Systematic investigations of anthocyanin–metal interactions by Raman spectroscopy

The FT‐Raman spectra of the chloride salts of pelargonidin‐3‐glucoside, cyanidin‐3‐glucoside and delphinidin‐3‐glucoside, their structures at pH 5.0 and their interaction with aluminium and ferric ions are presented for the first time and discussed with regard to their spectroscopic response. Two marker bands at approximately 1510 and 1330/1350 cm⁻¹ and one band at approximately 1330/1350 cm⁻¹ were identified being characteristic for the formation of ferric and aluminium chelates, respectively, of cyanidin‐3‐glucoside and delphinidin‐3‐glucoside. In contrast, pelargonidin‐3‐glucoside, exhibiting one single hydroxyl group in the B‐ring, did not form metal chelates, which could be clearly demonstrated by missing marker bands. The formation of anthocyanin–metal chelates was also verified in model systems containing commercial sugar beet pectin and a pectic polysaccharide fraction isolated thereof, respectively. In addition, the absence of anthocyanin–metal chelates in systems prepared with citrate buffer was confirmed, and the effects of low and high methoxylated citrus pectins on chelate formation were studied. Copyright © 2012 John Wiley & Sons, Ltd.     

Mass Spectrometry of Some Benzylidene Imidazolidinediones and Thiazolidinediones. II- chlorobenzyl imidazolidinedione and Fluoro or Chlorobenzyl Thiazolidinedione Compounds

In the present investigation, a study of the electron impact mass spectrometry data is reported for seven compounds of a series of some 3-(4-chlorobenzyl)-5-benzylidene-imidazolidine-2, 4-diones and 3-(4-fluoro or chlorobenzyl)-5-benzylidene-thiazolidine-2, 4-diones previously synthesized.     

Poisson–Boltzmann for oppositely charged bodies: an explicit derivation

The interaction between two parallel charged plates in ionic solution is a general starting point for studying colloidal complexes. An intuitive expression of the pressure exerted on the plates is usually proposed, which includes an electrostatic plus an osmotic contribution. We present here an explicit and self-consistent derivation of this formula in the only framework of the Poisson–Boltzmann (PB) theory. We also show that, depending on external constraints, the correct thermodynamic potential can differ from the usual PB free energy. For asymmetric, oppositely charged plates, the resulting expression predicts a non-trivial equilibrium position with the plates separated by a finite distance. The depth of this energy minimum is decisive for the stability of the complex. It is therefore crucial to obtain its explicit dependence on the charge densities of the plates and on the ion concentration. Analytic expressions for the position and depth of the energy minimum were derived in 1975 by Ohshima [Colloid Polym. Sci. 253, 150 (1975)] but, surprisingly, these important results seem to have been overlooked. We retrieve these expressions in a simpler formalism, more familiar to the physics community, and give a physical interpretation of the observed behavior.     

State transitions and the continuum limit for a 2D interacting, self-propelled particle system

We study a class of swarming problems wherein particles evolve dynamically via pairwise interaction potentials and a velocity selection mechanism. We find that the swarming system undergoes various changes of state as a function of the self-propulsion and interaction potential parameters. In this paper, we utilize a procedure which connects a class of individual-based models to their continuum formulations and determine criteria for the validity of the latter. H-stability of the interaction potential plays a fundamental role in determining both the validity of the continuum approximation and the nature of the aggregation state transitions. We perform a linear stability analysis of the continuum model and compare the results to the simulations of the individual-based one.     

Accurate Design of Finline Tapers for Millimeter Wave Applications

The design of nonuniform bilateral finlines on anisotropic substrates for millimeter wave applications is presented. The taper consists of a planar circuit with smooth variation of the slot width profile along the structure. The spectral domain method and Galerkin procedure are combined with the transmission line theory for studying the behavior of tapered bilateral finlines and evaluation of their design parameters. The influence of the substrate anisotropy on the propagation characteristics of these structures is also examined. This technique is general and can be applied to investigate a broad class of planar transmission line tapers.     

