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121.
Mojtaba Shamsipur Mehdi Asgari Mir Fazlollah Mousavi Reza Davarkhah 《Electroanalysis》2012,24(2):357-367
MWCNTs‐nanoNiO composite was used as a glassy carbon electrode modifier for construction of a novel catalase nanobiosensor for hydrogen peroxide. The immobilized catalase exhibited excellent electrocatalytic activity towards the reduction of H2O2. The resulting amperometric biosensor exhibited a linear response over a concentration range of 200 µM to 2.53 mM with a low detection limit of 19.0 µM. Electrochemical impedance measurements revealed that the modified electrode can be used for the sensitive detection of H2O2. The charge transfer resistance found to decrease significantly after enzymatic reaction of nanobiosensor with H2O2. The resulting impedance was highly sensitive to H2O2 over a linear range of 19–170 nM with a detection limit of 2.4 nM. 相似文献
122.
The interactions of two organoplatinum complexes, [Pt(C^N)Cl(dppa)], 1, and [Pt(C^N)Cl(dppm)], 2 (C^N = N(1), C(2')-chelated, deprotonated 2-phenylpyridine, dppa = bis(diphenylphosphino)amine, dppm = bis(diphenylphosphino)methane), as antitumor agents, with bovine serum albumin (BSA) and human serum albumin (HSA) have been studied by fluorescence and UV-vis absorption spectroscopic techniques at pH 7.40. The quenching constants and binding parameters (binding constants and number of binding sites) were determined by fluorescence quenching method. The obtained results revealed that there is a strong binding interaction between the ligands and proteins. The calculated thermodynamic parameters (ΔG, ΔH, and ΔS) confirmed that the binding reaction is mainly entropy-driven, and hydrophobic forces played a major role in the reaction. The displacement experiment shows that these Pt complexes can bind to the subdomain IIA (site I) of albumin. Moreover, synchronous fluorescence spectroscopy studies revealed some changes in the local polarity around the tryptophan residues. Finally, the distance, r, between donor (serum albumin) and acceptor (Pt complexes) was obtained according to F?rster theory of nonradiation energy transfer. 相似文献
123.
Boon Ho Ng Yulong Ding Mojtaba Ghadiri 《中国颗粒学报》2008,6(1):50-58
This paper aims to quantitatively assess the application of kinetic-frictional model to simulate the motion of dry granular materials in dense condition, in particular, the annular shearing in Couette configuration. The weight of frictional stress was varied to study the contribution of the frictional stress in dense granular flows. The results show that the pure kinetic-theory-based computational fluid dynamics (CFD) model (without frictional stress) over-predicts the dominant solids motion of dense granular flow while adding frictional stress [Schaeffer, D. G. (1987). Instability in the evolution equations describing incompressible granular flow. Journal of Differential Equations, 66(1), 19-50] with the solids pressure of [Lun, C. NTK., Savage, S. B., Jeffrey, D. J., & Chepurniy, N. (1984). Kinetic theories for granular flow: Inelastic particles in Couette flow and slightly inelastic particles in a general flow field. Journal of Fluid Mechanics, 140, 223-256] in the CFD model improves the simulation to better conform available experimental results. The results also suggest that frictional stress transmission plays an important role in dense granular flow and should not be neglected in granular flow simulations. Compatible simulation results to the experimental data are seen by increasing the weight of frictional stress to a factor of 1.25-1.5. These improved simulation results suggest the current constitutive relations (kinetic-frictional model) need to be improved in order to better reflect the real dense granular flow. 相似文献
124.
In this paper, the effects of turbulence on sound generation and velocity fluctuations due to pressure waves in a large subsonic wind tunnel are studied. A trip strip located at different positions in the contraction part or at one position in the diffuser of a large wind tunnel is used to investigate the aforementioned phenomenon, and the results indicate that the trip strip has significant effects on sound reduction. The lowest turbulence intensity and sound are obtained from a trip strip with a diameter of 0.91 mm located either at X/L = 0.79 or at X/L = 0.115 in the wide portion of the contraction. Furthermore, the effect of monopole, dipole and quadrupole sources of aerodynamic noise at different velocities is investigated, and it is demonstrated that the contribution of the monopole is dominant, while the shares due to the dipole and quadrupole remain less important. In addition, it is found that the sound waves have a modest impact on the measured longitudinal turbulence and are generated essentially by eddies. 相似文献
125.
