Synthesis,characterisation and dosimetric evaluation of MgB4O7 glass as thermoluminescent dosimeter

This study presumably reports the dosimetric properties of MgB₄O₇ glass system. A series of MgB₄O₇ glass samples with nominal compositions XMgO-(100-X) B₂O₃, with X?=?35, 40 and 45?mol% was successfully synthesied using conventional melt quenching method. The presence of broad humps and absence of any sharp peak in typical X-ray diffraction patterns confirm the amorphous nature of the synthesised glass samples. Good glass forming ability, 0.55, of the mixture resulting in a glass with excellent glass stability, 1.4, was observed. Thermoluminescence glow curve was observed to be simple with a single well defined dosimetric peak around 200°C. The dose response was found to be linear from 6?µGy to 0.5?kGy when irradiated to Cs-137 gamma rays. Considerably satisfying thermoluminescent (TL) characteristics suggests that the MgB₄O₇ glass could be recommended as a TL dosimeter.     

The Impact of Apple Variety and the Production Methods on the Antibacterial Activity of Vinegar Samples

Apple vinegar is a natural product widely used in food and traditional medicine as it contains many bioactive compounds. The apple variety and production methods are two factors that play a major role in determining the quality of vinegar. Therefore, this study aims to determine the quality of apple vinegar samples from different varieties (Red Delicious, Gala, Golden Delicious, and Starking Delicious) prepared by three methods using small apple pieces, apple juice, and crushed apple, through determining the physicochemical properties and antibacterial activity of these samples. The antibacterial activity was studied against five pathogenic bacteria: Staphylococcus aureus, Klebsiella pneumonia, Escherichia coli (ATB: 57), Escherichia coli (ATB: 97), and Pseudomonas aeruginosa, using two methods, disk diffusion and microdilution, for determining the minimum inhibitory concentrations and the minimum bactericidal concentrations. The results of this study showed that the lowest pH value was 3.6 for Stark Delicious, obtained by liquid fermentation, and the highest acetic acid values were 4.7 and 4% for the vinegar of Red Delicious and Golden Delicious, prepared by solid fermentation, respectively. The results of the antibacterial activity showed considerable activity of apple vinegar on the tested strains. Generally, the Staphylococcus aureus strain appears less sensitive and Pseudomonas aeruginosa seems to be very sensitive against all samples, while the other strains have distinct sensitivities depending on the variety studied and the method used. A higher antibacterial activity was found in vinegar obtained by the apple pieces method and the Red Delicious variety, with a low MIC and MBC recorded, at 1.95 and 3.90 µL/mL, respectively. This study has shown that the choice of both apple variety and production method is therefore an essential step in determining and aiming for the desired quality of apple vinegar.     

Special features of the fluorescence of organic molecules with two-photon absorption in a drop upon exposure to a femtosecond laser pulse

A closed system of equations for spherical microresonator modes and populations of energy levels of twophoton excited molecules placed in a resonator and exposed to a femtosecond laser pulse is derived. The threshold of transition of spontaneous emission into stimulated one (in the superfluorescence mode) in a microparticle is established with allowance for the microparticle morphology and laser pulse duration.     

Synthesis and characterization of chemically cross-linked polyimide-siloxane hybrid films

Chemically cross-linked polyimide and silica hybrid films were prepared through the sol-gel processing. PI matrix was prepared by the reaction of pyromellitic dianhydride with a mixture of diamines e.g., oxydianiline and 2,5-diaminohydroquinon (2,5-DAHQ) to include pendant hydroxyl groups on the chain. These groups were reacted further with isocyanatopropyltriethoxysilane. An appropriate amount of tetraethoxysilane was then added and the sol-gel process was carried out to condense ethoxy groups from both types of silanes thus producing chemically bonded composite films. The films with different silica contents were evaluated by a variety of techniques including FTIR, ²⁹Si NMR, SEM, tensile, thermal, mechanical and thermogravimetric analyses. The chemical interaction between the phases brought about an intimate dispersion of the two phases, which resulted in the formation of nano-sized co-continuous domains. The tensile modulus of such films was higher and thermal expansion coefficient was much lower than those with similar silica contents without inter-phase bonding.     

Comparison of the iterated equation of motion approach and the density matrix formalism for the quantum Rabi model

The density matrix formalism and the equation of motion approach are two semi-analytical methods that can be used to compute the non-equilibrium dynamics of correlated systems. While for a bilinear Hamiltonian both formalisms yield the exact result, for any non-bilinear Hamiltonian a truncation is necessary. Due to the fact that the commonly used truncation schemes differ for these two methods, the accuracy of the obtained results depends significantly on the chosen approach. In this paper, both formalisms are applied to the quantum Rabi model. This allows us to compare the approximate results and the exact dynamics of the system and enables us to discuss the accuracy of the approximations as well as the advantages and the disadvantages of both methods. It is shown to which extent the results fulfill physical requirements for the observables and which properties of the methods lead to unphysical results.     

