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81.
Berenika Kokoszka Nina K. Jarrah Cong Liu Prof. Dr. David T. Moore Prof. Dr. Kai Landskron 《Angewandte Chemie (International ed. in English)》2014,53(14):3698-3701
An electrical effect, the supercapacitive swing adsorption (SSA) effect is reported, which allows for reversible adsorption and desorption of carbon dioxide by capacitive charge and discharge of electrically conducting porous carbon materials. The SSA effect can be observed when an electrically conducting, nanoporous carbon material is brought into contact with carbon dioxide gas and an aqueous electrolyte. Charging the supercapacitor electrodes initiates the spontaneous organization of electrolyte ions into an electric double layer at the surface of each porous electrode. The presence of this double layer leads to reversible, selective uptake and release of the CO2 as the supercapacitor is charged and discharged. 相似文献
82.
Daniel B. Moore Prof. Matt Beekman Dr. Sabrina Disch Dr. David C. Johnson 《Angewandte Chemie (International ed. in English)》2014,53(22):5672-5675
Telluride misfit layer compounds are reported for the first time. These compounds were synthesized using a novel approach of structurally designing a precursor that would form the desired product upon low‐temperature annealing, which allows the synthesis of kinetically stable products that do not appear on the equilibrium phase diagram. Four new compounds of the [(PbTe)1.17]m(TiTe2)n family are reported, and their structures were examined by a variety of X‐ray diffraction techniques. 相似文献
83.
Photoprotection of Mammalian Acid-Soluble Collagen by Cuttlefish Sepia Melanin In Vitro 总被引:1,自引:0,他引:1
Julian M. Menter Abrienne M. Patta Thomas D. Hollins Cyril L. Moore Isaac Willis 《Photochemistry and photobiology》1998,68(4):532-537
Several important clinical conditions can result in close association between the pigment melanin and dermal collagen. Because melanin and its precursors can be chemically reactive in ground and excited states, it is important to know whether the resulting melanin-collagen interaction results in photoprotection or photoaggression. Acidic and neutral air-saturated collagen suspensions (0.033%) were irradiated with0–2.6 times 104 J/m2 UVC or with0–83 times 104 J/m2 solar-simulating UV radiation (SSR). Photochemical destruction of a photolabile collagen fluorophore (δem 360 nm) and collagen chain degradation were monitored as functions of irradiation time in the presence and absence of added (0–100μg) sepia eumelanin. Melanin retarded collagen photodamage but did not qualitatively alter the fluorescence fading kinetics. Both H202 and 02 can be produced by UV irradiation of eumelanin. Added H202 and K02 destroyed collagen fluorescence and caused 50% chain degradation at ca10–20-fold molar excess. Previous studies have demonstrated that eumelanins efficiently scavenge 02 . We demonstrated that eumelanin also efficiently scavenges H202 as evidenced by its ability to (a) compete with scopoletin for peroxide uptake and (b) directly take up H202 through a dialysis bag. The latter observation suggests that peroxide scavenging could occur in vivo by melanin sequestered in melanophages. Thus, neither UV-generated 02 nor H202 are likely to be present in concentrations high enough to cause measurable collagen damage. Absorption and/or scattering of excitation radiation away from the target chromophore appears to be the primary photoprotection mechanism, although scavenging of active 02 intermediates may play an important, if subtle role. 相似文献
84.
Reductions in leaf growth are a commonly observed response to ultraviolet radiation, but the underlying mechanisms remain poorly defined. This study examined the response of leaves exposed to a UV environment across a range of organizational scales, including leaf expansion rate, epidermal cell size and number, biomechanical properties, leaf–water relations and activity of cell-wall peroxidases. Two experimental approaches were used; Lettuce ( Lactuca sativa L.) plants were propagated under (a) supplementary UV-B (9 kJ m−2 day−1 ) in controlled environment (CE) conditions, and (b) field conditions, where plants were placed under three horticultural films with differing UV transmissions. In both experiments, UV-B caused the greatest reductions in leaf expansion and final leaf size, with some reductions attributable to UV-A wavelengths. In supplementary UV-B conditions, adaxial cell size was reduced, while in field plants, both cell size and cell number were lower in an increased UV environment, as was the case with abaxial cells in CE plants. Although leaf turgor and leaf extensibility were not affected by UV wavelengths, breaking strain of leaf tissue was decreased under supplementary UV-B. Cell-wall peroxidase activity was increased in both supplementary UV conditions and in the field, where only a zero UV environment showed no upregulation of cell-wall peroxidase. 相似文献
85.
