Four-body Efimov effect for three fermions and a lighter particle

We study three same-spin-state fermions of mass M interacting with a distinguishable particle of mass m in the unitary limit where the interaction has a zero range and an infinite s-wave scattering length. We predict an interval of mass ratio 13.384相似文献   

On subfÌields of radical extensions

A Jordan pair is constructed from a pair of cubic forms satisfying the adjoint identities. Given some parameters and an incidence structure S having three points on each line and no more than one line through two points, a pair of cubic forms are constructed. These forms satisfy the adjoint identities if and only if S is either a star or a generalized quadrangle and the parameters are precisely determined.     

Crystal structure of the quaternary alloy CuTaInSe3

The crystal structure of the quaternary compound CuTaInSe₃ belonging to the system (CuInSe₂)_1‐x(TaSe)_x with x= 0.5, was analyzed using X‐ray powder diffraction data. This material is isostructural with the CuFeInSe₃ compound, and crystallize in the tetragonal space group P42c (Nº 112), Z = 1, with unit cell parameters a = 5.7831(1) Å, c = 11.6227(4) Å, V = 388.71(2) ų. The Rietveld refinement of 18 instrumental and structural variables led to R_p = 8.0%, R_wp = 9.5%, R_exp = 6.3% and χ² = 1.5 for 4501 step intensities and 144 independent reflections. (© 2008 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)     

Kinetics and mechanisms of gas‐phase elimination of 2,2‐diethoxyethyl amine and 2,2‐diethoxy‐N,N‐diethylethanamine

The gas‐phase elimination kinetics of 2,2‐diethoxyethyl amine and 2,2‐diethoxy‐N,N‐diethylethanamine (320–380 °C; 40–150 Torr) in a seasoned reaction vessel are homogeneous, unimolecular and obey a first‐order rate law. These elimination processes involve two parallel reactions. The first gives ethanol and the corresponding 2‐ethoxyethenamine. The latter compound further decomposes to ethylene, CO and the corresponding amine. The second parallel reaction produce ethane and the corresponding ethyl ester of an α‐amino acid. The following Arrhenius expressions are given as: For 2,2‐diethoxyethyl amine For 2,2‐diethoxy‐N,N‐diethylethanamine Comparative kinetic and thermodynamic parameters of the overall, the parallel and the consecutive reactions lead to consider two types of mechanisms in terms of a concerted polar cyclic transition state structures. Copyright © 2008 John Wiley & Sons, Ltd.     

Current noise through a Kondo quantum dot in a SU(N) Fermi liquid state

The current noise through a mesoscopic quantum dot is calculated and analyzed in the Fermi liquid regime of the SU(N) Kondo model. The results connect the Johnson-Nyquist noise to the shot noise for an arbitrary ratio of voltage and temperature, and show that temperature corrections are sizable in the usual experiments. For the experimentally relevant SU(4) case, quasiparticle interactions are shown to increase the shot noise.     

Correlation between surface tension and void fraction in ionic liquids

An effort to systematize published and new data on the surface tension gamma of ionic liquids (ILs) is based on the hypothesis that the dimensionless surface tension parameter gamma V v (2/3)/ kT is a function of the void fraction x v = V v/ V m. The void volume V v is defined as the difference between the liquid volume V m occupied by an ion pair (known from cationic and anionic masses and liquid density measurements) and the sum V (+) + V (-) of the cationic and anionic volumes (known from crystal structures), while kT is the thermal energy. Our hypothesis that gamma V m (2/3)/ kT = G( x v) is initially based on cavity theory. It is then refined based on periodic lattice modeling, which reveals that the number N of voids per unit cell (hence the dimensionless surface tension) must depend on x v. Testing our hypothesis against data for the five ILs for which surface tension and density data are available over a wide range of temperatures collapses all of these data almost on a single curve G( x v), provided that slight (4%) self-consistent modifications are introduced on published crystallographic data for V (+) and V (-). An attempt to correlate the surface tension vs temperature data available for inorganic molten salts is similarly successful, but at the expense of larger shifts on the published ionic radii (8.8% for K; 3.3% for I). The collapsed G( x v) curves for ILs and inorganic salts do not overlap anywhere on x v space, and appear to be different from each other. The existence of a relation between gamma and x v is rationalized with a simple capillary model minimizing the energy. Our success in correlating surface tension to void fraction may apply also to other liquid properties.     

Synthesis of hydroxycinnamic acid glucuronides and investigation of their affinity for human serum albumin

Hydroxycinnamic acids (HCAs) are among the most abundant dietary polyphenols. Recent bioavailability studies have shown that HCAs enter the blood circulation mainly as glucuronides, which are thus most likely to express their potential health effects. In this work, an efficient synthesis of HCA O-arylglucuronides is developed. As for many xenobiotics, the resilience of HCA O-arylglucuronides in plasma and subsequent delivery to tissues could be governed by their binding to human serum albumin (HSA). Hence, the affinity of HCA O-arylglucuronides for HSA and its possible binding site were investigated by fluorescence spectroscopy. HCA O-arylglucuronides turn out to be moderate HSA ligands (K in the range 1-4 x 10(4) M(-1)) that bind HSA in sub-domain IIA, competitively or noncompetitively with other sub-domain IIA ligands such as dansylamide and the flavonol quercetin.     

Synthesis, X-ray, and electronic structures of a new nickel dibromide complex. Activity in the regioselective catalyzed dimerization of ethylene into 1-butene

Reaction of the bis-(3,4)-dimethylphosphole-Xanthene 1b with [NiBr2(DME)] afforded a new nickel(II) dibromide complex, 2. Both its color and its NMR behavior change with temperature and solvent due to changes in the spin state of the complex. This led us to study the complex spin states using DFT calculations. Furthermore, the activity of 2 in catalyzed ethylene dimerization was studied, revealing both high activity and selectivity toward the production of 1-butene.     

Metric Sample Spaces of Continuous Geometric Curves and Estimation of Their Centroids

The metric sample space of Fréechet curves (Fréechet , 1934,1951,1961) is based on a generalization of regular curves that covers continuous curves in full generality. This makes it possible to deal with both smooth and non-smooth, even non-rectifiable geometric curves in statistical analysis. In the present paper this sample space is further extended in two directions that are relevant in practice: to incorporate information on landmark points in the curves and to impose invariance with respect to an arbitrary group of isometric spatial transformations. Properties of the introduced sample spaces of curves are studied, specially those concerning to the generation and representation of random curves by random functions.In order to provide measures of central tendency and dispersion of random curves, centroids and restricted centroids ofrandom curves are defined in a general metric framework, and methods for their consistent estimation are derived.