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91.
Urbano RR Pagliuso PG Rettori C Kopelevich Y Moreno NO Sarrao JL 《Physical review letters》2002,89(8):087602
We report the first observation of the field distribution and flux-line lattice (FLL) depinning in the vortex-state (VS) of a type-II superconductor probed by conduction electron spin resonance (CESR). CESR was performed in MgB (2) (T(c) approximately 39 K) at 4.1 GHz (1455 Oe) and 9.5 GHz (3390 Oe). The field distribution, n(H), and a standard deviation of sigma approximately 14 Oe (at 28 K/4.1 GHz and at 7 K/9.5 GHz) were inferred, respectively, from the distortion and broadening of the CESR in the VS. For both frequencies, the FLL depinning temperature was determined. 相似文献
92.
Abstract— The fluorescent probe Prodan (6-propionyl-2-dimethyl-aminonaphthalene) binds with high affinity to human serum albumin (HSA). The spectral characteristics of the Prodan bound to the protein are very different from the free Prodan in solution. These differences allowed the spectra to be deconvoluted into log-normal bands in order to quantify the bound and unbound ligand and to calculate the binding constant at different temperatures. From such temperature dependence, we found the binding to be exothermic with a van't Hoff enthalpy of -22.8 kJ mol-1 . Thermodynamic analysis suggests that the in teraction may be mainly caused by hydrophobic forces and electrostatic interactions. The above analysis of the spectra and the measures of the fluorescence polarization during the successive presence of six specific drugs suggest that the Prodan binding site corresponds with the warfarin binding site on HSA, whereas under the present experimental conditions the other characteristic binding sites of HSA were not affected. Thus, this fluorescent probe provides a rapid and simple means for the characterization of a specific binding site on HSA and also for detecting potential or nonspecific drug-protein interactions. 相似文献
93.
We report what is believed to be the first demonstration of soft-x-ray interferometry of a plasma with a tabletop soft-x-ray laser. A Lloyd's mirror interferometer was used in combination with a very compact lambda = 46.9 nm capillary-discharge-pumped laser to map the electron density in the cathode region of a pinch plasma. 相似文献
94.
We have developed an experimental method based on the visibility factor of light-scattering minima to obtain size-polydispersity information from contaminants upon a flat substrate. We verify the method by using double-interaction-model calculations and use this technique to examine experimentally the radial variation of a micrometer-sized fiber and the size polydispersity of spherical particles upon a substrate. 相似文献
95.
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97.
The energy barriers for the addition to ethylene of a series of carbenes have been calculated at an ab initio level. using the STO-3G and 3-21G basis sets. It is shown that the usual extrapolation of experiment results, which predicts that the reactivity of carbenes decreases when increasing its nucleophilic character, is not valid. 相似文献
98.
M. Moreno 《Solid State Communications》1981,38(11):1045-1048
It is argued that in a series of complexes formed by ions of the same type and having the same geometry and ligand the degree of hybridization tends to decrease when covalency increases. This rule which discards any sp2 explanation for the ligand hybridization has been well verified through series of d9 and s1 complexes. The validity of such a rule, also useful for understanding the behaviour of in some D2h systems, outlines that ligand core polarization effects are negligible in these cases. 相似文献
99.
P-Donor nucleophiles of cone angle >or=145 degrees are known to react with Os3(CO)9(mu-C4Ph4) quite differently from those with cone angles 相似文献
100.
We report on direct measurements of the impurity band hole polarization in the diluted magnetic semiconductor (Ga,Mn)As. The polarization of impurity band holes in a magnetic field is strongly enhanced by antiferromagnetic exchange interaction with Mn ions. The temperature dependence of the hole polarization shows a strong increase of this polarization below the Curie temperature. We show that the ground state of the impurity band is formed by uniaxial stress split F=+/-1 states of antiferromagnetically coupled Mn ions (S=5/2) and valence band holes (J=3/2). The gap between the Mn acceptor related impurity band and the valence band is directly measured in a wide range of Mn content. 相似文献