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81.
Efficient Synthesis and Antibacterial Activities of Some Novel 1,2,3‐Triazoles Prepared from Propargylic Alcohols and Benzyl Azides 下载免费PDF全文
Rahman Hosseinzadeh Mohammadreza Khadem Abolfazli Mojtaba Mohseni Maryam Mohadjerani Zahra Lasemi 《Journal of heterocyclic chemistry》2014,51(5):1298-1305
A simple and effective procedure for regioselective preparation of 1,2,3‐triazoles from benzyl azides and propargylic alcohols is described using CuSO4.5H2O and sodium ascorbate. To screen the antibacterial activity of some newly synthesized triazole derivatives, minimum inhibitory concentration of 3d and 3k was evaluated against gram positive Staphylococcus aureus and Bacillus subtilis and gram negative Escherichia coli and Pseudomonas aeruginosa. 相似文献
82.
Mir Masoud Seyyed Fakhrabadi Mostafa Samadzadeh Abbas Rastgoo Mohammadreza Haeri Yazdi Mahmoud Mousavi Mashhadi 《Physica E: Low-dimensional Systems and Nanostructures》2011,44(3):565-578
This paper presents the molecular mechanics based finite element modeling of carbon nanotubes (CNTs) and their applications as mass sensors. The beam element with elastic behavior is considered as the bond between the carbon atoms and its properties are obtained using equating continuum and molecular characteristics. The first five natural frequencies of CNTs in cantilever and doubly clamped boundary conditions (BCs) and their corresponding mode shapes are studied in detail. Furthermore, a multilayer perceptron neural network is used to predict the fundamental vibration frequencies of the CNTs with different diameters and lengths. In addition, variations of the natural frequencies of the CNTs with distorted cross sections are investigated. Moreover, the effects of some attached masses with various values on the first three natural frequencies of a considered CNT are studied here. 相似文献
83.
Fahimeh?BiglariEmail authorView authors OrcID profile Ali?Ebadian Mohammadreza?Foroutan 《Mediterranean Journal of Mathematics》2018,15(1):11
This paper is aimed to extend the scheme of self scaling, appropriate for the quasi-Newton methods, to the two-step quasi-Newton methods. The scaling scheme has been performed during the main approach of updating the current Hessian approximation and prior to the computation of the next quasi-Newton direction whenever necessary. Global convergence property of the new method is explored on uniformly convex functions with the standard Wolfe line search. Preliminary numerical testing has been performed showing that this technique improves the performance of the two-step method substantially. 相似文献
84.
A General Strategy for Site‐Directed Enzyme Immobilization by Using NiO Nanoparticle Decorated Mesoporous Silica 下载免费PDF全文
Dr. Daishun Ling Dr. Liqian Gao Dr. Jianpeng Wang Mohammadreza Shokouhimehr Jiahui Liu Yongsheng Yu Dr. Michael J. Hackett Dr. Pui‐Kin So Dr. Bo Zheng Prof. Zhongping Yao Prof. Jiang Xia Prof. Taeghwan Hyeon 《Chemistry (Weinheim an der Bergstrasse, Germany)》2014,20(26):7916-7921
Mesoporous materials have recently gained much attention owing to their large surface area, narrow pore size distribution, and superior pore structure. These materials have been demonstrated as excellent solid supports for immobilization of a variety of proteins and enzymes for their potential applications as biocatalysts in the chemical and pharmaceutical industries. However, the lack of efficient and reproducible methods for immobilization has limited the activity and recyclability of these biocatalysts. Furthermore, the biocatalysts are usually not robust owing to their rapid denaturation in bulk solvents. To solve these problems, we designed a novel hybrid material system, mesoporous silica immobilized with NiO nanoparticles (SBA‐NiO), wherein enzyme immobilization is directed to specific sites on the pore surface of the material. This yielded the biocatalytic species with higher activity than free enzyme in solution. These biocatalytic species are recyclable with minimal loss of activity after several cycles, demonstrating an advantage over free enzymes. 相似文献
85.
Mohammadreza Gharavi 《Journal of Molecular Spectroscopy》2005,229(1):78-88
A diode laser sensor based on absorption spectroscopy has been developed for the measurement of spectroscopic parameters in the R (3) and R (4) manifolds of 2ν3 band of CH4. Individual linestrengths of each transition are determined for a range of temperatures. In addition, collision-broadened half-widths for CO2, N2, H2O, CH4, and CO collision partners are measured as a function of temperature and pressure for these strongly overlapped transitions. From this, temperature dependence of the collision half-width for each collision partner is determined. Using a new method for calculation of collisional broadening at high temperatures for strongly overlapped transitions makes these transitions accessible for spectroscopy. 相似文献
86.
Fakhar Majid Khodakhah Mohammadreza Mazyaki Ali Soubeyran Antoine Zafarani Jafar 《Journal of Global Optimization》2022,82(1):161-177
Journal of Global Optimization - This paper has two aspects. Mathematically, in the context of global optimization, it provides the existence of an optimum of a perturbed optimization problem that... 相似文献
87.
