首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   437200篇
  免费   4913篇
  国内免费   1219篇
化学   234452篇
晶体学   6598篇
力学   18820篇
综合类   13篇
数学   50000篇
物理学   133449篇
  2021年   4095篇
  2020年   4530篇
  2019年   4518篇
  2018年   5854篇
  2017年   5744篇
  2016年   8831篇
  2015年   5561篇
  2014年   8542篇
  2013年   20183篇
  2012年   15649篇
  2011年   19261篇
  2010年   13497篇
  2009年   13352篇
  2008年   17648篇
  2007年   17543篇
  2006年   16252篇
  2005年   14550篇
  2004年   13524篇
  2003年   11892篇
  2002年   11728篇
  2001年   13429篇
  2000年   10085篇
  1999年   7917篇
  1998年   6569篇
  1997年   6314篇
  1996年   6081篇
  1995年   5470篇
  1994年   5392篇
  1993年   5197篇
  1992年   5828篇
  1991年   5924篇
  1990年   5664篇
  1989年   5473篇
  1988年   5493篇
  1987年   5375篇
  1986年   5092篇
  1985年   6561篇
  1984年   6695篇
  1983年   5301篇
  1982年   5388篇
  1981年   5367篇
  1980年   4955篇
  1979年   5352篇
  1978年   5491篇
  1977年   5385篇
  1976年   5328篇
  1975年   4914篇
  1974年   4885篇
  1973年   4880篇
  1972年   3455篇
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
31.
32.

Convenient methods for synthesis of various aminomethylenediphosphorus-containing acids and their derivatives starting from available trimethylsilyl esters of hypophosphorous and phosphorous acids, ethoxymethyleneimine hydrochlorides, and N-substituted formamides have been proposed. Selected properties of the obtained compounds have been examined.

  相似文献   
33.
34.
Nature of structuring of aqueous solutions of paramagnetic endofullerenols Gd@C n (OH)38–40 was determined in relation to the concentration and pH factor from small-angle neutron scattering, viscometric, and conductometric data. Molecular fractal clusters of the type of branched polymers were found, with their correlation radius being about 20 nm and aggregation numbers reaching a value of 104. The clusterized systems obtained are promising as a basis for MRI-contrasting agents and other biomedical preparations for diagnostics and therapy.  相似文献   
35.
Trimeric porphyrin H6TP as well as its binuclear Cu2H2TP and trinuclear Cu3TP copper complexes have been prepared. Kinetic features of H6TP and Cu2H2TP complexes formation with copper(II) acetate in acetic acid as well as dissociation kinetics of Cu2H2TP and Cu3TP in acetic acid medium in the presence of sulfuric acid have been studied.  相似文献   
36.
Method of synthesis has been developed for a series of 3,6-di-tert-butyl-9H-carbazole derivatives and their photochemical properties have been investigated. The dependence of the Steglich esterification reaction on the nature of the catalyst was studied. The synthesized compounds show fluorescent emission in the range 400–600 nm with a high quantum yield.  相似文献   
37.
The concentrations of toxic elements (arsenic, cadmium, lead) in commercial algae Saccharina japonica and Ahnfeltia tobuchiensis from different habitats of the Sea of Japan have been determined. Bioaccumulation of heavy metals has been analyzed with respect to the habitat and growth conditions. The lead content of Sascharina japonica from all habitats and arsenic content of the same alga species from the Ol’ga Bay, Kievka Bay, and Tatar Strait have been found to exceed maximum permissible levels. Increased lead concentrations have been detected in Ahnfeltia tobuchiensis. Samples of Ahnfeltia tobuchiensis collected from the bottom layer contain more toxic elements than those from the upper layer.  相似文献   
38.
1H NMR method showed that in systems based on triisobutylaluminum (TIBA) and triphenylcyclopropenylium [Ph3C3]+[B(C6F5)4]–(CPB) or triphenylmethylium [Ph3C]+[B(C6F5)4]–(TB) perfluorophenylborates in a toluene–dichloromethane mixture the Friedel–Crafts process occurs with the formation of ditolylmethane (DTM) accompanied by the complete decomposition of TIBA to form isobutane. 19F NMR spectroscopy showed that the [B(C6F5)4]–anion decomposes in the systems to form B(C6F5)3 and HC6F5. The short-living [AlBu2 i]+ cation formed in the reaction of perfluorophenylborates with TIBA is assumed to be the species initiating the process. It has been shown that CPB is less reactive than TB. The addition of a stoichiometric amount of Ph2CCpFluHfMe2 exerts no effect on the process with the CPB-containing system but inhibits the reaction in the case of TB.  相似文献   
39.
Nickel nanoparticles were deposited on the surface of highly oriented pyrolytical graphite by laser electrodispersion and precipitation from a solution of reverse micelles. The particles were studied using scanning tunneling microscopy and spectroscopy as well as Auger spectroscopy. The elemental composition of the nanoparticles and specific features of the electronic structure of their surface were determined. Adsorption of molecular hydrogen was also studied.  相似文献   
40.
An experimental ultraviolet (UV) polymerizable hybrid organic–inorganic protective coating, mainly intended for the surface protection of porous calcareous stone substrates, has been recently proposed and patented. The hybrid product evidenced an extraordinary hydrophobicity character, able to guarantee a high protection of the stone against water actions, as well as a high traspirability. Furthermore, it is able to equal the performance of commercial available coatings, with the important adjunctive advantage to be free solvent. The application of this product involves the use of a “dual curing” treatment, necessary to harden the coating applied on the substrate, representing this latter a technological limit. The dual curing treatment consists of 6 hr of exposure to a UV‐lamp plus 1 hr at 140°C in oven. In order to avoid this procedure, not easy to realize in situ, two different modifications of the composition of the hybrid product are proposed in this paper. The first one allows the photopolymerization of the hybrid coating only by sunlight exposure. The second one, even though requiring a UV exposure to photo‐polymerize the coating, does not need the subsequent thermal treatment at 140°C. Several experimental characterizations were performed on the newly developed hybrid products, in order to select an optimal composition for the formulations. The selected innovative products were, finally, applied on a calcareous stone substrate, typical of Apulia Region (Pietra Leccese, PL). Both coatings exhibit excellent water‐repellent action and a slight variation of the natural stone color. Copyright © 2014 John Wiley & Sons, Ltd.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号