全文获取类型
收费全文 | 451篇 |
免费 | 0篇 |
专业分类
化学 | 168篇 |
晶体学 | 27篇 |
力学 | 5篇 |
数学 | 147篇 |
物理学 | 104篇 |
出版年
2022年 | 5篇 |
2021年 | 3篇 |
2020年 | 6篇 |
2019年 | 5篇 |
2018年 | 12篇 |
2017年 | 12篇 |
2016年 | 7篇 |
2015年 | 3篇 |
2014年 | 13篇 |
2013年 | 26篇 |
2012年 | 17篇 |
2011年 | 15篇 |
2010年 | 13篇 |
2009年 | 11篇 |
2008年 | 14篇 |
2007年 | 14篇 |
2006年 | 13篇 |
2005年 | 25篇 |
2004年 | 15篇 |
2003年 | 11篇 |
2002年 | 15篇 |
2001年 | 15篇 |
2000年 | 5篇 |
1999年 | 6篇 |
1998年 | 4篇 |
1997年 | 7篇 |
1996年 | 3篇 |
1995年 | 6篇 |
1994年 | 10篇 |
1993年 | 7篇 |
1992年 | 6篇 |
1991年 | 12篇 |
1990年 | 9篇 |
1989年 | 9篇 |
1988年 | 4篇 |
1985年 | 7篇 |
1984年 | 6篇 |
1983年 | 11篇 |
1982年 | 10篇 |
1981年 | 5篇 |
1980年 | 3篇 |
1978年 | 9篇 |
1977年 | 6篇 |
1976年 | 3篇 |
1974年 | 3篇 |
1973年 | 5篇 |
1971年 | 3篇 |
1966年 | 2篇 |
1959年 | 2篇 |
1958年 | 3篇 |
排序方式: 共有451条查询结果,搜索用时 78 毫秒
11.
S. V. Golovkin A. P. Kozhevnikov V. P. Kubarovsky A. I. Kulyavtzev V. F. Kurshetsov A. I. Kushnirenko L. G. Landsberg V. V. Molchanov V. A. Mukhin V. I. Solyanik D. V. Vavilov V. A. Victorov M. Ya. Balatz G. V. Dzubenko A. D. Kamenskii G. K. Kliger V. Z. Kolganov V. S. Lakaev G. S. Lomkatzi A. P. Nilov V. T. Smolyankin V. E. Vishnyakov 《Zeitschrift fur Physik C Particles and Fields》1995,68(4):585-594
In the experiments at the SPHINX facility in 70 GeV proton beam of the IHEP accelerator the coherent diffractive production reactions on carbon nucleip+C [(1385)0
K
++C andp+C[0
K
+]+C were investigated. The evidences for new baryon states were obtained in the study of hyperon-kaon effective mass spectra in these two reactions:X (2050) with massM=(2052±6) MeV and width =(35
–35
+22
) MeV inM[(1385)0
K
+] andX(2000) withM=1999±6 MeV and =91±17 MeV inM[0
K
+]. The unusual features of these massive states (small enough decay widths, anomalously large branching ratios for decays with strange particles emission) make them very serious candidates for cryptoexotic pentaquark baryons with hidden strangeness. 相似文献
12.
13.
A. P. Molchanov V. S. Korotkov R. R. Kostikov 《Russian Journal of Organic Chemistry》2006,42(8):1146-1150
In reaction of 4′-arylspiro[1,2,3,4-tetrahydronaphthalene-2,3′-(1′-pyrazolin)]-1-ones with N-chlorosuccinimide formed spirocyclic substituted 3-chloro-1-pyrazolines that lost nitrogen at heating transforming into spirocyclic chlorocyclopropanes. The reaction of the same pyrazolines with chlorine led to the formation of spirocyclic gem-dichlorocyclopropanes. 相似文献
14.
Esters of substituted 2,3,7-triazabicyclo[3.3.0]oct-3-ene-4-carboxylic acids react with acetone in the presence of hydrogen chloride (bromide) affording esters of substituted 2-(1,1-dimethyl-3-oxobutyl)-2,3,7-triazabicyclo[3.3.0]oct-3-ene-4-carboxylic acids. Reactions of esters of substituted 2,3,7-triazabicyclo[3.3.0]octa-1(5),3-diene-4-carboxylic acids with 1-adamantanol in trifluoroacetic acid resulted in esters of substituted 2-(1-adamantyl)- 2,3,7-triazabicyclo[3.3.0]octa-1(5),3-diene-4-carboxylic acids.__________Translated from Zhurnal Organicheskoi Khimii, Vol. 41, No. 2, 2005, pp. 252–263.Original Russian Text Copyright © 2005 by Stepakov, Molchanov, Kostikov. 相似文献
15.