Mechanical and thermodynamical stability of BiVO_4 polymorphs using first-principles study

First principles calculations of structural, electronic, mechanical, and thermodynamic properties of different polymorphs of BiVO_4 are performed using Bender-type plane/wave ultrasoft pseudopotentials within the generalized gradient approximation(GGA) in the frame of density functional theory(DFT). The calculated structural and electronic properties are consistent with the previous theoretical and experimental results. The electronic structures reveal that m-BiVO_4, opBiVO_4, and st-BiVO_4 have indirect band gaps, on the other hand, zt-BiVO_4 has a direct band gap. From the DOS and Mulliken's charge analysis, it is observed that only m-BiVO_4 has 6s~2Bi lone pair. Bond population analysis indicates that st-BiVO_4 shows a more ionic nature and a similar result is obtained from the elastic properties. From the elastic properties, it is observed that st-BiVO_4 is more mechanically stable than the others. st-BiVO_4 is more ductile and useful for high electro-optical and electro-mechanical coupling devices. Our calculated thermodynamic properties confirm the similar characteristics found from electronic and elastic properties. m-BiVO_4 is useful as photocatalysts, solid state electrolyte,and electrode and other polymorphs are applicable in electronic device fabrications.     

Growth rate of single acetaminophen crystals in supersaturated aqueous solution under different operating conditions

Single crystal growth experiments were conducted to investigate the growth rate of acetaminophen (paracetamol) crystals under carefully controlled conditions of temperature, supersaturation and pH value. The relative growth rate of the different faces was studied. Growth Rate Dispersion (GRD) was observed by studying the effect of supersaturation and temperature on the growth rate. The growth rate in all directions was found to be temperature dependant. Elongation of the crystals was measured due to the faster growth in the Y‐ direction and Xa direction compared to in the Xb direction. Dissolution of the crystals was observed at pH values greater than 8.5, and a growth rate retardation was observed when increasing the pH from 5.6, which is the normal value without additions, to higher values in both acidic and basic mediums up to 8.5. (© 2007 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)     

Experimental verification of epsilon-near-zero metamaterial coupling and energy squeezing using a microwave waveguide

Utilizing a microwave setup, we experimentally verify our recently developed theory of energy squeezing and tunneling [Phys. Rev. Lett. 97, 157403 (2006)10.1103/PhysRevLett.97.157403] through an ultranarrow waveguide channel that mimics zero-permittivity properties. Exploiting the infinite phase velocity supported by a waveguide transition section at cutoff, we test our theory of tunneling in this zero-permittivity region without use of resonant inclusions. This "supercoupling" is shown to have unique anomalous properties: an almost uniform phase along the narrow channel and weak dependence over its geometry.     

Surface and transport studies on La0.7Ba0.3MnO3:SnO2 bilayer

We report on study of morphology, optical contrast and transport characteristics of La_0.7Ba_0.3MnO₃ (LBMO) manganite thin films bilayered with SnO₂ on Si (0 0 1) substrate, synthesized using pulsed laser deposition system. X-ray diffraction study reveals that both LBMO and SnO₂ show polycrystalline growth over the substrate. Atomic force microscopy shows interesting pyramidal structures of LBMO of size ∼2 μm × 1 μm × 0.1 μm. On the other hand, SnO₂ grows in the form of close packed cylindrical clusters of ∼200 nm radius. Near-field optical microscopy (NSOM) study using 532 nm laser reveal that optical NSOM output intensity in LBMO is four times less than SnO₂ signal. Transport characterizations show that this bilayer configuration exhibit non-linear current-voltage characteristics from 300 upto 50 K. The nature becomes linear below this temperature. The results project the system as a promising candidate in non-conventional device category in the area of spintronics.     

Dissipative discrete spatial optical solitons in a system of coupled optical fibers with the Kerr and resonance nonlinearities

The propagation of monochromatic radiation in a system of weakly coupled single-mode optical fibers with saturable amplification and absorption and Kerr nonlinearity of the refractive index is analyzed. Conditions of stability and bistability of plane-wave regimes are determined. Discrete dissipative optical solitons are found and their stability is studied. The hysteresis dependences of the peak intensity of the discrete solitons on the value of the Kerr nonlinearity and the input beam intensity are demonstrated. The numerical estimates of the parameters of the spatial dissipative discrete solitons are presented.