Theoretical study of the structural and energetic properties of platinum clusters with up to 60 atoms

Structural Chemistry - Applying a theoretical approach that combines an efficient and fast global optimization based on genetic algorithms (GA) to search in structure space and the parameterized...     

Harmonic and intermodulation distortions and noise associated with two-tone modulation of high-speed semiconductor lasers

We present results of modeling and simulation of the harmonic and intermodulation distortions as well as the intensity noise of high-speed semiconductor lasers under two-tone modulation. Multiple quantum-well lasers are considered, which are characterized by large differential gain and a modulation bandwidth of about 25GHz. The study is based on the rate equation model of semiconductor lasers excited by injection current with two sinusoidal tones separated by a radio frequency. The modulated laser signal is modeled in both the time and frequency domains. The time domain characteristics include the fluctuating waveform, while the frequency domain characteristics include the frequency spectrum of the relative intensity noise (RIN), carrier-to-noise ratio, modulation response, harmonic distortion, and the second- and third-order intermodulation distortions (IMD2 and IMD3). The analysis is performed for three frequencies of 5, 15, and 24 GHz, which are, respectively, lower, comparable, and higher than the laser relaxation frequency. The range of the modulation depth covers the regimes of small and large-signal modulation. We show that both RIN and IMD3 of two-modulated laser are minimum when the modulation frequency is 5GHz, and maximum when the modulation frequency is 24 GHz. The second-order harmonic distortion, IMD2, and IMD3 values are larger in the vicinity of relaxation oscillations and increase with the modulation index, especially under large-signal modulation.     

Hexamethylenetetramine-based ionic liquid anchored onto the metal–organic framework MIL-101(Cr) as a superior and reusable heterogeneous catalyst for the preparation of hexahydroquinolines

Research on Chemical Intermediates - Regarding the significance of medicinal and pharmacological sciences, we explored one-pot multicomponent reaction of aromatic aldehydes, aryl amines,...     

Electrochemical determination of captopril in the presence of acetaminophen,tryptophan, folic acid,and l-cysteine at the surface of modified carbon nanotube paste electrode

Ionics - A novel carbon paste electrode (CPE) modified with 2,2′-[1,7–heptanediylbis(nitrilomethylidene)]-bis(4-hydroxyphenol) (DHB) and carbon nanotubes (CNTs) was prepared. At first,...