V. S. Molchanov Yu. A. Shashkina O. E. Philippova A. R. Khokhlov 《Colloid Journal》2005,67(5):606-609
The dependence of the viscosity of potassium oleate salt-containing solutions on the surfactant concentration is studied. The potassium oleate concentration corresponding to the formation of semidilute solution of cylindrical micelles is determined. It is shown that, in the semidilute regime, one can distinguish two regions characterized by different exponential dependences of the viscosity on the surfactant concentration. The first region corresponds to unbreakable micelle chains that have no time to be destroyed during the characteristic time of reptation, whereas the second region corresponds to “living chains” whose lifetime is shorter than the characteristic time of reptation. In the second region, rheological properties of semidilute potassium oleate solutions are adequately described by the Maxwell model with a single relaxation time. 相似文献
16.
Ksenia V. Ksenofontova Anastasia A. Kerner Alexander A. Ksenofontov Artyom Yu. Shagurin Pavel S. Bocharov Michael M. Lukanov Airat R. Kayumov Darya E. Zhuravleva Zalina I. Iskhakova Evgeniy E. Molchanov Dmitriy A. Merkushev Ilya A. Khodov Yuriy S. Marfin 《Molecules (Basel, Switzerland)》2022,27(22)
A boron-dipyrromethene (BODIPY) derivative reactive towards amino groups of proteins (NHS-Ph-BODIPY) was synthesized. Spectroscopic and photophysical properties of amine-reactive NHS-Ph-BODIPY and its non-reactive precursor (COOH-Ph-BODIPY) in a number of organic solvents were investigated. Both fluorescent dyes were characterized by green absorption (521–532 nm) and fluorescence (538–552 nm) and medium molar absorption coefficients (46,500–118,500 M−1·cm−1) and fluorescence quantum yields (0.32 – 0.73). Solvent polarizability and dipolarity were found to play a crucial role in solvent effects on COOH-Ph-BODIPY and NHS-Ph-BODIPY absorption and emission bands maxima. Quantum-chemical calculations were used to show why solvent polarizability and dipolarity are important as well as to understand how the nature of the substituent affects spectroscopic properties of the fluorescent dyes. NHS-Ph-BODIPY was used for fluorescent labeling of a number of proteins. Conjugation of NHS-Ph-BODIPY with bovine serum albumin (BSA) resulted in bathochromic shifts of absorption and emission bands and noticeable fluorescence quenching (about 1.5 times). It was demonstrated that the sensitivity of BSA detection with NHS-Ph-BODIPY was up to eight times higher than with Coomassie brilliant blue while the sensitivity of PII-like protein PotN (PotN) detection with NHS-Ph-BODIPY and Coomassie brilliant blue was almost the same. On the basis of the molecular docking results, the most probable binding sites of NHS-Ph-BODIPY in BSA and PotN and the corresponding binding free energies were estimated. 相似文献
17.
A. P. Molchanov T. Q. Tran A. V. Stepakov G. L. Starova R. R. Kostikov 《Russian Journal of Organic Chemistry》2014,50(1):78-82
N-Aryl-C-(arylcarbamoyl)nitrones regioselectively add to methyl 2-(2-phenylcyclopropylidene)-acetate and methyl 2-methylidene-3-phenylcyclopropanecarboxylate to give in each case two diastereoisomeric 5-oxa-6-azaspiro[2.4]heptane-4-carboxylates. 相似文献
18.
A flow chart for the extraction of high-purity (99.98%) crystalline graphite by hydrometallurgical methods from the high-carbon rocks of the Ruzhinskaya area was developed. The graphite was used as the starting material for plasma-chemical tests. Nano-sized carbon nanomaterials were isolated upon the experiment. Some of them could be inherited from the natural graphite-bearing rocks. The results of investigation will be used in the development of resource-saving process for extraction of useful components. 相似文献
19.
20.
A. P. Molchanov T. Q. Tran A. V. Stepakov V. V. Gurzhii R. R. Kostikov 《Russian Journal of Organic Chemistry》2013,49(4):530-535
Treatment of 3-methyl-2-phenylcycloprop-2-ene-1-carboxylic acid with potassium tert-butoxide induced its isomerization into trans-2-methylidene-3-phenylcyclopropane-1-carboxylic acid which was converted into methyl ester, and heating of the latter for 1 h in toluene gave methyl (E)-2-(2-phenylcyclopropylidene)acetate. Thermal isomerization of methyl (E)-2-(2-phenylcyclopropylidene)acetate on prolonged heating in toluene afforded 5-methoxy-3-methyl-2-phenylfuran, and the reaction with 1,3-diphenyl-2-benzofuran resulted in [4 + 2]-cycloaddition at the exocyclic double bond. 相似文献