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M. N. Moreno-Carretero J. M. Salas-Peregrín A. Mata-Arjona 《Journal of Thermal Analysis and Calorimetry》1984,29(3):553-559
The following Zn(II) complexes of deprotonated 6-amino-5-nitrosouracil (AH), 6-amino-3-methyl-5-nitrosouracil (BH) and 6-amino-1-methyl-5-nitrosouracil (CH) have been prepared and their thermal behaviour studied by TG and DSC techniques: ZnA2(H2O)2, ZnB2 · 4 H2O, ZnC2 · 4 H2O and ZnC2(H2O)2 · H2O. The values of the dehydration enthalpy of the complexes are in the 31.3–76.5 kJ mol?1 H2O range and, except in the first complex, the dehydration processes take place in several steps. The pyrolysis of the complexes finishes between 540 and 725° C ZnO remaining as residue. 相似文献
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Hueso-Ureña Francisco Illán-Cabeza Nuria A. Moreno-Carretero Miguel N. Peñas-Chamorro Antonio L. 《Transition Metal Chemistry》2001,26(1-2):160-163
The synthesis and spectroscopic characterization of NiII, CuII, PdII and AuIII complexes containing hydrazones derived from 6-amino-5-formyl-1,3-dimethyluracil and thiosemicarbazide, acetylhydrazine and nicotinic acid is reported. In all cases, the complexes appear to be monomeric and square planar, with three positions occupied by the N,N,Z-tridentate (Z = S or O) ligand, making two five- and six-membered chelate rings and the fourth position occupied by halide. 相似文献
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Francisco Hueso-Ureña Antonio L. Peñas-Chamorro Miguel N. Moreno-Carretero Miguel Quirós-Olozábal Juan M. Salas-Peregrín 《Journal of chemical crystallography》1999,29(3):283-286
The crystal structure of bis-(6-amino-5-formyl-1,3-dimethyluracilato benzoylhydrazone)cobalt(II) dimethylformamide solvate is described. This compound crystallizes in the triclinic system, space group P1¯, Z = 2 with a = 9.7368(8), b = 12.346(1), c = 17.184(1) Å, = 78.372(6), = 74.585(6), = 71.113(5)°, and V = 1869.0(3) Å3. The coordination polyhedron around the metal ion displays a slightly flattened M(NNO)2 octahedral shape. Both ligands bind in a trident fashion through the benzoylic oxygen atom, the hydrazone nitrogen atom closer to the uracil ring, and the deprotonated nitrogen atom of the amino group. The two ligands exhibit quite different conformations: one of them is almost planar, whereas the other is severely twisted. 相似文献
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