排序方式: 共有95条查询结果,搜索用时 328 毫秒
51.
E. A. Mikhaleva I. N. Flerov M. V. Gorev M. S. Molokeev A. V. Cherepakhin A. V. Kartashev N. V. Mikhashenok K. A. Sablina 《Physics of the Solid State》2012,54(9):1832-1840
The heat capacity and thermal expansion of the PbTiO3 ceramic sample have been measured in the temperature range 80?C970 K. The electrocaloric and barocaloric efficiencies of lead titanate in the ferroelectric phase transition range have been investigated by analyzing the experimental data in terms of the thermodynamic theory of phase transitions, the electrical equation of state P(T, E), the Pippard equation, and the S(T, p) diagram. 相似文献
52.
Bogdanov E. V. Pogoreltsev E. I. Gorev M. V. Molokeev M. S. Flerov I. N. 《Physics of the Solid State》2019,61(2):192-200
Physics of the Solid State - The crystals of (ND4)3VO2F4 with a high degree of deuteration (~87%) have been grown and a significant (~1.5%) increase in the unit cell volume has been detected. The... 相似文献
53.
I. N. Flerov M. V. Gorev V. D. Fokina A. F. Bovina M. S. Molokeev Yu. V. Boĭko V. N. Voronov A. G. Kocharova 《Physics of the Solid State》2006,48(1):106-112
A new chemical compound, (NH4)2KWO3F3, was synthesized. The Rietveld-refined crystal structure was found to be cubic at room temperature and to belong to the elpasolite
family (space group
). The heat capacity and unit cell parameters were studied within a broad temperature range. A second-order phase transition
was found to occur at 235.4 K and to be well described in terms of phenomenological theory. Hydrostatic pressure broadens
the temperature interval of stability of the cubic phase (dT0/dp = −10.8 K GPa−1). A possible model of structural ordering based on a comparison of the entropy parameters and electron density distribution
in oxygen and fluorine atoms is discussed. 相似文献
54.
Jianwei Qiao Lixin Ning Maxim S. Molokeev Yu‐Chun Chuang Qinyuan Zhang Kenneth R. Poeppelmeier Zhiguo Xia 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2019,131(33):11645-11650
Establishing an effective design principle in solid‐state materials for a blue‐light‐excited Eu2+‐doped red‐emitting oxide‐based phosphors remains one of the significant challenges for white light‐emitting diodes (WLEDs). Selective occupation of Eu2+ in inorganic polyhedra with small coordination numbers results in broad‐band red emission as a result of enhanced crystal‐field splitting of 5d levels. Rb3YSi2O7:Eu exhibits a broad emission band at λmax=622 nm under 450 nm excitation, and structural analysis and DFT calculations support the concept that Eu2+ ions preferably occupy RbO6 and YO6 polyhedra and show the characteristic red emission band of Eu2+. The excellent thermal quenching resistance, high color‐rendering index Ra (93), and low CCT (4013 K) of the WLEDs clearly demonstrate that site engineering of rare‐earth phosphors is an effective strategy to target tailored optical performance. 相似文献
55.
Drokina T. V. Petrakovskii G. A. Bayukov O. A. Molokeev M. S. Vorotynov A. M. Popkov S. I. Velikanov D. A. 《Physics of the Solid State》2020,62(2):297-307
Physics of the Solid State - The structural, thermal, static magnetic, and resonance properties of the low-dimensional NaCuFe2(VO4)3 compound obtained by the solid-phase synthesis have been... 相似文献
56.
Bogdanov E. V. Pogoreltsev E. I. Kartashev A. V. Gorev M. V. Molokeev M. S. Mel’nikova S. V. Flerov I. N. Laptash N. M. 《Physics of the Solid State》2020,62(7):1271-1279
Physics of the Solid State - The (NH4)3VOF5 crystals have been synthesized and their homogeneity and single-phase structure has been established by the X-ray diffraction, energy dispersive... 相似文献
57.
Denisova L. T. Molokeev M. S. Irtyugo L. A. Beletskii V. V. Belousova N. V. Denisov V. M. 《Physics of the Solid State》2020,62(2):384-387
Physics of the Solid State - The SmGaGe2O7 oxide material has been obtained from initial Sm2O3, Ga2O3, and GeO2 oxides by solid-phase synthesis with annealing in air in the temperature range of... 相似文献
58.
Physics of the Solid State - 85 RM3(BO3)4 (R is the rare-earth element (Y, La–Lu) and M = Al, Sc, Cr, Fe, or Ga) compounds with the huntite structure have been analyzed. The analysis of the... 相似文献
59.
I. A. Tarasov Z. I. Popov S. N. Varnakov M. S. Molokeev A. S. Fedorov I. A. Yakovlev D. A. Fedorov S. G. Ovchinnikov 《JETP Letters》2014,99(10):565-569
The dispersion of the relative permittivity ? of a 27-nm-thick epitaxial Fe3Si iron silicide film has been measured within the E = 1.16–4.96 eV energy range using the spectroscopic ellipsometry technique. The experimental data are compared to the relative permittivity calculated in the framework of the density functional theory using the GGA-PBE approximation. For Fe3Si, the electronic structure and the electronic density of states (DOS) are calculated. The analysis of the frequencies corresponding to the transitions between the DOS peaks demonstrates qualitative agreement with the measured absorption peaks. The analysis of the single wavelength laser ellipsometry data obtained in the course of the film growth demonstrates that a continuous layer of Fe3Si iron silicide film is formed if the film thickness achieves 5 nm. 相似文献
60.
E. I. Pogorel’tsev E. V. Bogdanov M. S. Molokeev V. N. Voronov L. I. Isaenko S. A. Zhurkov N. M. Laptash M. V. Gorev I. N. Flerov 《Physics of the Solid State》2011,53(6):1202-1211
According to the results of calorimetric and structural studies, the Fm{ie1202-1}m phase in K2NaMoO3F3 remains stable at least to 100 K. No ferroelectric transformation assumed earlier has been revealed in a series of Rb2KMoO3F3 samples prepared using various technologies. Only a phase transition of nonferroelectric origin has been observed near 195
K, and its thermodynamic characteristics have been determined. An analysis of the stability of the cubic structure of molybdenum
fluorine-oxygen elpasolites-cryolites has been performed in the framework of the hypothesis on strengths of interatomic bonds.
The barocaloric effect in Rb2KMoO3F3 has been estimated. 相似文献