A comparative study on p-doping behavior of polythiophenes with CH_3SO_3H

Four kinds of polythiophenes have been doped with CH3SO3H in CHCl3 under air,oxygen,and nitrogen. In the doping of two types of poly(3-hexylthiophene)s,P3HexTh(Zn/Ni)and P3HexTh(Fe)with different contents of a head-to-tail unit,the p-doping occurs at a similar rate.The reaction between poly(3-dodecylthiophene),P3DodTh,and the acid takes place more rapidly.P3OBuTh with a butoxy substituent undergoes more facile p-doping and receives photochemical reaction with CHCl3,and this reaction obeys a pseudo-first-order rate law with a rate constant kobs of 1.42×10-5s-1at room tempera- ture.     

Graphical representation of reflection from single and double coating systems on metallic substrate

In the present work a new graphical method is described to represent the resultant of the multiply reflected waves from coating systems consisting of single and double layers on metallic substrate, taking into account the optical phase properties of the films.     

Short-Range Correlations and Meson Exchange Currents in Photonucleon Emission

One-nucleon emission processes induced by photon absorption are studied by considering short-range correlation effects. At energies above the giant resonance region the validity of the direct knock-out model has been tested by comparison with continuum random phase approximation results. Nucleon re-scattering effects have been considered by using an optical potential. The role of the electromagnetic convection, magnetization, and meson exchange currents has been investigated as a function of both excitation energy and momentum transfer. The short-range correlation effects have been studied by using various correlation functions. We found that the nucleon photo-emission cross section is rather sensitive to the presence of short-range correlations at large values of nucleon emission angle. In this region, however, the effects of meson exchange currents are even larger than those produced by short-range correlations.     

Efficient synthesis,reactions, and biological activities of new thieno and furopyrazolo[3,4-b]pyrazines and their related heterocycles

In the present investigation, a simple and straightforward methodology for the preparation of novel bifunctional thienopyrazolopyrazines 4a–d has been reported. Synthesis of thieno or furopyrazolopyrazines 5a , b , e , f was achieved by the reaction of o-amino-esters 4a , b , e , f with 2,5-dimethoxytetrahydrofuran. The latter pyrrolyl derivatives 5a , b , e , f were used as starting intermediates for the synthesis of new pyrimido, pyrido, and pyrazino heterocycles fused to the thieno or furopyrazolopyrazine moiety. Furthermore, alkaline hydrolysis of the o-amino-ester 4a followed by acidification afforded the corresponding o-amino carboxylic acid 15 , which was used as a versatile precursor for the synthesis of other heterocyclic compounds fused to the thienopyrazolopyrazine ring system, namely: pyrimidine, oxazine, oxazepine, and pyridine derivatives 16–23 . The chemical structures of the synthesized compounds were confirmed on the basis of elemental and spectral analyses (Fourier-transform infrared spectroscopy [FT-IR], ¹H nuclear magnetic resonance [NMR], and mass spectroscopy [MS] in addition to ¹³C NMR for some of them). Moreover, from the biological screening, we found that most of the tested compounds exhibited promising antifungal, antibacterial, and anti-inflammatory activities compared with the corresponding reference drugs.     

Antitumor,cytotoxic, and antioxidant evaluation of six heterocyclic compounds containing different heterocycle moieties

Heterocyclic compounds with different heterocycle moieties, namely benzoxazinone, benzimidazole, quinazolinone, and benzofuranone heterocyclic rings, were synthesized, characterized, and evaluated for their anticancer activity against human hepatocellular carcinoma cell line (HepG2) using sulforhodamine B (SRB) and dimethylthiazol-diphenyltetrazolium bromide (MTT) assays. Also, their cytotoxic activities were tested against human epithelioid carcinoma (Hela) cell line in comparison with normal cell, amniotic epithelial (WISH) cell line, as an in vitro toxicity estimation model. The results showed clearly that 2-(2-benzyl-4-oxoquinazolin-3(4H)-yl)acetohydrazide 4 is the most potent antioxidant and anticancer agents. Although, 3-amino-2-benzylquinazolin-4(3H)-one 5 is less potent anticancer agent against Hela but it is more safe against normal cell (WISH).     

Improving the performance of three level code division multiplexing using the optimization of signal level spacing

In order to optimize the performance of three level code division multiplexing (3LCDM) at 2×20 Gb/s data rate, signal level spacing technique is investigated in this paper. The 3LCDM performance is improved considerably using both electrical and optical level spacing optimization configurations. The results demonstrate that by optimization, in conditions of the optical signal-to-noise ratio, an improvement of around 4.5 dB can be achieved in both approaches as well as 3.3 dB in the electrical configuration and 3.5 dB in the optical configuration can be accomplished for the 3LCDM in terms of the receiver sensitivity.     

On Near-Optimal Mean-Field Stochastic Singular Controls: Necessary and Sufficient Conditions for Near-Optimality

Near-optimization is as sensible and important as optimization for both theory and applications. This paper deals with necessary and sufficient conditions for near-optimal singular stochastic controls for nonlinear controlled stochastic differential equations of mean-field type, which is also called McKean–Vlasov-type equations. The proof of our main result is based on Ekeland’s variational principle and some estimates of the state and adjoint processes. It is shown that optimal singular control may fail to exist even in simple cases, while near-optimal singular controls always exist. This justifies the use of near-optimal stochastic controls, which exist under minimal hypotheses and are sufficient in most practical cases. Moreover, since there are many near-optimal singular controls, it is possible to select among them appropriate ones that are easier for analysis and implementation. Under an additional assumptions, we prove that the near-maximum condition on the Hamiltonian function is a sufficient condition for near-optimality. This paper extends the results obtained in (Zhou, X.Y.: SIAM J. Control Optim. 36(3), 929–947, 1998) to a class of singular stochastic control problems involving stochastic differential equations of mean-field type. An example is given to illustrate the theoretical results.