In the past two decades tissue adhesives and sealants have revolutionized bleeding control and wound healing. This paper focuses on existing tissue adhesive design, their structure, functioning mechanism, and their pros and cons in wound management. It also includes the latest advances in the development of new tissue adhesives as well as the emerging applications in regenerative medicine. We expect that this paper will provide insightful discussion on tissue bioadhesive design and lead to innovations for the development of the next generation of tissue bioadhesives and their related biomedical applications.
88.
Mohammadreza Aboudzadeh Yousef Fazaeli Helma Khodaverdi Hossein Afarideh 《Journal of Radioanalytical and Nuclear Chemistry》2013,295(1):105-113
[140Nd] labeled 5,10,15,20-tetraphenylporphyrin ([140Nd]-TPP) as a tumor–avid complex with a β-emitting radionuclide for evaluating its potential for target tumor therapy is reported. This complex was prepared using freshly prepared [140Nd] NdCl3 (purified by amino functionalized MCM-41 nano resin and commercial cation exchanger resins) and 5,10,15,20-tetraphenylporphyrin (H2TPP).Stability of the complex was investigated in final formulation and human serum for 24 h and the partition coefficient was calculated. The biodistribution of the labeled compound in vital organs of Swiss mice bearing fibro sarcoma tumor was studied using scarification studies and positron emission tomography imaging up to 4 h. 相似文献
89.
Mohammadmahdi Rabieizadeh Seyed Mohammadreza Kashefimofrad Fereshteh Naeimpoor 《Journal of separation science》2014,37(20):2983-2990
The application of molecularly imprinted polymers in the selective adsorption of macromolecules such as proteins by monolithic protein‐imprinted columns requires a macroporous structure, which can be provided by cryogelation at low temperature in which the formation of ice crystals gives a porous structure to the molecularly imprinted polymer. In this study, we applied this technique to synthesize lysozyme‐imprinted polyacrylamide cryogels containing 8% w/v of total monomers and 0.3% w/v of lysozyme. The synthesized cryogel was sponge‐like and elastic with very fast swelling and reshaping properties, showing a swelling ratio of 24.5 ± 3 and gel fraction yield of about 72%. It showed an imprinting effect of 1.58 and a separation factor of 1.37 for cytochrome c as the competing protein. Adsorption studies on the cryogel revealed that it follows the Langmuir isotherm, with a maximum theoretical adsorption capacity of 36.3 mg lysozyme per gram of cryogel. Additionally, it was shown that a salt‐free rebinding solution at low flow rate and pH = 7.0 is favorable for lysozyme rebinding. This kind of monolithic column promises a wide range of application in separation of various biomolecules due to its preparation simplicity, good rebinding characteristics, and macroporosity. 相似文献
90.
Investigation of polyethylene‐grafted‐maleic anhydride presence as a compatibilizer on various properties of nanocomposite films based on polyethylene/ethylene vinyl alcohol/ nanoclay 下载免费PDF全文
Mohammadreza Rahnama Abdulrasoul Oromiehie Shervin Ahmadi Ismaeil Ghasemi 《先进技术聚合物》2017,28(4):449-462
High oxygen barrier films were prepared based on low‐density polyethylene (LDPE)/ethylene vinyl alcohol (EVOH)/ nanoclay and polyethylene‐grafted‐maleic anhydride (LDPE‐g‐MA) as a compatibilizer. Box–Behnken statistical experiment design methodology was employed to study the effects of nanoclay, LDPE‐g‐MA, and EVOH presence and their contents on various properties of the final films. The R2 parameter varied between 0.89 and 0.99 for all the obtained responses. The morphology of the samples was evaluated. Results of oxygen transfer rate (OTR) test indicated that the addition of EVOH up to 30 wt% to neat LDPE can decrease oxygen permeability significantly. The addition of nanoclay also decreased the permeability of resulting films but, LDPE‐g‐MA reduced the permeability of the films only at an optimal content. Elastic modulus was increased with the addition of nanoclay, EVOH, and LDPE‐g‐MA to the matrix. An increase in EVOH content in the samples improved the tensile strength. Effect of nanoclay on tensile strength was highly dependent on the presence of a compatibilizer. The addition of compatibilizer to the samples and increasing its content enhanced the tensile strength of the specimens. Incorporation of nanoclay, EVOH, and LDPE‐g‐MA to the LDPE matrix and increasing the amount of these components in the samples led to higher storage modulus, zero shear rate viscosity, and shear thinning exponent, but, lowered the terminal slope and the frequency of intersection point of storage modulus (G′) and loss modulus (G″). The only exception was that EVOH increment resulted in a lower shear thinning exponent. Copyright © 2016 John Wiley & Sons, Ltd. 相似文献