全文获取类型
收费全文 | 772篇 |
免费 | 45篇 |
国内免费 | 18篇 |
专业分类
化学 | 482篇 |
晶体学 | 3篇 |
力学 | 49篇 |
综合类 | 3篇 |
数学 | 121篇 |
物理学 | 177篇 |
出版年
2023年 | 4篇 |
2022年 | 18篇 |
2021年 | 18篇 |
2020年 | 33篇 |
2019年 | 30篇 |
2018年 | 47篇 |
2017年 | 26篇 |
2016年 | 57篇 |
2015年 | 32篇 |
2014年 | 54篇 |
2013年 | 126篇 |
2012年 | 55篇 |
2011年 | 50篇 |
2010年 | 35篇 |
2009年 | 30篇 |
2008年 | 26篇 |
2007年 | 20篇 |
2006年 | 17篇 |
2005年 | 12篇 |
2004年 | 11篇 |
2003年 | 9篇 |
2002年 | 15篇 |
2001年 | 6篇 |
2000年 | 6篇 |
1999年 | 2篇 |
1998年 | 2篇 |
1997年 | 15篇 |
1996年 | 6篇 |
1995年 | 5篇 |
1994年 | 7篇 |
1993年 | 6篇 |
1992年 | 7篇 |
1991年 | 6篇 |
1990年 | 2篇 |
1989年 | 3篇 |
1988年 | 2篇 |
1987年 | 2篇 |
1984年 | 2篇 |
1983年 | 2篇 |
1981年 | 3篇 |
1980年 | 4篇 |
1979年 | 5篇 |
1978年 | 3篇 |
1975年 | 2篇 |
1971年 | 2篇 |
1969年 | 1篇 |
1968年 | 1篇 |
1958年 | 1篇 |
1955年 | 1篇 |
1948年 | 1篇 |
排序方式: 共有835条查询结果,搜索用时 15 毫秒
101.
The composition-independent virial coefficients of a d-dimensional binary mixture of (additive) hard hyperspheres following from a recent proposal for the equation of state of the mixture (Santos, A., Yuste, S. B., and López de Haro, M., 1999, Molec. Phys., 96, 1) are examined. Good agreement between theoretical estimates and available exact or numerical results is found for d = 2, 3, 4 and 5, except for mixtures whose components are very disparate in size. A slight modification that remedies this deficiency is introduced and the resummation of the associated virial series is carried out, leading to a new proposal for the equation of state. The case of binary hard sphere mixtures (d = 3) is analysed in some detail. 相似文献
102.
103.
Multiconfigurational perturbation theory (CASPT2) and difference dedicated configuration interaction (DDCI) are applied to study the ferrimagnetic coupling in an oxamido-bridged Mn(II)Cu(II) molecular species. CASPT2 reproduces the experimental coupling very well. From the partition of the CASPT2 energy, the most important contributions to the coupling are established. Spin populations are calculated with DDCI. The successive improvement of the N-electron wave function allows us to analyse the contributions to the spin delocalization. 相似文献
104.
BARB FLORIN DAN; DE KONING WILLEM L.; IONESCU VLAD 《IMA Journal of Mathematical Control and Information》1995,12(3):253-298
This paper represents a Popov-theory-based assessment of thecurrent status of the digital control of infinitedimensionalsystems with certain unboundedness in control and/or observation,summarizing some results and indicating which, in the authors'opinion, would be the promising directions for future research. 相似文献
105.
This paper deals with robustness of adaptive control of continuoussystems subject to known output delay, input saturation, unmodelledlinear dynamics, and bounded disturbances. A simple gradient-typealgorithm with a relative deadzone is used. The relative deadzoneis built with an estimated contribution of the unmodelled dynamicsto the system output. The basic tool used for stability androbustness analysis is Gronwall's lemma. 相似文献
106.
107.
A detailed analysis of the gas phase pyrolysis of 1,4-dithiaspiro[4,4]nonane(I), 1,5-dithiaspiro(5.4)decane(II), 1,4-dithiaspiro(4.5)decane(III), and 1,5-(5,5)undecane(IV) is presented. Pyrolysis resulted primarily in cleavage of the molecules to thiocyclopentanone and thiocyclohexanone. The products observed are discussed in relation to the effect of ring size in cyclic dithioketals. A definite correlation was noted between the thermal and their electron-impact-induced fragmentations of these materials. 相似文献
108.
Wollastonite glass-ceramics were prepared through pressureless sintering. The sinterability of the prepared samples of the glassy powder in the system (SiO2-CaO-Na2O-Fe2O3-WO3) was investigated in the temperature range 720-900 °C and soaking time of 180 min. The influence of the increase in the glass powder particle size on the sinterability and dielectric properties of the glass-ceramic samples was studied.The sintered specimens were characterized by scanning electron microscopy (SEM) and X-ray diffraction (XRD) methods. XRD analysis revealed that wollastonite was the main crystalline phase in the sintered glass-ceramics. Dielectric properties such as dielectric constant and dielectric loss were measured via a network analyzer at 10 GHz.It was observed that the increase of the glassy powder particle size improved the sinterability and dielectric properties of the glass-ceramic specimens. Wollastonite glass-ceramics with 16 μm particle size had maximum constant and minimum loss (εr = 10.10 and tan δ = 0.005) compared with the other glass-ceramics. 相似文献
109.
110.
The orientational data of four rigid solutes dissolved in the nematic solvents ZLI1132, EBBA and in a 55wt% ZLI1132 + EBBA mixture have been obtained from proton NMR spectra at different temperatures and used to find a relationship between the solute order in the two nematics and in their mixture. A crossed comparison of the data shows that a simple linear relation, where the normalized weights of the combination are coincident with the molar fractions of ZLI1132 and EBBA in the mixture, gives excellent agreement independently of the solutes and temperatures. Consideration is given to the possibility of a generalization of the results to any mixture of two nematics. 相似文献