全文获取类型
收费全文 | 1502篇 |
免费 | 63篇 |
国内免费 | 14篇 |
专业分类
化学 | 889篇 |
晶体学 | 10篇 |
力学 | 60篇 |
数学 | 265篇 |
物理学 | 355篇 |
出版年
2023年 | 10篇 |
2022年 | 17篇 |
2021年 | 22篇 |
2020年 | 24篇 |
2019年 | 28篇 |
2018年 | 19篇 |
2017年 | 20篇 |
2016年 | 32篇 |
2015年 | 29篇 |
2014年 | 36篇 |
2013年 | 59篇 |
2012年 | 57篇 |
2011年 | 76篇 |
2010年 | 39篇 |
2009年 | 32篇 |
2008年 | 52篇 |
2007年 | 65篇 |
2006年 | 68篇 |
2005年 | 88篇 |
2004年 | 67篇 |
2003年 | 42篇 |
2002年 | 37篇 |
2001年 | 22篇 |
2000年 | 29篇 |
1999年 | 21篇 |
1998年 | 25篇 |
1997年 | 17篇 |
1996年 | 26篇 |
1995年 | 15篇 |
1994年 | 16篇 |
1993年 | 27篇 |
1992年 | 20篇 |
1991年 | 17篇 |
1990年 | 25篇 |
1989年 | 17篇 |
1988年 | 21篇 |
1987年 | 17篇 |
1985年 | 22篇 |
1984年 | 18篇 |
1983年 | 16篇 |
1982年 | 16篇 |
1981年 | 19篇 |
1980年 | 26篇 |
1979年 | 11篇 |
1978年 | 19篇 |
1977年 | 20篇 |
1976年 | 11篇 |
1975年 | 22篇 |
1974年 | 21篇 |
1973年 | 13篇 |
排序方式: 共有1579条查询结果,搜索用时 15 毫秒
71.
Raghida Bou Zerdan Zhishuai Geng Benjaporn Narupai Yvonne J. Diaz Morgan W. Bates David S. Laitar Biswas Souvagya Antony K. Van Dyk Craig J. Hawker 《Journal of polymer science. Part A, Polymer chemistry》2020,58(14):1989-1997
The utility of pentafluorophenyl esters for the selective introduction of functional units and branch points in well-defined poly(acrylic acid) (PAA) derivatives is demonstrated using a combination of controlled radical polymerization and postpolymerization modification. Reversible addition-fragmentation chain transfer enables the synthesis of well-defined copolymers—poly(pentafluorophenyl acrylate-co-tert-butyl acrylate)—with the active ester repeat units serving as attachment points for reaction with primary amines, specifically tris(2-(t-butoxycarbonyl)ethyl)methyl amine (Behera's amine). Deprotection using trifluoroacetic acid removes both the backbone and side chain t-butyl esters to give a series of branched PAA derivatives containing novel tricarboxylic acid side chains that are well suited to complexation and multidentate interactions. Surprisingly, the active ester homopolymer is shown to have the highest reactivity with Behera's amine when compared to copolymers with lower incorporation of pentafluorophenyl esters, suggesting an intriguing interplay of neighboring group effects and steric interactions. The ability to tune the efficiency of postpolymerization modification gives a library of PAA derivatives. 相似文献
72.
73.
Brienne N. Seiner Shannon M. Morley Tere A. Beacham Morgan M. Haney Stephanie Gregory Lori Metz 《Journal of Radioanalytical and Nuclear Chemistry》2014,302(1):673-678
The purpose of this work was to determine polonium losses from a variety of sample types (soil, cotton fiber, and air filter) due to digestion technique, chemical separation, and deposition method for alpha energy analysis. Results demonstrated that yields from a perchloric acid wet-ash (87 ± 5 %) were similar to that from a microwave digestion (100 ± 7 %), but both were greater than the dry-ash procedure (38 ± 5 %). The polonium was separated from an SRM soil using an AG1X8 ion exchange column and deposited on a Ag disk with a recovery of 83 ± 7 % of polonium-209 (Po-209). Deposition yields without chemical separation averaged 90 ± 5 % of Po-209. The polonium-210 content was successfully measured in the three matrix types and quantitated using alpha spectroscopy. 相似文献
74.
