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971.
N. Alberro Macias I. Pupo González L. Valcárcel Rojas D. Frías Fonseca J. R. Estévez Álvarez D. López Sánchez A. Montero Álvarez D. Simón Pérez M. A. Isaac Tejera J. F. Pérez Oliva 《Journal of Radioanalytical and Nuclear Chemistry》2006,269(3):597-603
Summary The quality of the potable and purified for haemodialysis waters used in the National Institute of Nephrology was evaluated
since 2002 up to now. A total of 20 chemical components were analyzed. The analytical results were compared with the admissible
maximum concentrations according to the Cuban Standard NC 92-02:85 for potable water and with the Spanish Standard UNE 111-301-90,
related to the quality of water for use in haemodialysis. The quality of both types of water was found to comply with the
Standards regulations. The CEADEN analytical chemistry laboratory operates a quality management system since 1992, that was
credited according to ISO/IEC 17025 requirements. 相似文献
972.
New syntheses of the alkaloids eudistomin T and S are described. The key step, formation of the 1-phenylacetyl β- carboline, involves a tandem aza Wittig / electrocyclic ring closure process. The first synthesis of the alkaloid xestomanzamine A is achieved by coupling of a N-protected harmane, now available via aza Wittig / electrocyclic ring closure process, with a 5-lithioimidazole derivative. 相似文献
973.
M. Quesada J. Puig J.M. Delgado J.M. Peula J.A. Molina R. Hidalgo-Álvarez 《Colloids and surfaces. B, Biointerfaces》1997,8(6):80-309
Polymer colloids coated by antibodies are used in diagnostic tests for the detection of antigens in biological fluids. We present in this paper a simple kinetic model for the optical monitoring of the formation of specific complexes between antigen and antibody with amplification by latex beads. The antibodies are physical or chemically adsorbed onto sulphonate polystyrene or chloromethylstyrene particles respectively. This is a very simple model combining the La Mer idea of optimum surface coverage with Langmuir adsorption of antigen molecules. The kinetic model explains reasonably well the optical response of immunolatex prepared by both methods of immobilization of antibodies on polymer carriers. According to the results obtained with this model the percentage of active IgG on latex particles is extremely low, with a maximum of a 5%. 相似文献
974.
Árpád Elbert Andrea Laforgia 《Zeitschrift für Angewandte Mathematik und Physik (ZAMP)》1983,34(6):774-786
In this paper we are interested in the behaviour respect tov of thekth positive zeroc′ vk of the derivative of the general Bessel functionC v(x)=J v(x)cosα?Y v(x)sinα, 0≤α<π, whereJ v(x) andY v(x) indicate the Bessel functions of first and second kind respectively. It is well known that forc′ vk>∥v∥,c′ vk increases asv increases. Here we prove several additional properties forc′ vk. Our main result is thatc′ vk is concave as a function ofv, whenc′ vk>∥v∥>0. This implies the concavity ofc′ vk for everyk=2,3, ?. In the case of the zerosJ′ vk of d dx J v(x) we extend this property tok=1 for everyv≥0. 相似文献
975.
V. ARÁMBULA-VILLAZANA M. SOLACHE-RÍOS M. T. OLGUÍN 《Journal of inclusion phenomena and macrocyclic chemistry》2006,55(3-4):237-245
Many factors may affect the heavy metals sorption on natural zeolites among them the temperature, for this reason in this paper the cadmium retention behavior on Mexican zeolitic rich tuff as a function of temperature is considered. The kinetic and the isotherms were determined at 303, 318, and 333 K, the remaining cadmium in the solution samples was analyzed by atomic absorption spectrometry. The pseudo-second order rate constant, k, as well as the apparent diffusion coefficients were calculated from the cadmium uptake by the zeolitic rock as a function of the contact time and temperature, the highest amounts were found for the experiments done at 333 K. The maximum cadmium adsorption capacity by the zeolitic material was 12.2 mg Cd2+/g at 318 K corresponding to 20% of the effective ion exchange capacity of the Chihuahua zeolitic rock. In order to explain the cadmium sorption behavior different kinetics and isotherm models were considered. 相似文献
976.
The potential of micellar electrokinetic chromatography (MEKC) with laser-induced fluorescence (LIF) detection for the separation and determination of phosphorus-containing amino acid-herbicides (glufosinate and glyphosate), and aminomethylphosphonic acid (the major metabolite of glyphosate), involving derivatization with fluorescein isothiocyanate (FITC) isomer I, was investigated. Different variables that affect derivatization (pH, FITC concentration, time and temperature) and separation (pH and concentration of the buffer, kind and concentration of surfactants and applied voltage) were studied. The analysis was conducted within about 8 min and the use of the nonionic surfactant Triton X-100 improved the selectivity, thus indirectly enhancing sensitivity by shifting of the interfering peaks of the FITC excess. Dynamic ranges of 2.0-3,000 microg/L, limits of detection at microgram or submicrogram-per-liter level, and relative standard deviations from 4.7 to 6.4% were obtained. The ensuing method--nonionic surfactant MEKC-- is a useful choice for the determination of these herbicides as it provides limits of detection similar or lower than those reported by existing chromatographic alternatives without the use of an additional preconcentration technique such as solid-phase extraction. The separation of a mixture of nine FITC-derivatized amino acids, selected as target compounds, was also carried out to assess the discrimination power of the nonionic surfactant MEKC method for the analysis of closely related anionic analytes. 相似文献
977.
