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61.
Khodabakhsh NIKNAM Mohammad Ali ZOLFIGOL Zahra HOSSIENINEJAD Nader DANESHVAR 《催化学报》2007,28(7):591-595
以金属硫酸氢盐M(HSO4)n(Ca(HSO4)2,Zn(HSO4)2和过硫酸氢钾制剂oxone○R)为催化剂催化醛、1,3-二羰基化合物和尿素进行缩合反应,在90℃及无溶剂的条件下高收率、一锅法合成了3,4-二氢嘧啶-2(1H)-酮. 相似文献
62.
Mohammad Ali Bigdeli Abbas Rahmati Hossein Abbasi-Ghadim Gholam Hossein Mahdavinia 《Tetrahedron letters》2007,48(26):4575-4578
Aromatic amines have been synthesized efficiently from enamines using SnCl4 and SbCl5 in CH2Cl2 at room temperature. 相似文献
63.
A simple one-pot procedure for the direct conversion of alcohols into azides using TsIm 总被引:1,自引:0,他引:1
A facile and efficient method for one-pot conversion of alcohols into azides using N-(p-toluenesulfonyl)imidazole (TsIm) is described. In this method, alcohols are refluxed with a mixture of NaN3, TsIm and triethylamine in the presence of catalytic amounts of tetra-n-butylammonium iodide (TBAI) in DMF affording the corresponding alkyl azides in good yields. This methodology is highly efficient for various structurally diverse alcohols with selectivity for ROH: 1° > 2° > 3°. 相似文献
64.
Michelini Mdel C Russo N Alikhani ME Silvi B 《Journal of computational chemistry》2004,25(13):1647-1655
The Density functional theory has been applied to characterize the structural features of Mo(1,2)-NH(3),-C(2)H(4), and -C(2)H(2) compounds. Coordination modes, geometrical structures, and binding energies have been calculated for several spin multiplets. It has been shown that in contrast to the conserved spin cases (Mo(1,2)-NH(3)), the interaction between Mo (or Mo(2)) and C(2)H(4) (or C(2)H(2)) are the low-spin (Mo-C(2)H(4) and -C(2)H(2)) and high-spin (Mo(2)-C(2)H(4) and -C(2)H(2)) complexes. In the ground state of Mo(1,2)-C(2)H(4) and -C(2)H(2), the metal-center always reacts with the C-C center. The spontaneous formation of the global minima is found to be possible due to the crossing between the potential energy surfaces (ground and excited states with respect to the metallic center). The bonding characterization has been performed using the topological analysis of the Electron Localization Function. It has been shown that the most stable electronic structure for a pi-acceptor ligand correlates with a maximum charge transfer from the metal center to the C-C bond of the unsaturated hydrocarbons, resulting in the formation of two new basins located on the carbon atoms (away from hydrogen atoms) and the reduction of the number of attractors of the C-C basin. The interaction between Mo(1,2) and C(2)H(4) (or C(2)H(2)) should be considered as a chemical reaction, which causes the multiplicity change. Contrarily, there is no charge transfer between Mo(1,2) and NH(3), and the partners are bound by an electrostatic interaction. 相似文献
65.
Fasih A. Siddiqi N. Lakshminarayanaiah Mohammad N. Beg 《Journal of polymer science. Part A, Polymer chemistry》1971,9(10):2853-2867
The permeability of various electrolytes through parchment-supported ferrocyanide membranes of manganese, cobalt, silver, and cadmium has been measured at 10, 15, 20, 25, and 30°C. The order of permeability at a given temperature was Cl- > NO3- > CNS- > CH3COO- > SO42- for both monovalent and divalent cations. For any given anion, the cations followed the sequence NH4+ > Li+ > Ba2+ > Ca2+ > Mg2+ > Al3+. This sequence has been correlated with the size of the hydrated ion. Further, the data have been considered from the standpoint of the theory of rate processes and the values for the entropy of activation (ΔS′) have been derived assuming an equilibrium distance of 3 Å in the membrane. The values of ΔS′ were all negative and decreased with increasing valence of the ions. This was interpreted to mean electrolyte permeation with partial immobilization in the membrane. 相似文献
66.
