Supported ionic liquids: ordered mesoporous silicas containing covalently linked ionic species

Ordered mesoporous silicas with hexagonal or lamellar architectures incorporating covalently bound ionic species were synthesized via a template directed hydrolysis-polycondensation of tetraethoxysilane (TEOS) with triethoxysilylated imidazole [(EtO)(3)Si(CH(2))(3)-Im] or alkylimidazolium halides [(EtO)(3)Si(CH(2))(3)-Im(+)-R Hal(-)].     

Queueing Dynamics and Maximal Throughput Scheduling in Switched Processing Systems

We study a processing system comprised of parallel queues, whose individual service rates are specified by a global service mode (configuration). The issue is how to switch the system between various possible service modes, so as to maximize its throughput and maintain stability under the most workload-intensive input traffic traces (arrival processes). Stability preserves the job inflow–outflow balance at each queue on the traffic traces. Two key families of service policies are shown to maximize throughput, under the mild condition that traffic traces have long-term average workload rates. In the first family of cone policies, the service mode is chosen based on the system backlog state belonging to a corresponding cone. Two distinct policy classes of that nature are investigated, MaxProduct and FastEmpty. In the second family of batch policies (BatchAdapt), jobs are collectively scheduled over adaptively chosen horizons, according to an asymptotically optimal, robust schedule. The issues of nonpreemptive job processing and non-negligible switching times between service modes are addressed. The analysis is extended to cover feed-forward networks of such processing systems/nodes. The approach taken unifies and generalizes prior studies, by developing a general trace-based modeling framework (sample-path approach) for addressing the queueing stability problem. It treats the queueing structure as a deterministic dynamical system and analyzes directly its evolution trajectories. It does not require any probabilistic superstructure, which is typically used in previous approaches. Probability can be superposed later to address finer performance questions (e.g., delay). The throughput maximization problem is seen to be primarily of structural nature. The developed methodology appears to have broader applicability to other queueing systems.     

Design of Stacked Self-Healing Rings Using a Genetic Algorithm

Ring structures in telecommunications are taking on increasing importance because of their self-healing properties. We consider a ring design problem in which several stacked self-healing rings (SHRs) follow the same route, and, thus, pass through the same set of nodes. Traffic can be exchanged among these stacked rings at a designated hub node. Each non-hub node may be connected to multiple rings. It is necessary to determine to which rings each node should be connected, and how traffic should be routed on the rings. The objective is to optimize the tradeoff between the costs for connecting nodes to rings and the costs for routing demand on multiple rings. We describe a genetic algorithm that finds heuristic solutions for this problem. The initial generation of solutions includes randomly-generated solutions, complemented by seed solutions obtained by applying a greedy randomized adaptive search procedure (GRASP) to two related problems. Subsequent generations are created by recombining pairs of parent solutions. Computational experiments compare the genetic algorithm with a commercial integer programming package.     

Inhibition and exaltation of emission in layer-controlled colloidal photonic architectures

We described the engineering and characterization of photonic colloidal crystals based on silica spheres with incorporated YVO₄:Eu luminescent nanoparticles. These structures exhibit strong angle-dependent luminescent properties. The controlled incorporation of a planar defect in the periodic structures gives rise to the creation of a pass band in the pseudo-gap. In the energy range of this pass band, we observed a strong increase in combination with a sharp width of the emission spectrum, which opens new possibilities for the design of low-threshold and/or single mode photonic crystal lasers.     

Study of active naphtodianthrone St John's Wort compounds by electrospray ionization Fourier transform ion cyclotron resonance and multi‐stage mass spectrometry in sustained off‐resonance irradiation collision‐induced dissociation and infrared multiphoton dissociation modes

Five well‐known active naphtodianthrone constituents of Hypericum perforatum (St John's Wort) extracts have been investigated by electrospray ionization Fourier transform ion cyclotron resonance mass spectrometry (ESI‐FTICRMS) and ESI‐FTICRMSⁿ. The studied compounds were hypericin, pseudohypericin, protohypericin, protopseudohypericin (biosynthetic precursors of the two former compounds, respectively) and isopseudohypericin (alkaline degradation product of pseudohypericin). Dissociation mass spectrometry measurements performed on the [M–H]^? ion presented a variable efficiency as a function of the used activation mode. Sustained off‐resonance irradiation collision‐induced dissociation (SORI–CID) only led to a restricted number of fragment ions. In contrast, IRMPD ensured the detection of numerous product ions. Ions detected in ESI‐FTICRMS and ESI‐FTICRMSⁿ experiments were measured with a very high mass accuracy (typically mass error is lower than 0.5 mDa at m/z close to 500) that allowed unambiguous formulae to be assigned to each signal observed in a mass spectrum. In spite of similar structures, specific fragmentation patterns were observed for the different compounds investigated. This study may be useful in the future to characterize in natural extracts these compounds (or derivatives of these compounds) by liquid chromatography/tandem mass spectrometry (LC/MS/MS) experiments by considering the MS/MS transitions highlighted in this paper. Copyright © 2009 John Wiley & Sons, Ltd.     

What do cylinders look like?

The farthest point mapping is bijective and involutive on any right circular cylinder of radius r and height h ≤ r(π ? 2). For any right cylinder C over a typical convex body K, most points in bd(K) are endpoints of C.     

Bioactive polymers 61. synthesis and characterization of some retard antibiotics

Ampicillin and chloramphenicol were coupled on xanthan by activation by dicyclohexyl-carbodiimide. Drug release from the support was studied in vitro for ampicillin, and in vitro and in vivo conditions for chloramphenicol.