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81.
Monica R. Nemtanu Mirela Brasoveanu Viorica Meltzer Elena Pincu C. Oproiu 《Journal of Thermal Analysis and Calorimetry》2009,97(1):309-313
The purpose of the present work deals with the evaluation of the electron beam irradiation effects on some natural products
based on thermal analysis. Some natural products with therapeutic contributions (artichoke, sea buckthorn, common sage, stonebreaker
and cloves) were irradiated with doses up to 9 kGy using accelerated electron beam. The thermal profiles lead to identify
three phenomena: dehydration — volatilization, irreversible degradation — molecular reorganization and residue decomposition.
The radio-induced degradations determine slight shifts of the temperatures where these phenomena occur. The energetic value
of the studied products is affected by e-beam treatment depending on irradiation dose. 相似文献
82.
Pietro Franceschi Roland Thissen Odile Dutuit Christian Alcaraz Heloise Soldi-Lose Davide Bassi Daniela Ascenzi Paolo Tosi Jan Zabka Zdenek Herman Marcello Coreno Monica de Simone 《International journal of mass spectrometry》2009,280(1-3):119
The long-lived excited states of doubly charged rare gases can markedly affect their reactivity. In this paper we demonstrate the presence of strong state-specific effects in the charge exchange of Ar2+ (3P, 1D and 1S) with several neutral targets (He, Ne, Kr, Xe, D2, and CH4). State sensitive measurements have been performed by producing the different Ar2+ electronic states via tunable synchrotron radiation (Elettra-Trieste, Italy and SuperACO-Orsay, France). From the product ion yield data of charge transfer, state-selected total cross-sections have been deduced. Using the state-specific reactivity of Ar2+ towards different neutral targets, it has been possible to extract the photon-energy-dependent production branching of the three doubly charged states and to investigate the autoionization dynamics of neutral or singly charged Ar in the vicinity of the double ionization threshold. 相似文献
83.
Monica Magureanu Daniela Piroi Florin Gherendi Nicolae Bogdan Mandache Vasile Parvulescu 《Plasma Chemistry and Plasma Processing》2008,28(6):677-688
The decomposition of methylene blue (MB) in aqueous solution was investigated using a pulsed corona discharge. The discharge
was ignited in the gas bubbled in the solution through several needle electrodes. The influence of treatment time, volume
of the treated solution and initial concentration of the dye in solution on MB degradation was studied. The effect of the
nature of the gas introduced was also investigated. For the same energy input, MB conversion increased in the order air < argon < oxygen.
When using oxygen, the decomposition of MB exceeded 95% after ~20 min plasma treatment. Higher efficiency was obtained for
higher treated volume and higher initial concentration. At 90% conversion the yield obtained with oxygen was ~5 g/kWh for
an initial concentration of 150 mg/l and a treated volume of solution of 100 ml. 相似文献
84.
85.
Monica E. Bad Dumitrescu 《Annals of the Institute of Statistical Mathematics》1987,39(1):211-218
Summary The Bayesian estimation problem for the parameter θ of an exponential probability distribution is considered, when it is assumed
that θ has a natural conjugate prior density and a loss-function depending on the squared error is used. It is shown that,
with probability one, the posterior density of the Bayesian—centered and scaled parameter converges pointwise to the normal
probability density. The weak convergence of the posterior distributions to the normal distribution follows directly. Both
correct and incorrect models are studied and the asymptotic normality is stated respectively. 相似文献
86.
Serpe MJ Whitehead JR Rivera M Clark RL Craig SL 《Colloids and surfaces. A, Physicochemical and engineering aspects》2009,346(1-3):20-27
Single-molecule force spectroscopy, as implemented in an atomic force microscope, provides a rarely used method by which to monitor dynamic processes that occur near surfaces. Here, a methodology is presented and characterized that facilitates the study of polymer bridging across nanometer-sized gaps. The model system employed is that of DNA-based reversible polymers, and an automated procedure is introduced that allows the AFM tip–surface contact point to be automatically determined, and the distance d between opposing surfaces to be actively controlled. Using this methodology, the importance of several experimental parameters was systematically studied, e.g. the frequency of repeated tip/surface contacts, the area of the substrate surface sampled by the AFM, and the use of multiple AFM tips and substrates. Experiments revealed the surfaces to be robust throughout pulling experiments, so that multiple touches and pulls could be carried out on a single spot with no measurable affect on the results. Differences in observed bridging probabilities were observed, both on different spots on the same surface and, more dramatically, from one day to another. Data normalization via a reference measurement allows data from multiple days to be directly compared. 相似文献
87.
An eco-friendly tandem tosylation/Ferrier N-glycosylation of amines catalyzed by Er(OTf)3 in 2-MeTHF
Monica Nardi Natividad Herrera Cano Antonio De Nino Maria Luisa Di Gioia Loredana Maiuolo Manuela Oliverio Ana Santiago Diletta Sorrentino Antonio Procopio 《Tetrahedron letters》2017,58(18):1721-1726
Er(OTf)3 in 2-MeTHF provides a new and eco-friendly process for Ferrier glycosylation of sulfonamides and amino acids with various N-nucleophiles.The stereoselective synthesis of 2,3-unsaturated-N-pseudoglycals was carried out with 3,4,6-tri-O-acetyl-d-glucal and different nucleophiles affording good results in a short time. 相似文献
88.
This Article reveals a rare synthesis of pure Pr(2)O(2)CO(3) (POC) nanopowder by thermolysis (700 °C) of a single chemical precursor in an autogenic reaction. The autogenic thermolysis of praseodymium acetate is a solvent-free, efficient, and straightforward approach yielding luminescent POC nanoparticles. The as-prepared POC nanopowder converted to PrO(1.833) (PO) powder via combustion. Methodical morphological, structural, and compositional characterizations of POC and PO powders are carried out, supported by mechanistic elucidation and the photoluminescent properties. 相似文献
89.
Iuliu O. Marian Nicolae Bonciocat Cecilia Cristea Robert Săndulescu Monica Bucşa Mircea Vlassa 《Electroanalysis》2010,22(5):542-548
The electrochemical and spectroelectrochemical behavior of 9‐substituted with ? CN and ? COOH acridine N‐oxides with potential antitumor activity was investigated. In SER spectra of the investigated compounds, the ring stretching vibration at 1568 cm?1 for 9‐CN‐substituted compound respectively 1639 cm?1 for 9‐COOH‐substituted compound was analyzed. Cyclic voltammograms indicates that the reduction potential ?0.766 V for ? CN substituted compound increase towards ?0.745 V for ? COOH substituted compound. The proposed theoretical method in the electrochemical impedance spectroscopy uses a reference redox dielectrode and a multielectrode containing the compound. To account for the change of electrochemical impedance we have considered two theoretical quantities: a pseudocapacitance and a pseudo inductance. Two possible arrangements of them: in series, respective in parallel can be used like criteria of drug classification. 相似文献
90.
The synthesis of two oligomers, of a bifunctional diketopiperazine scaffold DKP-1, formally derived from the cyclization of l-aspartic acid and (S)-2,3-diaminopropionic acid, is reported. A trimeric and a tetrameric structure were prepared by solution-phase peptide synthesis (Boc strategy). Conformational analysis of these derivatives was carried out by a combination of 1H NMR spectroscopy, CD spectroscopy, and molecular modeling, and revealed the formation of β-bend ribbon involving 10-membered H-bonded rings and a reverse turn of the growing peptide chain. 相似文献