SYNTHESES,CRYSTAL STRUCTURES,AND ANTIMICROBIAL ACTIVITIES OF ZINC COMPLEXES DERIVED FROM 2-AMINO-N′- (PYRIDIN-2-YLMETHYLENE)BENZOHYDRAZIDE

Journal of Structural Chemistry - New zinc complexes, [ZnBr2(HL)] (1), [ZnBr(HL)(NCS)]·0.5H2O (2), [Zn(HL)I2] (3), and [ZnL2] (4), where L is the monoanionic form of...     

Long-Chain Alkane Dehydrogenation over Hierarchically Porous Ti-Doped Pt–Sn–K/TiO2–Al2O3 Catalysts

Kinetics and Catalysis - Hierarchically porous γ-Al2O3, TiO2–Al2O3 composite supports, and Pt–Sn–K/Al2O3 and Pt–Sn–K/TiO2–Al2O3 catalysts were prepared...     

Secondary Metabolites of Clinacanthus nutans

Chemistry of Natural Compounds -     

Secondary Metabolites of Mahonia bealei

Chemistry of Natural Compounds -     

An analysis on effect of transverse convex curvature on turbulent flow and heat transfer

An analysis based on a model of modified mixing length by Hornby, Mistry und Barrow [1] was made on the effect of transverse convex curvature in turbulent boundary layer for incompressible axial flows along circular cylinders. The deviation of various turbulent flow and heat transfer properties from those of flat plates is presented. The agreement between the analyses and the experimental results for skin friction and heat transfer rate is good. The study demonstrated that, for a given condition, both the friction coefficient and Stanton number increase with decreasing value of the cyclinder radius and that their values are always greater than those for the flow over a flat plate.     

Direct-contact heat transfer to a spherical liquid/vapor two-phase bubble trailing a wake

The paper deals with the heat transfer causing evaporation of liquid drops in a medium of an immiscible, less volatile liquid. Each drop turns into a two-phase bubble, consisting of a growing vapor phase and a reducing liquid phase, which continues to buoy up in the medium. The bubble is modeled as a sphere in which the yet-to-be vaporized liquid spreads over the rear surface while the rest is occupied by the heat-insulating vapor phase. The rear surface to serve as the effective heat transfer area is assumed to be covered with an axisymmetric wake instead of a boundary layer flow. The quasi-steady, overall heat transfer through the wake in the medium and the layer of the yet-to-be vaporized liquid in the bubble is predicted and compared with relevant experimental results.Die Untersuchung befaßt sich mit der durch die Verdampfung von Flüssigkeitstropfen in einem aus unvermischbarer, flüchtiger Flüssigkeit bestehendem, Medium verursachten Wärmeübertragung. Aus jedem Tropfen entsteht eine Zweiphasenblase, bestehend aus einer wachsenden Dampfphase und einer abnehmenden Flüssigkeitsphase, die in das Medium aufsteigt. Die Blase wird anhand eines Kugelmodells betrachtet, an dem sich die noch nicht verdampfte Flüssigkeit über die Rückseite verteilt und die restliche Fläche mit der wärmeisolierenden Dampfphase behaftet ist. Es wird angenommen, daß sich an der Rückseite als wirksamer Wärmeübergangsbereich ein achsensymmetrischer Nachlauf bildet. Es werden die quasi-gleichförmige Wärmeübertragung durch den Nachlauf in das Medium und durch die Schicht Lage der nicht verdampften Flüssigkeit in der Blase mathematisch berechnet und mit relevanten Versuchsergebnissen verglichen.     