Modulation of humoral immune response to oral BCG vaccination by Mycobacterium bovis BCG Moreau Rio de Janeiro (RDJ) in healthy adults

We hypothesize that the energy strategy of a cell is a key factor for determining how, or if, the immune system interacts with that cell. Cells have a limited number of metabolic states, in part, depending on the type of fuels the cell consumes. Cellular fuels include glucose (carbohydrates), lipids (fats), and proteins. We propose that the cell's ability to switch to, and efficiently use, fat for fuel confers immune privilege. Additionally, because uncoupling proteins are involved in the fat burning process and reportedly in protection from free radicals, we hypothesize that uncoupling proteins play an important role in immune privilege. Thus, changes in metabolism (caused by oxidative stresses, fuel availability, age, hormones, radiation, or drugs) will dictate and initiate changes in immune recognition and in the nature of the immune response. This has profound implications for controlling the symptoms of autoimmune diseases, for preventing graft rejection, and for targeting tumor cells for destruction.     

Stable isotope analysis of white-tailed deer teeth as a paleoenvironmental proxy at the Maya site of La Joyanca,northwestern Petén,Guatemala*

ABSTRACT

Carbon and oxygen isotopes ratios from herbivore teeth have previously been used as paleo-environmental proxies in temperate zones. However, their utility in tropical zones remains uncertain. In this study, sequential sub-samples from white-tailed deer (Odocoileus virginianus) teeth (second and third molars) from the Maya archaeological site of La Joyanca, located in northwestern Petén, Guatemala, show that δ¹⁸O of enamel carbonate corresponds broadly to modern observed precipitation δ¹⁸O over the 10-month period of tooth formation, capturing rainfall seasonality. The analyses also detect significant diachronic differences in the δ¹⁸O between the periods 1100–1000 BP (850–950 A.D.) and 1000–900 BP (950–1050 A.D.) at La Joyanca. The δ¹³C in both periods are indicative of a C₃-plant based diet, which suggests cultivation of maize did not differentially affect deer diet during this period.     

Colour diversification in octocorals based on conjugated polyenes: A Raman spectroscopic view

Polyenic pigments in octocorals have been investigated by Raman spectroscopy using laser excitation at 532, 785 and 1064 nm. The spectral features suggest the structural nature of carotenoids from Phyllogorgia dilatata, Leptogorgia punicea, Muricea atlantica, Carijoa riisei and conjugated polyenals from L. punicea, L. setacea, Muricea flamma and Renilla muelleri. The observed vibrational bands at ca. 1540–1520 ν₁(C=C), 1159 ν₂(C–C) and 1005 cm⁻¹ ρ₃(C–CH₃) were assigned to carotenoids, whereas the identification of non‐methylated conjugated polyenals have been proposed due to two major Raman bands at ca. 1500 and 1120 cm^‐1, assigned to ν(C=C) and ν(C–C), respectively. Copyright © 2012 John Wiley & Sons, Ltd.     

A high-voltage lithium-ion battery prepared using a Sn-decorated reduced graphene oxide anode and a LiNi<Subscript>0.5</Subscript>Mn<Subscript>1.5</Subscript>O<Subscript>4</Subscript> cathode

This paper describes the preparation and characterization of a high-voltage lithium-ion battery based on Sn-decorated reduced graphene oxide and LiNi_0.5Mn_1.5O₄ as the anode and cathode active materials, respectively. The Sn-decorated reduced graphene oxide is prepared using a microwave-assisted hydrothermal synthesis method followed by reduction at high temperature of a mixture of (C₆H₅)₂SnCl₂ and graphene oxide. The so-obtained anode material is characterized by thermogravimetric analysis, X-ray diffraction, scanning electron microscopy, and electron diffraction spectroscopy. The LiNi_0.5Mn_1.5O₄ is a commercially available product. The two materials are used to prepare composite electrodes, and their electrochemical properties are investigated by galvanostatic charge/discharge cycles at various current densities in lithium cells. The electrodes are then used to assemble a high-voltage lithium-ion cell, and the cell is tested to evaluate its performance as a function of discharge rate and cycle number.