Redoxpolymerisation von Acrylnitril: Kinetik der mit dem Redoxsystem aus 1-Propanol und Chroms?ure ausgel?sten Reaktion

Ohne Zusammenfassung     

On non-orthogonal main effect plans for asymmetrical factorials

Summary Following the lines of Raktoe and Federer [19] a unified approach for constructing main effect plans in any factorials wherek _i's are the numbers of equispaced levels of each of then _i factors, andk _i's are not necessarily primes or prime powers and need not satisty any relations among themselves, is presented. The method consists of, first, dividing the totality of treatment combinations, omitting, of course, some, if necessary, in to pairs such that the differences within the pairs are clear of ‘even’ effects and the sums are clear of ‘odd’ effects, and then, depending on the number of error d.f. wanted, selecting a suitable sub-set of these pairs which lead to the solution of the estimates of main effects. A general class of non-orthogonal main effect plans for 2 ^m ×2 ⁿ factorials is proposed. Information matrices and their inverses for such plans are worked out. An example followed by discussions and comparison statements is presented.     

Diamagnetic persistent current in diffusive normal-metal rings

We have measured a diamagnetic persistent current with flux periodicities of both h/e and h/2e in an array of thirty diffusive mesoscopic gold rings. At the lowest temperatures, the magnitudes of the currents per ring corresponding to the h/e- and h/2e-periodic responses are both comparable to the Thouless energy E(c) identical with Planck's over 2pi/tau(D), where tau(D) is the diffusion time. Taken in conjunction with earlier experiments, our results strongly challenge the conventional theories of persistent current. We consider a new approach associated with the saturation of the phase coherence time tau(phi).     

Predictions of a natural SUSY dark matter model for direct and indirect detection experiments

Journal of High Energy Physics - Based on the analysis of 5 fb−1 of data at the LHC, the ATLAS and CMS collaborations have presented evidence for a Higgs boson with a mass in the 125 GeV...     

Enhanced conductivity and electrical relaxation studies of carbon-coated LiMnPO4 nanorods

Lithium manganese phosphate (LiMnPO₄) nanorods were synthesized using the modified polyol method. Polyvinylpyrrolidone was used as a stabilizer to control the shape and size of LiMnPO₄ nanorods. Resin coating process was used to coat the carbon over the LiMnPO₄ nanorods. X-ray diffraction and Fourier transform infrared spectroscopy results showed the formation of LiMnPO₄ crystalline phase. The TEM image shows a uniform coating of the nano size (2.3 nm) carbon over the surface of LiMnPO₄ nanorods and the EDS spectrum of the carbon-coated LiMnPO₄ nanorods confirming the presence of carbon element along with the other Mn, P, and O elements. Impedance measurements were made on pure and carbon-coated LiMnPO₄ nanorods, and their conductivities were evaluated by analyzing the measured impedance data using the WinFIT software. More than two orders of magnitude of conductivity enhancement was observed in the carbon-coated LiMnPO₄ nanorods compared to pure ones, and the conductivity enhancement may be attributed to the presence of carbon over LiMnPO₄ nanorods. Temperature dependence of conductivity and ac conductivity were calculated using impedance data of pure and carbon-coated LiMnPO₄ nanorods. CR2032 type lithium ion coin cells were fabricated using pure and carbon-coated LiMnPO₄ nanorods and characterized by measuring charge–discharge cycles between 2.9 and 4.5 V at room temperature. More than 25 % of improved capacity was achieved in the carbon-coated LiMnPO₄ nanorods when compared to pure ones synthesized using modified polyol and resin coating processes.     

Synthesis of Vegetable Oil‐Based Polyurethane: A Study on Curing Kinetics Behavior

In the present study, biobased polyurethane (BPU) samples were synthesized from three different polyols along with polymeric hexamethylene diisocyanate. The three different polyols were synthesized by reacting castor oil with ethylene glycol, triethylene glycol, and triethanolamine. The synthesized polyols were confirmed using proton nuclear magnetic resonance (¹H NMR) spectra analysis. BPU samples were confirmed by the disappearance of isocyanate peak in the FTIR spectra. The cross‐linking densities of all BPU samples were determined using swelling studies. Curing kinetics behavior of all BPU samples were analyzed using differential scanning calorimetry at three different heating rates (5, 7.5, and 10°C/min). The curing kinetic parameters were studied using three nonisothermal methods such as Kissinger, Flynn–Wall–Ozawa, and Ozawa, respectively. The activation energies were found to increase with increasing degree of cure (α). Surface properties of all the synthesized BPU samples were evaluated by dynamic mechanical analysis and scanning electron microscopy.     

Acetic anhydride-promoted one-pot condensation of 2,4-thiazolidinedione with bisulfite adducts of aldehydes

We describe a simple and efficient one-pot method for condensing bisulfite adducts of aromatic aldehydes directly with 2,4-thiazolidinedione catalyzed by acetic anhydride. The two main highlights of this study are the one-pot condensation of bisulfite adducts with 2,4-thiazolidinedione in non-aqueous media and the use of Design of Experiment to understand and optimize the reaction conditions. This methodology was then generalized using other active methylene compounds, such as malononitrile.     

Net-proton measurements at RHIC and the quantum chromodynamics phase diagram

Two measurements related to the proton and antiproton production near midrapidity in \(\sqrt {s_{{NN}}} = 7.7\) , 11.5, 19.6, 27, 39, 62.4 and 200 GeV Au+Au collisions using the STAR detector at the Relativistic Heavy Ion Collider (RHIC) are discussed. At intermediate impact parameters, the net-proton midrapidity dv ₁/dy, where v ₁ and y are directed flow and rapidity, respectively, shows non-monotonic variation as a function of beam energy. This non-monotonic variation is characterized by the presence of a minimum in dv ₁/dy between \(\sqrt {s_{NN}} = 11.5\) and 19.6 GeV and a change in the sign of dv ₁/dy twice between \(\sqrt {s_{{NN}}}\) = 7.7 and 39 GeV. At small impact parameters the product of the moments of net-proton distribution, kurtosis × variance (κ σ ²) and skewness × standard deviation (S σ) are observed to be significantly below the corresponding measurements at large impact parameter collisions for \(\sqrt {s_{{NN}}}\) = 19.6 and 27 GeV. The κ σ ² and S σ values at these beam energies deviate from the expectations from Poisson statistics and that from a hadron resonance gas model. Both these measurements have implications towards understanding the quantum chromodynamics (QCD) phase structures, the first-order phase transition and the critical point in the high baryonic chemical potential region of the phase diagram.