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排序方式: 共有466条查询结果,搜索用时 3 毫秒
91.
Antoine Leydier Yi Lin Guilhem Arrachart Raphaël Turgis Delphine Lecerclé Alain Favre-Reguillon Frédéric Taran Marc Lemaire Stéphane Pellet-Rostaing 《Tetrahedron》2012,68(4):1163-1170
Synthesis of modified EDTA and DTPA ligands and determination of their binding affinities for the uranyl cation are described.Thanks to a screening method, based on a chromophoric complex displacement procedure, chelating properties were studied in aqueous media under various pH conditions for evaluation of their in vivo uranyl-removal efficacy. Each ligand showed a more or less pronounced affinity for uranium. Specific ligands based on EDTA or DTPA analogues containing sulfocatecholamide (CAMS) were found to exhibit a significant affinity towards uranyl ion in acidic, neutral or basic conditions. 相似文献
92.
Tomas Fritioff Conny Carlberg Guilhem Douysset Reinhold Schuch Ingmar Bergström 《Hyperfine Interactions》2001,132(1-4):229-242
The Penning trap mass spectrometer SMILETRAP has been considerably improved during the last two years. The helium pressure
has been carefully stabilized and is now independent of irregular air pressure. The temperature of the hyperboloidal precision
trap is stabilized to ±0.03°C. Remaining temperature instabilities are compensated by changes in the current of a warm coil
surrounding the precision trap. The frequency synthesizer is now locked to GPS. This means that it is much easier to accurately
measure resonances during several days. The improvements have demonstrated that in mass doublet measurements with an excitation
time of 1 s it is possible to determine the mass of ions with q/A=1/2 at an uncertainty to a few times of 0.1 ppb, using selected rather than cooled ions. In routine measurements lasting
for one day it is possible to reach a mass uncertainty of 1 ppb. The masses of the following particles and atoms have been
measured with uncertainties in the region 0.3–2 ppb: p, 3H, 3He, 4He, 22Ne, 28Si, 36Ar, 76Ge, 76Se, 86Kr and 133Cs. It has also been shown that though we are using a warm bore the trap pressure is sufficiently low to prevent electron
capture from the rest gas for excitation times of 3 s and for ion charges as high as 50+.
This revised version was published online in July 2006 with corrections to the Cover Date. 相似文献
93.
Intrinsic viscosities, [η], second virial coefficients, A2, and preferential solvation coefficients, λ, for the ternary systems n-alkane (l)-butanone (2)-poly(dimethylsiloxane) (PDMS) (3), with n-alkane = n-hexane, n-heptane, n-nonane and n-undecane, have been determined at 20°. The K and a constants of the Mark-Houwink equation have been evaluated over the whole composition range of the binary solvent mixtures. Polymer (mixed solvent) interaction parameters and unperturbed dimensions have been evaluated both from A2 and [η] data, the feasibility of A2 evaluation from [η] experimental data or vice versa being discussed. Experimental and calculated (through Dondos and Patterson theory) excess free energies, GE, follow similar trends with composition; large numerical discrepancies, however, arise between both sets of GE. Maxima in [η], in a and in A2 are accompanied by inversion points in λ. The solvent mixture composition range in which PDMS is preferentially solvated by n-alkane, as well as the extent of solvation, decrease with increasing number of carbon atoms in the n-alkane. 相似文献
94.
Bernard Dietrich Jean Guilhem Jean-Marie Lehn Claudine Pascard Etienne Sonveaux 《Helvetica chimica acta》1984,67(1):91-104
The crystal structures of four anion cryptates [X? ? BT -6H+] formed by the protonated macrobicyclic receptor BT -6H+ with F?, Cl?, Br? and N have been determined. They provide a homogeneous series of anion coordination patterns with the same ligand. The small F?-ion is tetracoordinated, while Cl? and Br? are bound in an octahedron of H-bonds. The non-complementarity between these spherical anions and the ellipsoïdal cavity of BT -6H+ is reflected in ligand distortions. Structural complementarity is achieved for the linear triatomic substrate N, which is bound by two pyramidal arrays of three H-bonds, each interacting with a terminal N-atom of N. The formation constants of the complexes formed by BT -6H+ with a variety of anions (halides, N, NO, carboxylates, SO, HPO, AMP2?, ADP3?, ATP4?, P2O) have been determined. Very strong complexations are found, as well as marked electrostatic and structural effects on stability and selectivity; in particular the binding of F?, Cl?, Br?, and N may be analyzed in terms of the crystal structure data. The cryptand BT -6H+ is a molecular receptor containing an ellipsoïdal recognition site for linear triatomic substrates of size compatible with the size of the molecular cacity. Further developments of various aspects of anion coordination chemistry are considered. 相似文献
95.