75.
Morgan A. Higgins Christopher R. Maroon Jacob Townsend Xinyi Wang Konstantinos D. Vogiatzis Brian K. Long 《Journal of polymer science. Part A, Polymer chemistry》2020,58(18):2644-2653
Polymeric membranes have shown tremendous promise for the separation of CO2 from flue gas streams. However, few systematic studies have been conducted to better understand the impact that chemical functionalities have on membrane-based gas separation performance. To address this gap, we herein describe the synthesis and gas separation performance of a series of vinyl-addition polynorbornenes bearing various CO2-philic functional groups. To facilitate direct comparison between functional groups, each material was designed to maintain a common polymer backbone. Though the incorporation of CO2-philic moieties within a dense polymeric membrane is frequently hypothesized to enhance CO2 solubility, and thereby increase CO2/N2 selectivity, our results demonstrate that the incorporation of CO2-philic groups onto a common polymer backbone do not necessarily result in increased gas separation performance. Experimental and computational results demonstrate that the incorporation of amidoxime groups onto a polynorbornene backbone increase CO2/N2 selectivity, whereas commonly employed ethereal side chains only increased permeability. 相似文献
76.
77.
An overall three step preparation of the bis-diimine bridging ligand 4,7-phenanthrolino-5,6:5′,6′-pyrazine (ppz, 1) from 2-methoxy-1,4-phenylenediamine hydrosulfate 4 is reported. 相似文献
78.
Alkoxyallene‐ynes: Selective Preparation of Bicyclo[5.3.0] Ring Systems Including a δ‐Alkoxy Cyclopentadienone 下载免费PDF全文
Dr. Aurélien Tap Camille Lecourt Sabrina Dhambri Mathieu Arnould Dr. Gilles Galvani Dr. Olivier Nguyen Van Buu Dr. Morgan Jouanneau Dr. Jean‐Pierre Férézou Prof. Janick Ardisson Dr. Marie‐Isabelle Lannou Dr. Geoffroy Sorin 《Chemistry (Weinheim an der Bergstrasse, Germany)》2016,22(14):4938-4944
The development of an intramolecular rhodium(I)‐catalyzed Pauson–Khand reaction of alkoxyallene‐ynes with a proximal alkoxy group is reported. This reaction, in the presence of a [Rh(cycloocta‐1,5‐diene)Cl]2/propane‐1,3‐diylbis(diphenylphosphane) system under a CO atmosphere, constitutes a powerful tool for selectively accessing carbo‐ and heterobicyclo[5.3.0] frameworks featuring an enol ether moiety. Through this procedure, a straightforward access to guaiane skeletons with a tertiary hydroxy group at the C10 position was achieved. 相似文献
79.
M. Morgan H. M. D. R. Herath P. J. Cabot P. N. Shaw A. K. Hewavitharana 《Analytical and bioanalytical chemistry》2012,404(10):3111-3121
Dynorphin A 1–17 (DYN A) is an endogenous neuropeptide that is of interest due to its diverse roles in analgesia, inflammation and addiction. Upon release, DYN A is subject to metabolism by a range of enzymes and its biotransformation is dependent on the site and environment into which it is released. In this study, we investigated the biotransformation of DYN A in rat inflamed tissue at pH?7.4 and 5.5, in rat serum and in trypsin solution. DYN A-porcine was incubated at 37?°C in each matrix over a range of incubation periods. The resultant fragments were separated using a C4 column and detected by mass spectrometry using total ion current mode. Incubation of DYN A in trypsin solution and in rat serum resulted in 6 and 14 fragments, respectively. Incubation in inflamed rat paw tissue occasioned 21 fragments at pH?7.4 and 31 fragments at pH?5.5. Secondary breakdown of some larger primary fragments was also observed in this study. 相似文献
80.
We report the synthesis of three new dipyrrinone imine analogues and the characterisation of their self-association properties. Based on vapour pressure osmometry and nuclear magnetic resonance studies, placing the imine functional group at C(9) of the dipyrrinone disrupts the native self-association of the dipyrrinone core in a manner that correlates with the conformational A-value of the imine N-substituent. 相似文献