Heavy gauge bosons such as W' are expected to exist in many extensions of the Standard Model. In this paper, the most general Lagrangian for the interaction of W' with top and bottom quarks is considered. This Lagrangian consists of V- A and V + A structure with in general complex couplings. Such interactions produce an Electric Dipole Moment (EDM) for the top quark at one loop level. We predict the allowed ranges for the mass and couplings of W' by using the upper limit on the top quark EDM. 相似文献
126.
Ebrahim Karkhaneei Mohammad Hasan Zebrajadian Mojtaba Shamsipur 《Journal of inclusion phenomena and macrocyclic chemistry》2001,40(4):309-312
7Li NMR measurements were employed to monitor the stoichiometry andstability of Li+ ion complexes with 12-crown-4 (12C4), 15-crown-5 (15C5), benzo-15-crown-5 (B15C5) l8-crown-6 (18C6), dicyclohexano-18-crown-6 (DC18C6) and dibenzo-18-crown-6 (DB18C6) in binary acetone-nitrobenzene mixtures of varying composition. In all cases studied, the variation of 7Li chemical shift with the crown/Li+ mole ratio indicated the formation of 1:1 complexes. The formation constants of the resulting complexes were evaluated from computer fitting of the mole ratio data to an equation that relates the observed chemical shifts to the formation constant. In all solvent mixtures used, the stabilities of the resulting 1:1 complexes varied in the order15C5 > B15C5 > DC18C6 > 18C6 > 12C4 >DB18C6. It was found that,in the case of all complexes, an increase in the percentage of acetone in thesolvent mixtures significantly decreased the stability of the complexes. 相似文献
127.
A simple and reliable method for rapid and selective separation of trace amounts of Sr2+ ions from alkali and alkaline earth metal ions by using octadecyl silica membrane disks modified with decyl- 18-crown-6 in
the presence of 1.0 × 10−3 M picric acid is presented. The influence of picric acid concentration, flow rates and nature and amount of the stripping
acid have been investigated. Maximum capacity of the membrane disks modified with 10 mg of the macrocycle was found to be
484 μg of Sr2+ ions. The proposed method permitted enrichment factors of about 80 and higher. The limit of detection of the proposed method
is 1.5 μg per 1000 ml. The method was successfully applied to the recovery of Sr2+ ions from different synthetic and water samples.
Received August 10, 2000. Revision April 17, 2001. 相似文献
128.
L-Lysine was produced by a microbial process utilizing a Corynebacterium glutamicum (ATCC 21799) strain. L-Lysine was purified from the cultivated medium by fixed-bed and simulated moving bed (SMB) chromatography. The separation conditions including pH, eluent concentration and Lys+ and Lys2+ adsorption isotherms were studied in batch adsorption. The column capacity, eluent flow rate and eluent concentration have been studied in fixed-bed chromatography. Maximum purification rate of lysine was obtained as 0.066 g/(g·h) (per gram resin and per hour) at an eluent flow rate of 10 mL/min in fixed-bed chromatography. The results obtained from SMB were 0.11 g/(g·h) for L-lysine purification rate and 96% for L-lysine recovery. 相似文献
129.
M. R. Ganjali Tahereh Poursaberi Fatemeh Basiripour Masoud Salavati-Niassari Mohammad Yousefi Mojtaba Shamsipur 《Analytical and bioanalytical chemistry》2001,370(8):1091-1095
A PVC membrane electrode based on a cadmium–salen (N,N′-bis-salicylidene-1,2ethylenediamine) complex as an anion carrier is described. The electrode has an anti-Hofmeister selectivity
sequence with a preference for thiocyanate at pH 1.5–11.0. It has a linear response to thiocyanate from 1.0 × 10–6 to 1.0 × 10–1 mol L–1 with a slope of 59.1 ± 0.2 mV per decade, and a detection limit of 7 × 10–7 mol L–1. This electrode has high selectivity for thiocyanate relative to many common organic and inorganic anions. The proposed sensor
has a fast response time of approximately 15 s. It was applied to the determination of thiocyanate in a milk sample.
Received: 1 December 2000 / Revised: 19 April 2001 / Accepted: 30 April 2001 相似文献
130.
Bagherzadeh Seyed Amin Ruhani Behrooz Namar Mohammad Mostafa Alamian Rezvan Rostami Sara 《Journal of Thermal Analysis and Calorimetry》2020,139(4):2781-2790
Journal of Thermal Analysis and Calorimetry - Energy consumption growth in the world is one of the primary concerns of researchers in the energy fields. Providing demanded power, especially in peak... 相似文献