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811.
The steady-state two-phase flow non-linear equation is considered in the case when one of phases has low effective permeability in some periodic set, while on the complementary set it is high; the second phase has no contrast of permeabilities in different zones. A homogenization procedure gives the homogenized model with macroscopic effective permeability of the second phase depending on the gradient and on the second order derivatives of the macroscopic pressure of the first phase. This effect cannot be obtained by classical (one small parameter) homogenization. To cite this article: G.P. Panasenko, G. Virnovsky, C. R. Mecanique 331 (2003). 相似文献
812.
V. V. AntiĆ M. P. AntiĆ M. N. Govedarica P. R. DvorniĆ 《Journal of polymer science. Part A, Polymer chemistry》2007,45(11):2246-2258
The kinetics of the formation of poly(carbosiloxane), as well as of alkyl-substituted poly(siloxane), by Karstedt's catalyst catalyzed hydrosilylation were investigated. Linear poly(carbosiloxane), poly[(1,1,3,3-tetramethyldisiloxanyl)ethylene], (PTMDSE), was obtained by hydrosilylation of 1,3-divinyltetramethyldisiloxane (DVTMDS) and 1,1,3,3-tetramethyldisiloxane (TMDS), while alkyl-substituted poly(siloxane), poly(methyldecylsiloxane), (PMDS), was synthesized by hydrosilylation of poly(methylhydrosiloxane) (PMHS) and 1-decene. To investigate the kinetics of PTMDSE formation, two series of experiments were performed at reaction temperatures ranging from 25 to 56 °C and with catalyst concentrations ranging from 7.0 × 10−6 to 3.1 × 10−5 mol Pt/mol CHCH2. A series of experiments was performed at reaction temperatures ranging from 28 to 48 °C, with catalyst concentrations of 7.0 ×10−6 mol of Pt per mol of CHCH2, when kinetics of PMDS formation was investigated. All reactions were carried out in bulk, with equimolar amounts of the reacting Si H and CHCH2 groups. The course of the reactions was monitored by following the disappearance of the Si H bands using quantitative infrared spectroscopy. The results obtained showed typical first order kinetics for the PTMDSE formation, consistent with the proposed reaction mechanism. In the case of PMDS an induction period occurred at lower reaction temperatures, but disappeared at 44 °C and the rate of Si H conversion also started to follow the first-order kinetics. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 2246–2258, 2007 相似文献
813.
Kentsch U. Zschornack G. Grossmann F. Ovsyannikov V. P. Ullmann F. 《Hyperfine Interactions》2003,148(1-4):237-242
Hyperfine Interactions - It is well known that many reinforced concrete structures are at risk of deterioration due to chloride ion contamination of the concrete or atmospheric carbon dioxide... 相似文献
814.
Runge–Kutta based convolution quadrature methods for abstract, well-posed, linear, and homogeneous Volterra equations, non
necessarily of sectorial type, are developed. A general representation of the numerical solution in terms of the continuous
one is given. The error and stability analysis is based on this representation, which, for the particular case of the backward
Euler method, also shows that the numerical solution inherits some interesting qualitative properties, such as positivity,
of the exact solution. Numerical illustrations are provided. 相似文献
815.
V. P. Maslov 《Theoretical and Mathematical Physics》2007,150(1):102-122
From the standpoint of thermodynamic averaging of fission microprocesses, we investigate the origin of radioactive release
in an NPP after an accident or after resource depletion. The genesis of the NPP release is interpreted as a new thermodynamic
phenomenon, a zeroth-order phase transition. This problem setting results in a problem in probabilistic number theory. We
prove the corresponding theorem leading to quantization of the Zipf law for the frequency of a zeroth-order phase transition
with different values of the jump of the Gibbs thermodynamic potential. We introduce the notion of hole dimension.
__________
Translated from Teoreticheskaya i Matematicheskaya Fizika, Vol. 150, No. 1, pp. 118–142, January, 2007. 相似文献
816.
P. P. Nikitin 《Journal of Mathematical Sciences》2007,141(4):1479-1493
We consider the walled Brauer algebra Br
k, l(n) introduced by V. Turaev and K. Koike. We prove that it is a subalgebra of the Brauer algebra and that it is isomorphic,
for sufficiently large n ∈ ℕ, to the centralizer algebra of the diagonal action of the group GLn(ℂ) in a mixed tensor space. We also give the presentation of the algebra Br
k, l(n) by generators and relations. For a generic value of the parameter, the algebra is semisimple, and in this case we describe
the Bratteli diagram for this family of algebras and give realizations for the irreducible representations. We also give a
new, more natural proof of the formulas for the characters of the walled Brauer algebras. Bibliography: 29 titles.
__________
Translated from Zapiski Nauchnykh Seminarov POMI, Vol. 331, 2006, pp. 170–198. 相似文献
817.
818.
The surface of polystyrene was modified with the bovine serum albumin-Tween 80 complex. The adsorption of the complex and the formation of films on the surface of polystyrene were studied using the piezoelectric weighing method. The state of the modified surface was evaluated by contact angle measurements. The stability of the modifying layer was determined based on the critical interfacial energy values of the surface equilibrated with water. A conclusion was drawn that the complex can be effectively used to enhance the biocompatibility of polymer materials. 相似文献
819.
Ph. Komninou Th. Kehagias A. Delimitis G.P. Dimitrakopulos J. Kioseoglou E. Dimakis A. Georgakilas Th. Karakostas 《Superlattices and Microstructures》2004,36(4-6):509
The structural properties of InN thin films, grown by rf plasma-assisted molecular beam epitaxy on Ga-face GaN/Al2O3(0001) substrates, were investigated by means of conventional and high resolution electron microscopy. Our observations showed that a uniform InN film of total thickness up to 1 μm could be readily grown on GaN without any indication of columnar growth. A clear epitaxial orientation relationship of , was determined. The quality of the InN film was rather good, having threading dislocations as the dominant structural defect with a density in the range of 109–1010 cm−2. The crystal lattice parameters of wurtzite InN were estimated by electron diffraction analysis to be a=0.354 nm and c=0.569 nm, using Al2O3 as the reference crystal. Heteroepitaxial growth of InN on GaN was accomplished by the introduction of a network of three regularly spaced misfit dislocation arrays at the atomically flat interface plane. The experimentally measured distance of misfit dislocations was 2.72 nm. This is in good agreement with the theoretical value derived from the in-plane lattice mismatch of InN and GaN, which indicated that nearly full relaxation of the interfacial strain between the two crystal lattices was achieved. 相似文献
820.
P. Schlagheck A. Buchleitner 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》2003,22(3):401-415
We provide a detailed quantum treatment of the spectral characteristics and of the dynamics of nondispersive two-electron
wave packets along the periodically driven, collinear frozen planet configuration of helium. These highly correlated, long-lived
wave packets arise as a quantum manifestation of regular islands in a mixed classical phase space, which are induced by nonlinear
resonances between the external driving and the unperturbed dynamics of the frozen-planet configuration. Particular emphasis
is given to the dependence of the ionization rates of the wave packet states on the driving field parameters and on the quantum
mechanical phase space resolution, preceded by a comparison of 1D and 3D life times of the unperturbed frozen planet. Furthermore,
we study the effect of a superimposed static electric field component, which, on the grounds of classical considerations,
is expected to stabilize the real 3D dynamics against large (and possibly ionizing) deviations from collinearity.
Received 7 November 2002 / Received in final form 2 December 2002 Published online 28 January 2003 相似文献