Density functional theory calculations are performed for the adsorption of O2, coadsorption of CO, and the CO+O2 reaction at the interfacial perimeter of nanoparticles supported by rutile TiO2(110). Both stoichiometric and reduced TiO2 surfaces are considered, with various relative arrangements of the supported Au particles with respect to the substrate vacancies. Rather stable binding configurations are found for the O2 adsorbed either at the trough Ti atoms or leaning against the Au particles. The presence of a supported Au particle strongly stabilizes the adsorption of O2. A sizable electronic charge transfer from the Au to the O2 is found together with a concomitant electronic polarization of the support meaning that the substrate is mediating the charge transfer. The O2 attains two different charge states, with either one or two surplus electrons depending on the precise O2 adsorption site at or in front of the Au particle. From the least charged state, the O2 can react with CO adsorbed at the edge sites of the Au particles leading to the formation of CO2 with very low (approximately 0.15 eV) energy barriers. 相似文献
978.
Martínez-López F Cabrerizo-Vílchez MA Hidalgo-Álvarez R 《Journal of colloid and interface science》2000,232(2):303-310
In this paper, we propose a model to analyze the stability of colloidal particles at the air-liquid interface. The proposed model for the colloidal particle interaction considers DLVO interactions and capillary, hydrophobic, and dipolar interactions between the particles. Typical values from the literature were assigned to most parameters included in the model. Numerical computation revealed the most important parameter in determining the total interaction is the density of dipoles at the external surface of the particles. We have found significant differences for the pair potential between hydrophobic and hydrophilic particles. Hydrophobic particles must aggregate in a principal minimum of the interaction potential curve while hydrophilic particles aggregate in a secondary minimum. Copyright 2000 Academic Press. 相似文献
979.
In the present work, a novel approach is proposed for the simultaneous determination of three widely used pesticides (namely, fuberidazole (FBZ), carbaryl (CBL) and benomyl (BNM)). The proposed method is based on a single continuous-flow solid surface fluorimetric multi-optosensor implemented with the use of a minicolumn placed just before the flow-through cell and filled with C18 silica gel. The three pesticides are determined from an only injection (simultaneous determination): the minicolumn strongly retains two of them while the third develops a transitory signal when passing through the sensing solid microzone. Then, two alternate eluting solutions appropriately selected perform the sequential elution of the two pesticides from the minicolumn, achieving the detection zone and developing their transitory signals. The proposed optosensor works under optimal sensitivity conditions for all the three analytes because of the use of multi-wavelength fluorescence detection mode, so recording three different signals corresponding at three pairs of optima excitation/emission wavelengths. Using a sample volume of 2100 μl, the system was calibrated in the range 0.5-15, 40-800 and 50-1000 μg l−1 with detection limits of 0.09, 6 and 9 μg l−1 for FBZ, CBL and BNM, respectively. The R.S.D values (n=10) were lower than 2% in all cases. The proposed methodology was applied satisfactorily to water samples. Recovery percentages ranging from 97.8 to 101.1%, 97.9 to 103% and from 97 to 105% for FBZ, CBL and BNM, respectively, were obtained. 相似文献
980.
A liquid chromatography electrospray mass spectrometry (LC/ESI/MS) method has been developed to identify and quantify microcystins in fish liver and intestine. Microcystins (MCs) were extracted from 500 mg sample with methanol-water (85:25, v/v) and the extracts concentrated to 250 microl. The parameters were optimized by a full factorial 2(3) design. Neither laborious pre-treatment nor clean up were necessary. MCs were separated using conventional C18 column and an acetonitrile-acidified water (pH 3) gradient. Negative samples (without MCs) were discriminated by liquid chromatography diode array detection (LC/DAD). The limits of detection (LOD) and the limits of quantification (LOQ) resulted equal for MC-RR, MC-YR, and MC-LR and were 0.1 and 0.5 microg g(-1), respectively. MCs recoveries at three levels in spiked samples (0.5-3.0 microg g(-1)) were > 92%, with relative standards deviations (RSDs) < 16% for liver samples and > 68% with RSDs < 18% for intestine samples. The proposed method was applied to determine MC-LR in exposed fish to evaluate the bioaccumulation risk. The results showed the transference of MC-LR from cyanobacterial cells to fish tissues. 相似文献