The cation distribution in spinel-related titanium-substituted lithium ferrite, Li0.5+0.5xFe2.5−1.5xTixO4 has been explored using interatomic potential and ab initio calculations. The results suggest that the cation distribution with Ti4+ substituting for Fe3+ on octahedral B sites and excess Li+ substituting for Fe3+ on tetrahedral A sites is stabilised by the formation of clusters of two octahedrally coordinated Ti4+ ions and one tetrahedrally coordinated Li+ ion linked through a common oxygen. 相似文献
86.
G. Cleaver A. Faraggi J. Greenwald D. Moore K. Pechan E. Remkus T. Renner 《The European Physical Journal C - Particles and Fields》2011,71(12):1842
Quasi-realistic heterotic-string models in the free fermionic formulation typically contain an anomalous U(1) that leads to supersymmetry breaking. Supersymmetry is restored by imposing F- and D-flatness on the vacuum. A three generation free fermionic standard-like model which did not admit stringent F- and D-flat directions has been presented (Cleaver et al. in Phys. Rev. D 78, 046009, 2008) and it was argued that all the moduli in that model were fixed. The particular property of that model was the reduction
of the untwisted Higgs spectrum by a combination of symmetric and asymmetric internal dimension boundary conditions with respect
to the internal fermions associated with the compactified dimensions. This reduction occurred without the need or presence
of flat directions. In this paper we extend the analysis of free fermionic models with reduced Higgs spectrum to models with
the same internal space but with modified gauge groups: SO(10) or flipped SU(5) subgroup. We show that all the models studied in this paper do admit stringent flat directions. Currently, the only examples
of models that do not admit stringent flat directions are the standard-like models of Cleaver et al. (Phys. Rev. D 78, 046009,
2008). We comment on the relationship between flat directions and reduced Higgs in free fermionic models as well as the possible
connection between moduli stabilization and model phenomenology. 相似文献
87.
P. Karvonen T. Sonoda I. D. Moore J. Billowes A. Jokinen T. Kessler H. Penttilä A. Popov B. Tordoff J. Äystö 《The European physical journal. Special topics》2007,150(1):283-284
The ion guide technique was developed in Jyv?skyl? during the early 1980's. In the ion guide the reaction recoil products
are stopped and thermalized in high purity helium gas where they remain ionic due to high ionization potential of helium atoms.
Different designs of ion guide exist for light-ion induced fusion reactions, for heavy-ion induced fusion and for proton induced
fission. Although the IGISOL method is fast and universal it is chemically unselective and in many cases relatively inefficient.
In order to address these deficiencies in the technique, a new laser ion source project, FURIOS (Fast Universal Resonant laser
Ion
Source), commenced in 2004. In addition, resonance ionization spectroscopy has been tested off – line within a sextupole ion
beam
guide. 相似文献
88.
89.
Oxide-layer tunnel junctions exhibiting both quasi-particle and Josephson tunneling were produced by overlaying lead on niobium-tin thin films. The superconducting transition temperature and average energy gap of the Nb-Sn both increased as the tin concentration was increased toward Nb3Sn and reached maximum values of 17.2 K and 3.2 meV, respectively, or 2Δ = 4.3 kTc. 相似文献
90.
Factors affecting thresholds for sinusoidal signals in narrow-band maskers with fluctuating envelopes 总被引:2,自引:0,他引:2
When a signal is higher in frequency than a narrow-band masker, thresholds are lower when the masker envelope fluctuates than when it is constant. This article investigates the cues used to achieve the lower thresholds, and the factors that influence the amount of threshold reduction. In experiment I the masker was either a sinusoid (constant envelope) or a pair of equal-amplitude sinusoids (fluctuating envelope) centered at the same frequency as the single sinusoid (250, 1000, 3000, or 5275 Hz). The signal frequency was 1.8 times the masker frequency. At all center frequencies, thresholds were lower for the two-tone masker than for the sinusoidal masker, but the effect was smaller at the highest and lowest frequencies. The reduced effect at high frequencies is attributed to the loss of a cue related to phase locking in the auditory nerve. The reduced effect at low frequencies can be partly explained by reduced slopes of the growth-of-masking functions. In experiment II the masker was a sinusoid amplitude modulated at an 8-Hz rate. Masker and signal frequencies were the same as for the first experiment. Randomizing the modulation depth between the two halves of a forced-choice trial had no effect on thresholds, indicating that changes in modulation depth are not used as a cue for signal detection. Thresholds in the modulated masker were higher than would be predicted if they were determined only by the masker level at minima in the envelope, and the threshold reduction produced by modulating the master envelope was less at 250 Hz than at higher frequencies. Experiments III and IV reveal two factors that contribute to the reduced release from masking at low frequencies: The rate of increase of masked threshold with decreasing duration is greater at 250 Hz than at 1000 Hz; the amount of forward masking, relative to simultaneous masking, is greater at 250 Hz than at 1000 Hz. The results are discussed in terms of the relative importance of across-channel cues and within-channel cues. 相似文献