometrical model, a 3D model for burner was developed while an axis-symmetric model for the combustion chamber was implemented to reduce the computational costs. The model formulated was validated against a currently operating autothermal reactor and then has been used to investigate different aspects of these reactors. Results show that effect of oxygen to methane ratio is more than that of feed temperature. It is demonstrated that a 60% increase in O₂/CH₄ ratio causes a 15.4% decrease and 42.7% increase in H₂/CO ratio and methane conversion, respectively. In contrast, a 60% increase in feed temperature does not have a significant effect on the process.     

Modelling the yield point phenomena during deformation at elevated temperatures: case study on Inconel 600

The discontinuous yield behaviour (DYB) of Inconel 600 was studied during hot compression tests at temperatures in range of 850–1150°C and strain rates of 0.001–1?s^?1. The yield point phenomena were observed in the temperature range of 850–1000°C and strain rates of 0.001–0.1 s^?1. The DYB was modelled by considering the evolution of dislocation density at the early stages of yielding. The opposite effects of dislocation multiplication, dislocation interaction (work hardening) and dynamic recovery (DRV) were considered. It was shown that the dislocation multiplication and DRV result in flow softening, while the dislocation interaction leads to work hardening. The model was established in a way to consider the effects of various microstructural evolutions on the σ(ε) function. The discontinuous flow curves were fitted by the developed model with acceptable precision. The variations of material constants with temperature and strain rate were found physically meaningful. The dislocation multiplication parameter was determined at various temperatures and strain rates. It was concluded that the rate of dislocation multiplication increases as temperature rises or strain rate declines. Accelerated dislocation multiplication leads to less drop in yield stress between the upper and lower yield points.     

Strain-dependent deformation behavior in nanocrystalline metals

The deformation behavior as a function of applied strain was studied in a nanostructured Ni-Fe alloy using the in situ synchrotron diffraction technique. It was found that the plastic deformation process consists of two stages, undergoing a transition with applied strain. At low strains, the deformation is mainly accommodated at grain boundaries, while at large strains, the dislocation motion becomes probable and eventually dominates. In addition, current results revealed that, at small grain sizes, the 0.2% offset criterion cannot be used to define the macroscopic yield strength any more. The present study also explained the controversial observations in the literature.