A Cosserat shell model for interphases in elastic media

This study is concerned with the modeling of interphases in elastic media in general, and in composite materials in particular. The aim is to replace a boundary value problem consisting of a three-phase configuration, say that of fiber-interphase-matrix, by a simpler problem which involves the fiber and matrix only, plus certain matching conditions which simulate the interphase. The simplest of such known representations replaces a thin interphase by a “perfect contact interface” (a single surface) across which the displacements and tractions are assumed to be continuous. Another classical model replaces a thin and soft interphase by a “spring-type interface”, across which the tractions are continuous, but the displacement field undergoes a discontinuity. In the present paper, a Cosserat shell model of the interphase is derived which successfully models the original interphase in a unified manner, for the full range of its material parameters relative to those of the neighboring media. The model is derived in the setting of three-dimensional linear elasticity with small deformations and displacements. Comparisons with an existing exact solution of a coated fiber in an infinite matrix show that it performs extremely well even for moderately thick interphases.     

Natural convection in rectangular enclosures with partial heating and cooling

The flow and heat transfer in partially heated and partially cooled cavities were numerically analyzed. Using the control volume approach, a computer program based on SIMPLE algorithm was developed. A square enclosure with variable size heater and cooler on the vertical walls was considered. Computations were carried out to investigate the effects of heater and cooler size on the heat transfer rate. It was observed that for a given cooler size, the mean Nusselt number decreases with increasing heater size. On the other hand, for a given heater size, the mean Nusselt number increases with increasing cooler size. For all Rayleigh numbers considered, the same behavior was observed.

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Natürliche Konvektion in geschlossenen Räumen mit partieller Heizung und Kühlung der Wände

Zusammenfassung Es wurde ein numerisches Modell zur Analyse des Strömungs- und Wärmeübergangsverhaltens in teilweise beheizten und gekühlten Hohlräumen entwickelt und unter Verwendung des Kontrollvolumenprinzips und des Algorithmus SIMPLE als Computer-Programm formuliert. Der Hohlraum ist rechteckig und die variablen Heiz- und Kühlflächen befinden sich auf gegenüberliegenden Vertikalseiten. Hauptziel der Berechnungen war es, den Einfluß der variablen Heiz- und Kühlflächen auf den Wärmeübergang zu ermitteln. Für eine bestimmte Kühlergröße zeigte sich eine Abnahme der gemittelten Nußelt-Zahl mit zunehmender Heizfläche. Andererseits — bei gegebener Heizfläche — stieg die Nußelt-Zahl mit der Kühlfläche an. Dieses Verhalten wurde bei allen untersuchten Rayleighzahlen gefunden.

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Nomenclature g gravitational acceleration - H height of cavity - k thermal conductivity of fluid - l _C cooler size - l _H heater size - mean Nusselt number - Nu _y local Nusselt number - P pressure - Pr Prandtl number - Ra Rayleigh number (Ra = gH ³(T _H –T _C)/()) - T temperature - T _C temperature of cold surface - T _H temperature of hot surface - T _R reference temperature (T _R = (T _C +T _H)/2) - u velocity component inx-direction - x horizontal axis - v velocity component iny-direction - y vertical axis Greek symbols thermal diffusivity - thermal expansion coefficient - density of fluid - stream function - kinematic viscosity     

Development of a three-directional stress cell and measurement of stress distribution on a backhoe bucket

In order to solve the problems between soil and construction machinery such as a hydraulic excavator, it is important to understand their mechanism. The purpose of this research is the development of a three-directional stress cell to measure stress distribution on a backhoe bucket to understand the mechanism of excavation. This three-directional stress cell can directly measure three-directional stresses simultaneously and has both strong structure and high sensitivity, which is not changed by the abrasion of the detecting plate. By using these cells, three-directional stress distribution on the bucket during excavation is measured. The results of the excavation experiments have given us the most fundamental theory of soil excavation, some hints to solve the problems between soil and construction machinery, and a future image of intelligent construction machinery with intelligent sensors.     

Residual stresses and warp generated by one-sided quench of an epoxy-resin beam

This paper discusses the warp and accompanying residual stress in a rectangular epoxy beam produced by water cooling its lower surface. First, the theoretical values of this warp and residual stress are obtained by the linear-viscoelastic theory. The specimen is then subjected to quenching. The variations in the warp are observed. After quenching, the residual stress is measured by a layer-removal method. The experimental and theoretical results are then compared and discussed.