Mohammad R.?SaidiEmail author Mohammad?Nazari 《Monatshefte für Chemie / Chemical Monthly》2004,135(3):309-312
Summary. The solid LiClO4-mediated one-pot reaction of aldehydes with secondary amines and C nucleophiles afforded the corresponding aminoalkylation products in high yields. Unlike the previous reported procedure, the aminoalkylation of aldehyde was achieved in the presence of only 0.5 equivalents of solid lithium perchlorate in dichloromethane as the solvent with good to high yields at room temperature. 相似文献
67.
Irradiation of the red-light absorbing dye, methylene blue (MB), in the presence of the metal complex, cis-Rh(phen)2Cl2+ (BISPHEN), leads to irreversible photobinding of both reagents to DNA. Evidence from absorption and emission spectroscopy indicates that the dye is strongly complexed to the DNA at the concentrations used in the experiments and that this complex is unaffected by the presence of BISPHEN. The level of covalent binding is proportional to the absorbed light dose, with the quantum efficiency for covalent binding of BISPHEN to the DNA with 633 nm light equal to 3.5 x 10(-4). Electrospray ionization mass spectrum of a mixture of DNA fragments created by enzymatic degradation of DNA isolated following irradiation indicates that purine adducts are formed with both BISPHEN and the dye. In addition, UV-Vis and high-performance liquid chromatography analyses of the irradiated MB/BISPHEN/DNA mixture and isolated adducts show extensive conversion of the dye and metal complex to the corresponding N-demethylated and aquated derivatives, respectively. Triplet quenchers for MB, for example oxygen and benzoquinone, inhibit both the photoconjugation and the photochemistry of BISPHEN. A mechanism for the synergistic interaction is proposed that involves photoconjugation of both partners to the DNA following oxidation and reduction via electron transfer between 1MB*/DNA and 3MB*/BISPHEN. 相似文献
68.
69.
M. A. Taher 《Journal of Analytical Chemistry》2004,59(10):985-991
A highly selective, sensitive, rapid, and economical differential pulse polarographic method has been developed for the determination of trace amounts of lead in various standard alloys and biological samples after the adsorption of its 2-nitroso-l-naphthol-4-sulfonic acid (nitroso-S)—tetradecyldimethylbenzylammonium (TDBA) chloride on microcrystalline naphthalene in the pH range of 8.0–10.5. After filtration, the solid mass is shaken with 9.0 mL of 1 M hydrochloric acid, and lead is determined by differential pulse polarography (DPP). Lead can alternatively be quantitatively adsorbed on 2-nitroso-l-naphthol-4-sulfonic acid-tetradecyldimethylbenzylammonium-naphthalene adsorbent packed in a column and determined similarly. In this case, 1.0 g of lead can be concentrated in a column from 500 mL of an aqueous sample in which its concentration is as low as 2 ng/mL. Characterization of the electroactive process included an examination of the degree of reversibility. Various parameters, such as the pH effect, volume of aqueous phase, HCl concentration, reagent concentration, naphthalene concentration, shaking time, and the interference of a number of metal ions on the determination of lead were studied in detail to optimize the conditions for determination in standard alloys and standard biological samples. 相似文献
70.
A column preconcentration method has been developed for the determination of trace amounts of manganese by preconcentration on 2-nitroso-1-naphthol-4-sulfonic acid (nitroso-S)-tetradecyldimethylbenzylammonium (TDBA) naphthalene as an adsorbent using a simple funnel tipped glass tube. Manganese reacts with nitroso-S to form a water soluble brown colored chelate anion. The chelate anion forms a water insoluble Mn-Nitroso-S-TDBA ion pair on naphthalene packed in a column in the pH range 9.6-10.5 at a flow rate of 1-2 ml/min. The solid mass consisting of manganese complex and naphthalene is dissolved in 5 ml of dimethylformamide (DMF) and the metal determined by second derivative spectrophotometry. The calibration curve is linear in the concentration range 0.25-35.0 micrograms of Mn in 5 ml of the final DMF solution. Eight replicate determinations of 25 micrograms of standard manganese solution give a mean peak height of 4.0 with a correlation coefficient of 0.9995 and relative standard deviation of +/- 1.1%. The sensitivity was calculated to be 0.502(d2 A/d lambda 2)/microgram ml-1 from the slope of the calibration curve. The detection limit was 0.020 microgram ml-1 for manganese at the minimum instrumental settings (signal to noise ratio = 2). Various parameters effecting the method such as the effect of pH, volume of aqueous phase and interference of a number of metal ions on the determination of manganese have been evaluated to optimize the conditions for its determination in standard alloys and biological samples. 相似文献