In this paper,dynamic similarity conditions are derived for discrete element simulations by non-dimensionalising the governing equations.These conditions must b... 相似文献
96.
David Molnar Christian Niedermeier Alejandro Mora Peter Binkele Siegfried Schmauder 《Continuum Mechanics and Thermodynamics》2012,24(4-6):607-617
Kinetic Monte-Carlo (KMC) methods are used as an approach to simulate precipitation in Cu-alloyed bcc Fe. In order to characterize the process, transformed fractions, that is, the precipitated atoms, are related to Johnson-Mehl-Avrami-Kolmogorov theory. However, simulated data often deviate from corresponding fit curves and so does the resulting growth exponent when compared to theoretical expectations. Furthermore, some data may suggest the development of a metastable phase. In our study, we show that the characteristics of the transformed fraction and, as a consequence, the derived growth exponents sensitively depend on the number of atoms that are considered to form a particle and hence contribute to the transformed fraction. With a temperature dependence of the critical cluster size and additionally accounting for severe impingement of the particles, we obtain growth exponents which lie close to the expected range between n = 1.5 and n = 2.5 for pre-existing nuclei or continuous nucleation, respectively. From these, we obtain activation energies for nucleation and growth of precipitates. In this way, atomistic KMC simulations yield thermodynamical quantities, which can be valuable input parameters for larger length scale simulation methods, for example, for Phase Field Method simulations. 相似文献
97.
Maria Giovanna Mora Stefan Müller 《Calculus of Variations and Partial Differential Equations》2007,28(2):161-178
A rigorous derivation is given of a rod theory for a multiphase material, starting from three-dimensional nonlinear elasticity. The stored energy density is supposed to be nonnegative and to vanish exactly on a set consisting of two copies of the group of rotations SO(3). The two potential wells correspond to the two crystalline configurations preferred by the material. We find the optimal scaling of the energy in terms of the diameter of the rod and we identify the limit, as the diameter goes to zero, in the sense of Γ-convergence. 相似文献
98.
99.
Differential scanning calorimetry (DSC) was utilized to study the behavior of six Ge-Se glasses containing 0, 5, 10, 15, 17.5
and 20 at.% Ge during the glass transition. These alloys readily form glasses and can be prepared by quenching in air. Moreover,
their behavior depends greatly on the composition. This work reveals that two additional properties must be considered: the
variation in the glass transition temperature and different structural relaxation. The quantity used to quantify the relaxation
was the enthalpy relaxation as this measures the heat lost by the glass during annealing. Given the complexity of the relaxation
process, the experimental results were analysed by means of the empirical Kohlrausch-Williams-Watts relaxation model.
This revised version was published online in July 2006 with corrections to the Cover Date. 相似文献
100.
J. J. Suñol N. Clavaguera M. T. Mora 《Journal of Thermal Analysis and Calorimetry》1998,52(3):853-862
The low-temperature parts of the temperature-heating rate-transformation (T-HR-T) and temperature-time transformation (T-T-T)
diagrams were obtained for crystallization processes. A knowledge of the kinetic model governing crystallization is not needed
because both transformation curves can be obtained from non-isothermal calorimetric experiments. The calorimetric study was
performed by means of differential scanning calorimetry. The method was applied to analyse crystallization processes of Fe-Ni-based
amorphous alloys prepared by melt spinning. The compositions studied were Fe40Ni40P14Si6, Fe40Ni40P10Si10 and Fe40Ni40P6Si14.
A good concordance was observed between the experimental T-HR-T curves obtained by calculation and the experimental data,
which verifies the reliability of the method. In the T-T-T diagrams, the agreement was good in process B1, while in processes
A1 and C1 there are small differences that could be related to different crystallization products obtained in isothermal/non-isothermal
experiments.
This revised version was published online in July 2006 with corrections to the Cover Date. 相似文献