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41.
Agnieszka Szymaszek-Wawryca Urbano Díaz Bogdan Samojeden Monika Motak 《Molecules (Basel, Switzerland)》2022,27(9)
The application of layered zeolites of MWW topology in environmental catalysis has attracted growing attention in recent years; however, only a few studies have explored their performance in selective catalytic reduction with ammonia (NH3-SCR). Thus, our work describes, for the first time, the one-pot synthesis of Fe-modified NH3-SCR catalysts supported on MCM-22, MCM-36, and ITQ-2. The calculated chemical composition of the materials was Si/Al of 30 and 5 wt.% of Fe. The reported results indicated a correlation between the arrangement of MWW layers and the form of iron in the zeolitic structure. We have observed that one-pot synthesis resulted in high dispersion of Fe3+ sites, which significantly enhanced low-temperature activity and prevented N2O generation during the reaction. All of the investigated samples exhibited almost 100% NO conversion at 250 °C. The most satisfactory activity was exhibited by Fe-modified MCM-36, since 50% of NO reduction was obtained at 150 °C for this catalyst. This effect can be explained by the abundance of isolated Fe3+ species, which are active in low-temperature NH3-SCR. Additionally, SiO2 pillars present in MCM-36 provided an additional surface for the deposition of the active phase. 相似文献
42.
We have recently described an efficient preparation of ketones (or esters) from organomanganous iodides (RMnI) and acid chlorides2 (or chloro-carbonates3). The scope of this reaction is very large and RMnI is often superior to other organometallics. However, the major limitations of this reaction are2b: 相似文献
43.
Jiawei Zhang Yiliu Liu Bin Yuan Prof. Zhiqiang Wang Prof. Monika Schönhoff Prof. Xi Zhang 《Chemistry (Weinheim an der Bergstrasse, Germany)》2012,18(47):14968-14973
Stable multilayer films with cucurbit[8]uril have been fabricated on the basis of the alternating layer‐by‐layer assembly of a novel side‐chain pseudopolyrotaxane and a photoreactive polyanion. The as‐prepared multilayer films exhibit good properties as surface‐imprinted multilayers, because cucurbit[8]uril molecules that are locked inside the multilayers can act as nanocontainers with specific binding to certain guest molecules, and the loading and release of the guest is redox‐controllable and reversible. 相似文献
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45.
Lipophilicity study of eight cephalosporins by reversed‐phase thin‐layer chromatographic method 下载免费PDF全文
Monika Dąbrowska Łukasz Komsta Jan Krzek Kinga Kokoszka 《Biomedical chromatography : BMC》2015,29(11):1759-1768
The lipophilicity (RM0) and specific hydrophobic surface area for the representatives of four generation cephalosporins have been determined by reversed‐phase thin‐layer chromatography, and the effect of different mobile‐phase modifiers (such as methanol, acetonitrile, acetone, 1,4‐dioxane and 2‐propanol) on the retention has been studied. The compounds studied showed typical retention behavior; their RM values decreased linearly with increasing concentration of the organic modifier in the eluent. The linear correlations between the volume fraction of the organic solvent and the RM values over a limited range were established for each solute, resulting in high values of correlation coefficients (>0.95 in most cases). RM values were determined by various concentrations of organic modifier, and the correlation obtained was extrapolated to 0% of organic modifier. Chromatographically established logP (RM0) parameters were compared with computationally calculated partition coefficients values (AClogP, ALOGP, KOWWIN, ALOGPs, XLOGP2, MLOGP and XLOGP3) and experimental octanol–water logP values (measured by the shake flask method). The received results demonstrate that RP‐TLC may be a good alternative technique for analytics in describing the lipophilic nature of investigated cephalosporins as well as the activity. Copyright © 2015 John Wiley & Sons, Ltd. 相似文献
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The liquid‐crystalline polymorphism of the homologous series of 4‐hexyloxybenzylidene‐4′‐alkyloxyanilines is investigated. Basing on the polarization microscopy (POM, TOA), the DSC calorimetry and miscibility studies the following mesophases were detected: nematic, smectic A, smectic C and smectic I. The phase diagrams of the compounds of these series with 4‐hexyloxybenylidene‐4′‐pentylaniline (as the standard of mesophases) show induction of the smectic F mesophases. Their dependence on the alkyl chain length and mole fraction is shown. 相似文献
48.
Monika Dhariwal T. Maitra Ishwar Singh S. Koley A. Taraphder 《Solid State Communications》2012,152(20):1912-1916
The debate over the orbital order in the layered triangular lattice system NaTiO2 has been rekindled by the recent experiments of McQueen et al. [Phys. Rev. Lett. 101 (2008) 166402] on NaVO2. In view of this, the nature of orbital ordering, in both high and low temperature phases, is studied using an ab-initio electronic structure calculation. The orbital order observed in our calculations in the low temperature structure of NaTiO2 is consistent with the predictions of McQueen et al. An LDA plus dynamical mean-field calculation shows considerable transfer of spectral weight from the Fermi level but no metal–insulator transition, confirming the poor metallic behavior observed in transport measurements. 相似文献
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50.
Moamen S. Refat Sulekh Chandra Monika Tyagi 《Phosphorus, sulfur, and silicon and the related elements》2013,188(1):22-33
Mn(II), Co(II), Ni(II), and Cu(II) complexes have been synthesized with benzil bis(thiosemicarbazone) (L) and characterized by elemental analyses, molar conductance measurements, magnetic susceptibility measurements, thermogravimetric studies, infrared (IR), electronic, and electron paramagnetic resonance (eEPR) spectral studies. The molar conductance measurements of the complexes in DMF correspond to the non-electrolytic nature of the complexes. Thus these complexes may be formulated as [M(L)X2] (where M = Mn(II), Co(II), Ni(II), Cu(II) and X = Cl? and NO3 ?). On the basis of IR, electronic, and EPR spectral studies, an octahedral geometry has been assigned for Mn(II), Co(II), and Ni(II) complexes, whereas a tetragonal geometry for the Cu(II) complexes is presumed. The free ligand and its metal complexes were tested against the phytopathogenic fungi (i.e., Rhizoctonia baticola, Alternaria alternata) in vitro. 相似文献